Self-assembled polymeric supramolecular frameworks

Nikolay Houbenov; Johannes S. Haataja; Hermis Iatrou; Nikos Hadjichristidis; Janne Ruokolainen; Charl F.J. Faul; Olli Ikkala

doi:10.1002/anie.201007185

Self-assembled polymeric supramolecular frameworks

Nikolay Houbenov^*, Johannes S. Haataja, Hermis Iatrou, Nikos Hadjichristidis, Janne Ruokolainen, Charl F.J. Faul, Olli Ikkala

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Within the framework: Ionic complexation of diblock copolypeptide poly(γ-benzyl-L-glutamate)-block-poly(L-lysine) (PBLG-b-PLL) with 2′-deoxyguanosine 5′-monophosphate (dGMP, gray) generates a polymeric supramolecular framework solid with self-assembled cages based on two orthogonal shape-persistent motifs: PBLG α helices (blue) and PLL β sheets (red), which in turn are held together by shape-persistent hydrogen-bonded G-ribbons.

Original language	English (US)
Pages (from-to)	2516-2520
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	11
DOIs	https://doi.org/10.1002/anie.201007185
State	Published - Mar 7 2011
Externally published	Yes

Keywords

nanomaterials
nucleotides
porous materials
self-assembly
supramolecular chemistry

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201007185

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title = "Self-assembled polymeric supramolecular frameworks",

abstract = "Within the framework: Ionic complexation of diblock copolypeptide poly(γ-benzyl-L-glutamate)-block-poly(L-lysine) (PBLG-b-PLL) with 2′-deoxyguanosine 5′-monophosphate (dGMP, gray) generates a polymeric supramolecular framework solid with self-assembled cages based on two orthogonal shape-persistent motifs: PBLG α helices (blue) and PLL β sheets (red), which in turn are held together by shape-persistent hydrogen-bonded G-ribbons.",

keywords = "nanomaterials, nucleotides, porous materials, self-assembly, supramolecular chemistry",

author = "Nikolay Houbenov and Haataja, {Johannes S.} and Hermis Iatrou and Nikos Hadjichristidis and Janne Ruokolainen and Faul, {Charl F.J.} and Olli Ikkala",

year = "2011",

month = mar,

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doi = "10.1002/anie.201007185",

language = "English (US)",

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journal = "Angewandte Chemie - International Edition",

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T1 - Self-assembled polymeric supramolecular frameworks

AU - Houbenov, Nikolay

AU - Haataja, Johannes S.

AU - Iatrou, Hermis

AU - Hadjichristidis, Nikos

AU - Ruokolainen, Janne

AU - Faul, Charl F.J.

AU - Ikkala, Olli

PY - 2011/3/7

Y1 - 2011/3/7

N2 - Within the framework: Ionic complexation of diblock copolypeptide poly(γ-benzyl-L-glutamate)-block-poly(L-lysine) (PBLG-b-PLL) with 2′-deoxyguanosine 5′-monophosphate (dGMP, gray) generates a polymeric supramolecular framework solid with self-assembled cages based on two orthogonal shape-persistent motifs: PBLG α helices (blue) and PLL β sheets (red), which in turn are held together by shape-persistent hydrogen-bonded G-ribbons.

AB - Within the framework: Ionic complexation of diblock copolypeptide poly(γ-benzyl-L-glutamate)-block-poly(L-lysine) (PBLG-b-PLL) with 2′-deoxyguanosine 5′-monophosphate (dGMP, gray) generates a polymeric supramolecular framework solid with self-assembled cages based on two orthogonal shape-persistent motifs: PBLG α helices (blue) and PLL β sheets (red), which in turn are held together by shape-persistent hydrogen-bonded G-ribbons.

KW - nanomaterials

KW - nucleotides

KW - porous materials

KW - self-assembly

KW - supramolecular chemistry

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U2 - 10.1002/anie.201007185

DO - 10.1002/anie.201007185

M3 - Article

C2 - 21370328

AN - SCOPUS:79952274302

SN - 1433-7851

VL - 50

SP - 2516

EP - 2520

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

Self-assembled polymeric supramolecular frameworks

Abstract

Keywords

ASJC Scopus subject areas

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