Separation properties of an H-Mordenite modified by anchored tris(methyl)-tin and -germanium complexes

A. Théolier; A. Choplin; J. M. Basset; E. Benazzi

doi:10.1016/S0167-2991(08)63670-8

Separation properties of an H-Mordenite modified by anchored tris(methyl)-tin and -germanium complexes

A. Théolier, A. Choplin, J. M. Basset, E. Benazzi

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The sorption properties of an H-Mordenite, modified by controlled chemical reaction with tetramethyl-tin, SnMe₄, and -germanium, GeMe₄, were determined for linear and branched hydrocarbons. Their variations are correlated with the amount of anchored complex; the influence of the size of the alkyl ligands was determined. The separation of linear and monobranched C₆ hydrocarbons from their dimethyl isomers could be achieved with some of these modified mordenites.

Original language	English (US)
Pages (from-to)	1293-1298
Number of pages	6
Journal	Studies in Surface Science and Catalysis
Volume	84
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(08)63670-8
State	Published - Jan 1 1994
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/S0167-2991(08)63670-8

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abstract = "The sorption properties of an H-Mordenite, modified by controlled chemical reaction with tetramethyl-tin, SnMe4, and -germanium, GeMe4, were determined for linear and branched hydrocarbons. Their variations are correlated with the amount of anchored complex; the influence of the size of the alkyl ligands was determined. The separation of linear and monobranched C6 hydrocarbons from their dimethyl isomers could be achieved with some of these modified mordenites.",

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AU - Théolier, A.

AU - Choplin, A.

AU - Basset, J. M.

AU - Benazzi, E.

PY - 1994/1/1

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AB - The sorption properties of an H-Mordenite, modified by controlled chemical reaction with tetramethyl-tin, SnMe4, and -germanium, GeMe4, were determined for linear and branched hydrocarbons. Their variations are correlated with the amount of anchored complex; the influence of the size of the alkyl ligands was determined. The separation of linear and monobranched C6 hydrocarbons from their dimethyl isomers could be achieved with some of these modified mordenites.

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Separation properties of an H-Mordenite modified by anchored tris(methyl)-tin and -germanium complexes

Abstract

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