Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework

Jesús Ferrando-Soria; Pablo Serra-Crespo; Martijn De Lange; Jorge Gascon Sabate; Freek Kapteijn; Miguel Julve; Joan Cano; Francesc Lloret; Jorge Pasán; Catalina Ruiz-Pérez; Yves Journaux; Emilio Pardo

doi:10.1021/ja3045822

Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework

Jesús Ferrando-Soria, Pablo Serra-Crespo, Martijn De Lange, Jorge Gascon Sabate^*, Freek Kapteijn, Miguel Julve, Joan Cano, Francesc Lloret, Jorge Pasán, Catalina Ruiz-Pérez, Yves Journaux, Emilio Pardo

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

109 Scopus citations

Abstract

A novel isoreticular oxamato-based manganese(II)-copper(II) open metal-organic framework H ₂O@iso1 featuring a pillared square/octagonal layer structure with alternating open and closed octagonal pores has been rationally prepared. The open-framework topology is responsible for a large selectivity in the separation of small gas (CO ₂ over CH ₄) and vapor molecules (CH ₃OH over CH ₃CN and CH ₃CH ₂OH). H ₂O@iso1 displays a long-range three-dimensional ferromagnetic ordering with a drastic variation of the critical temperature as a function of the guest molecule [T _C < 2.0 K (CO ₂@iso1 and CH ₄@iso1) and T _C = 6.5 (CH ₃OH@iso1) and 21.0 K (H ₂O@iso1)].

Original language	English (US)
Pages (from-to)	15301-15304
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	134
Issue number	37
DOIs	https://doi.org/10.1021/ja3045822
State	Published - Sep 19 2012

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja3045822

Cite this

Ferrando-Soria, J., Serra-Crespo, P., De Lange, M., Gascon Sabate, J., Kapteijn, F., Julve, M., Cano, J., Lloret, F., Pasán, J., Ruiz-Pérez, C., Journaux, Y., & Pardo, E. (2012). Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework. Journal of the American Chemical Society, 134(37), 15301-15304. https://doi.org/10.1021/ja3045822

@article{3f1da13b35a84ee4a74fa6c9c1a600bb,

title = "Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework",

abstract = "A novel isoreticular oxamato-based manganese(II)-copper(II) open metal-organic framework H 2O@iso1 featuring a pillared square/octagonal layer structure with alternating open and closed octagonal pores has been rationally prepared. The open-framework topology is responsible for a large selectivity in the separation of small gas (CO 2 over CH 4) and vapor molecules (CH 3OH over CH 3CN and CH 3CH 2OH). H 2O@iso1 displays a long-range three-dimensional ferromagnetic ordering with a drastic variation of the critical temperature as a function of the guest molecule [T C < 2.0 K (CO 2@iso1 and CH 4@iso1) and T C = 6.5 (CH 3OH@iso1) and 21.0 K (H 2O@iso1)].",

author = "Jes{\'u}s Ferrando-Soria and Pablo Serra-Crespo and {De Lange}, Martijn and {Gascon Sabate}, Jorge and Freek Kapteijn and Miguel Julve and Joan Cano and Francesc Lloret and Jorge Pas{\'a}n and Catalina Ruiz-P{\'e}rez and Yves Journaux and Emilio Pardo",

year = "2012",

month = sep,

day = "19",

doi = "10.1021/ja3045822",

language = "English (US)",

volume = "134",

pages = "15301--15304",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "37",

}

Ferrando-Soria, J, Serra-Crespo, P, De Lange, M, Gascon Sabate, J, Kapteijn, F, Julve, M, Cano, J, Lloret, F, Pasán, J, Ruiz-Pérez, C, Journaux, Y & Pardo, E 2012, 'Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework', Journal of the American Chemical Society, vol. 134, no. 37, pp. 15301-15304. https://doi.org/10.1021/ja3045822

TY - JOUR

T1 - Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework

AU - Ferrando-Soria, Jesús

AU - Serra-Crespo, Pablo

AU - De Lange, Martijn

AU - Gascon Sabate, Jorge

AU - Kapteijn, Freek

AU - Julve, Miguel

AU - Cano, Joan

AU - Lloret, Francesc

AU - Pasán, Jorge

AU - Ruiz-Pérez, Catalina

AU - Journaux, Yves

AU - Pardo, Emilio

PY - 2012/9/19

Y1 - 2012/9/19

N2 - A novel isoreticular oxamato-based manganese(II)-copper(II) open metal-organic framework H 2O@iso1 featuring a pillared square/octagonal layer structure with alternating open and closed octagonal pores has been rationally prepared. The open-framework topology is responsible for a large selectivity in the separation of small gas (CO 2 over CH 4) and vapor molecules (CH 3OH over CH 3CN and CH 3CH 2OH). H 2O@iso1 displays a long-range three-dimensional ferromagnetic ordering with a drastic variation of the critical temperature as a function of the guest molecule [T C < 2.0 K (CO 2@iso1 and CH 4@iso1) and T C = 6.5 (CH 3OH@iso1) and 21.0 K (H 2O@iso1)].

AB - A novel isoreticular oxamato-based manganese(II)-copper(II) open metal-organic framework H 2O@iso1 featuring a pillared square/octagonal layer structure with alternating open and closed octagonal pores has been rationally prepared. The open-framework topology is responsible for a large selectivity in the separation of small gas (CO 2 over CH 4) and vapor molecules (CH 3OH over CH 3CN and CH 3CH 2OH). H 2O@iso1 displays a long-range three-dimensional ferromagnetic ordering with a drastic variation of the critical temperature as a function of the guest molecule [T C < 2.0 K (CO 2@iso1 and CH 4@iso1) and T C = 6.5 (CH 3OH@iso1) and 21.0 K (H 2O@iso1)].

UR - http://www.scopus.com/inward/record.url?scp=84866503803&partnerID=8YFLogxK

U2 - 10.1021/ja3045822

DO - 10.1021/ja3045822

M3 - Article

AN - SCOPUS:84866503803

SN - 0002-7863

VL - 134

SP - 15301

EP - 15304

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 37

ER -

Selective gas and vapor sorption and magnetic sensing by an isoreticular mixed-metal-organic framework

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this