Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid

Anastasiya V. Bavykina; Elena Rozhko; Maarten G. Goesten; Tim Wezendonk; Beatriz Seoane; Freek Kapteijn; Michiel Makkee; Jorge Gascon

doi:10.1002/cctc.201600419

Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid

Anastasiya V. Bavykina^*, Elena Rozhko, Maarten G. Goesten, Tim Wezendonk, Beatriz Seoane, Freek Kapteijn, Michiel Makkee, Jorge Gascon

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50–90 °C) and in the dehydrogenation of formic acid.

Original language	English (US)
Pages (from-to)	2217-2221
Number of pages	5
Journal	ChemCatChem
Volume	8
Issue number	13
DOIs	https://doi.org/10.1002/cctc.201600419
State	Published - Jul 6 2016
Externally published	Yes

Keywords

carbon dioxide hydrogenation
catalyst shaping
covalent triazine frameworks
formic acid

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1002/cctc.201600419

Cite this

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title = "Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid",

abstract = "A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50–90 °C) and in the dehydrogenation of formic acid.",

keywords = "carbon dioxide hydrogenation, catalyst shaping, covalent triazine frameworks, formic acid",

author = "Bavykina, {Anastasiya V.} and Elena Rozhko and Goesten, {Maarten G.} and Tim Wezendonk and Beatriz Seoane and Freek Kapteijn and Michiel Makkee and Jorge Gascon",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2016",

month = jul,

day = "6",

doi = "10.1002/cctc.201600419",

language = "English (US)",

volume = "8",

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journal = "ChemCatChem",

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T1 - Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid

AU - Bavykina, Anastasiya V.

AU - Rozhko, Elena

AU - Goesten, Maarten G.

AU - Wezendonk, Tim

AU - Seoane, Beatriz

AU - Kapteijn, Freek

AU - Makkee, Michiel

AU - Gascon, Jorge

PY - 2016/7/6

Y1 - 2016/7/6

N2 - A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50–90 °C) and in the dehydrogenation of formic acid.

AB - A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50–90 °C) and in the dehydrogenation of formic acid.

KW - carbon dioxide hydrogenation

KW - catalyst shaping

KW - covalent triazine frameworks

KW - formic acid

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DO - 10.1002/cctc.201600419

M3 - Article

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IS - 13

ER -

Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid

Abstract

Keywords

ASJC Scopus subject areas

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