TY - JOUR
T1 - [(≡SiO)TaV (=CH2)Cl2], the first tantalum methylidene species prepared and identified on the silica surface
AU - Chen, Yin
AU - Callens, Emmanuel
AU - Abou-Hamad, Edy
AU - Basset, Jean-Marie
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We thanks KAUST for the financial support and YC gratefully acknowledges generous donation from SABIC.
PY - 2013/11
Y1 - 2013/11
N2 - A novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. © 2013 Elsevier B.V. All rights reserved.
AB - A novel surface tantalum methylidene [(≡SiO)TaV (=CH 2)Cl2] was obtained via thermal decomposition of the well-defined surface species [(≡SiO)TaVCl2Me 2]. This first surface tantalum methylidene ever synthesized has been fully characterized and the kinetics of the a-hydrogen abstraction reaction has also been investigated in the heterogeneous system. © 2013 Elsevier B.V. All rights reserved.
UR - http://hdl.handle.net/10754/563064
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X13003562
UR - http://www.scopus.com/inward/record.url?scp=84884535334&partnerID=8YFLogxK
U2 - 10.1016/j.jorganchem.2013.04.050
DO - 10.1016/j.jorganchem.2013.04.050
M3 - Article
SN - 0022-328X
VL - 744
SP - 3
EP - 6
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
ER -