TY - JOUR
T1 - Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework
T2 - Interplay of the Magnetic Properties
AU - Mon, Marta
AU - Pascual-Álvarez, Alejandro
AU - Grancha, Thais
AU - Cano, Joan
AU - Ferrando-Soria, Jesús
AU - Lloret, Francesc
AU - Gascon, Jorge
AU - Pasán, Jorge
AU - Armentano, Donatella
AU - Pardo, Emilio
N1 - Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2016/1/11
Y1 - 2016/1/11
N2 - Single-ion magnets (SIMs) are the smallest possible magnetic devices and are a controllable, bottom-up approach to nanoscale magnetism with potential applications in quantum computing and high-density information storage. In this work, we take advantage of the promising, but yet insufficiently explored, solid-state chemistry of metal-organic frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host-guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering of the structured MOF and the slow magnetic relaxation of the SIM.
AB - Single-ion magnets (SIMs) are the smallest possible magnetic devices and are a controllable, bottom-up approach to nanoscale magnetism with potential applications in quantum computing and high-density information storage. In this work, we take advantage of the promising, but yet insufficiently explored, solid-state chemistry of metal-organic frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host-guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering of the structured MOF and the slow magnetic relaxation of the SIM.
KW - magnetic ordering
KW - metal-organic frameworks
KW - multifunctional materials
KW - quantum tunneling effects
KW - single-ion magnet
UR - http://www.scopus.com/inward/record.url?scp=84953366061&partnerID=8YFLogxK
U2 - 10.1002/chem.201504176
DO - 10.1002/chem.201504176
M3 - Article
C2 - 26603579
AN - SCOPUS:84953366061
SN - 0947-6539
VL - 22
SP - 539
EP - 545
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 2
ER -