Solid-state supramolecular organization of polythiophene chains containing thienothiophene units

Patrick Brocorens; Antoine Van Vooren; Michael L. Chabinyc; Michael F. Toney; Maxim Shkunov; Martin Heeney; Iain McCulloch; Jérôme Cornil; Roberto Lazzaroni

doi:10.1002/adma.200801668

Solid-state supramolecular organization of polythiophene chains containing thienothiophene units

Patrick Brocorens, Antoine Van Vooren, Michael L. Chabinyc, Michael F. Toney, Maxim Shkunov, Martin Heeney, Iain McCulloch, Jérôme Cornil, Roberto Lazzaroni

Research output: Contribution to journal › Article › peer-review

77 Scopus citations

Abstract

We use molecular modeling and the simulation of X-ray diffraction patterns to determine the molecular packing of a thiophene-based polymer showing exceptionally high field-effect mobilities (up to 1 cm2 V -1 s-1). We focus on the organization of the polymer chains in lamellae and the orientation of these crystalline domains with respect to the substrate in thin films. The analysis is supported by XRD and NEXAFS experiments and is complemented by calculating intermolecular transfer integrals, which govern the charge mobility. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA.

Original language	English (US)
Pages (from-to)	1193-1198
Number of pages	6
Journal	Advanced Materials
Volume	21
Issue number	10-11
DOIs	https://doi.org/10.1002/adma.200801668
State	Published - Mar 20 2009
Externally published	Yes

ASJC Scopus subject areas

Mechanics of Materials
General Materials Science
Mechanical Engineering

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abstract = "We use molecular modeling and the simulation of X-ray diffraction patterns to determine the molecular packing of a thiophene-based polymer showing exceptionally high field-effect mobilities (up to 1 cm2 V -1 s-1). We focus on the organization of the polymer chains in lamellae and the orientation of these crystalline domains with respect to the substrate in thin films. The analysis is supported by XRD and NEXAFS experiments and is complemented by calculating intermolecular transfer integrals, which govern the charge mobility. {\textcopyright} 2009 WILEY-VCH Verlag GmbH & Co. KGaA.",

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T1 - Solid-state supramolecular organization of polythiophene chains containing thienothiophene units

AU - Brocorens, Patrick

AU - Van Vooren, Antoine

AU - Chabinyc, Michael L.

AU - Toney, Michael F.

AU - Shkunov, Maxim

AU - Heeney, Martin

AU - McCulloch, Iain

AU - Cornil, Jérôme

AU - Lazzaroni, Roberto

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PY - 2009/3/20

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AB - We use molecular modeling and the simulation of X-ray diffraction patterns to determine the molecular packing of a thiophene-based polymer showing exceptionally high field-effect mobilities (up to 1 cm2 V -1 s-1). We focus on the organization of the polymer chains in lamellae and the orientation of these crystalline domains with respect to the substrate in thin films. The analysis is supported by XRD and NEXAFS experiments and is complemented by calculating intermolecular transfer integrals, which govern the charge mobility. © 2009 WILEY-VCH Verlag GmbH & Co. KGaA.

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EP - 1198

JO - Advanced Materials

JF - Advanced Materials

IS - 10-11

ER -

Solid-state supramolecular organization of polythiophene chains containing thienothiophene units

Abstract

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