Selective formation of propene from CO + H2 or C 2H4 with Fe3(CO)12 supported on inorganic oxides. Mechanistic implication in Fischer-Tropsch synthesis

François Hugues; Bernard Besson; Jean M. Basset

doi:10.1039/C39800000719

Selective formation of propene from CO + H₂ or C ₂H₄ with Fe₃(CO)₁₂ supported on inorganic oxides. Mechanistic implication in Fischer-Tropsch synthesis

François Hugues^*, Bernard Besson, Jean M. Basset

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

When a catalyst derived from Fe₃(CO)₁₂ supported on magnesia is treated either with CO + H₂ or C₂H₄ propene is formed selectively; this can be explained on the basis of a carbene + olefin ⇌ metallacyclobutane mechanism.

Original language	English (US)
Pages (from-to)	719-721
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39800000719
State	Published - 1980
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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@article{b60947cf4fa74278ab1d1605f787c9d8,

title = "Selective formation of propene from CO + H2 or C 2H4 with Fe3(CO)12 supported on inorganic oxides. Mechanistic implication in Fischer-Tropsch synthesis",

abstract = "When a catalyst derived from Fe3(CO)12 supported on magnesia is treated either with CO + H2 or C2H4 propene is formed selectively; this can be explained on the basis of a carbene + olefin ⇌ metallacyclobutane mechanism.",

author = "Fran{\c c}ois Hugues and Bernard Besson and Basset, {Jean M.}",

year = "1980",

doi = "10.1039/C39800000719",

language = "English (US)",

pages = "719--721",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "15",

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T1 - Selective formation of propene from CO + H2 or C 2H4 with Fe3(CO)12 supported on inorganic oxides. Mechanistic implication in Fischer-Tropsch synthesis

AU - Hugues, François

AU - Besson, Bernard

AU - Basset, Jean M.

PY - 1980

Y1 - 1980

N2 - When a catalyst derived from Fe3(CO)12 supported on magnesia is treated either with CO + H2 or C2H4 propene is formed selectively; this can be explained on the basis of a carbene + olefin ⇌ metallacyclobutane mechanism.

AB - When a catalyst derived from Fe3(CO)12 supported on magnesia is treated either with CO + H2 or C2H4 propene is formed selectively; this can be explained on the basis of a carbene + olefin ⇌ metallacyclobutane mechanism.

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U2 - 10.1039/C39800000719

DO - 10.1039/C39800000719

M3 - Article

AN - SCOPUS:0009344373

SN - 0022-4936

SP - 719

EP - 721

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 15

ER -

Selective formation of propene from CO + H₂ or C ₂H₄ with Fe₃(CO)₁₂ supported on inorganic oxides. Mechanistic implication in Fischer-Tropsch synthesis

Abstract

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