Scope of the copper halide/bipyridyl system associated with calixarene-based multihalides for the synthesis of well-defined polystyrene and poly(meth)acrylate stars

Stéphanie Angot; K. Shanmugananda Murthy; Daniel Taton; Yves Gnanou

doi:10.1021/ma000570j

Scope of the copper halide/bipyridyl system associated with calixarene-based multihalides for the synthesis of well-defined polystyrene and poly(meth)acrylate stars

Stéphanie Angot, K. Shanmugananda Murthy, Daniel Taton, Yves Gnanou

Research output: Contribution to journal › Article › peer-review

111 Scopus citations

Abstract

Novel multihalide compounds were used to initiate the atom transfer radical polymerization (ATRP) of styrene, tert-butyl acrylate and methyl methacrylate. The polymerization was restricted to low conversion to prevent stars from mutually coupling and to avoid their contamination. Overlapping concentration was found to play a significant role in the occurrence of star-star coupling. The functionality of the stars was checked by comparing their molar mass with that of their individual arms isolated after hydrolysis of the ester functions. The viscometric characterization attested to the well-defined character of the star polymers.

Original language	English (US)
Pages (from-to)	7261-7274
Number of pages	14
Journal	Macromolecules
Volume	33
Issue number	20
DOIs	https://doi.org/10.1021/ma000570j
State	Published - Oct 3 2000
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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abstract = "Novel multihalide compounds were used to initiate the atom transfer radical polymerization (ATRP) of styrene, tert-butyl acrylate and methyl methacrylate. The polymerization was restricted to low conversion to prevent stars from mutually coupling and to avoid their contamination. Overlapping concentration was found to play a significant role in the occurrence of star-star coupling. The functionality of the stars was checked by comparing their molar mass with that of their individual arms isolated after hydrolysis of the ester functions. The viscometric characterization attested to the well-defined character of the star polymers.",

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AU - Angot, Stéphanie

AU - Murthy, K. Shanmugananda

AU - Taton, Daniel

AU - Gnanou, Yves

PY - 2000/10/3

Y1 - 2000/10/3

N2 - Novel multihalide compounds were used to initiate the atom transfer radical polymerization (ATRP) of styrene, tert-butyl acrylate and methyl methacrylate. The polymerization was restricted to low conversion to prevent stars from mutually coupling and to avoid their contamination. Overlapping concentration was found to play a significant role in the occurrence of star-star coupling. The functionality of the stars was checked by comparing their molar mass with that of their individual arms isolated after hydrolysis of the ester functions. The viscometric characterization attested to the well-defined character of the star polymers.

AB - Novel multihalide compounds were used to initiate the atom transfer radical polymerization (ATRP) of styrene, tert-butyl acrylate and methyl methacrylate. The polymerization was restricted to low conversion to prevent stars from mutually coupling and to avoid their contamination. Overlapping concentration was found to play a significant role in the occurrence of star-star coupling. The functionality of the stars was checked by comparing their molar mass with that of their individual arms isolated after hydrolysis of the ester functions. The viscometric characterization attested to the well-defined character of the star polymers.

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U2 - 10.1021/ma000570j

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ER -

Scope of the copper halide/bipyridyl system associated with calixarene-based multihalides for the synthesis of well-defined polystyrene and poly(meth)acrylate stars

Abstract

ASJC Scopus subject areas

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