Solution properties and characteristic ratio of near-monodisperse poly(tert-butyl methacrylate)

Anthony Karandinos; Jimmy W. Mays; Nikos Hadjichristidis

doi:10.1007/BF00297326

Solution properties and characteristic ratio of near-monodisperse poly(tert-butyl methacrylate)

Anthony Karandinos^*, Jimmy W. Mays, Nikos Hadjichristidis

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The dilute solution properties of six near-monodisperse samples of poly(tert-butyl methacrylate) covering the molecular weight range {Mathematical expression} are reported. Unperturbed chain dimensions were derived from a combination of light scattering and intrinsic viscosity data. A characteristic ratio (C_∞) of 12.0 was obtained in the theta solvent cyclohexane at 10°C. This C_∞ value is considerably larger than the value of 8.8 reported previously for poly(n-butyl methacrylate) and reflects the greater bulkiness of the tert-butyl substituent and also, possibly, tacticity effects.

Original language	English (US)
Pages (from-to)	251-254
Number of pages	4
Journal	Polymer Bulletin
Volume	24
Issue number	2
DOIs	https://doi.org/10.1007/BF00297326
State	Published - Aug 1990
Externally published	Yes

ASJC Scopus subject areas

General Chemistry
Condensed Matter Physics
Polymers and Plastics
Materials Chemistry

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title = "Solution properties and characteristic ratio of near-monodisperse poly(tert-butyl methacrylate)",

abstract = "The dilute solution properties of six near-monodisperse samples of poly(tert-butyl methacrylate) covering the molecular weight range {Mathematical expression} are reported. Unperturbed chain dimensions were derived from a combination of light scattering and intrinsic viscosity data. A characteristic ratio (C∞) of 12.0 was obtained in the theta solvent cyclohexane at 10°C. This C∞ value is considerably larger than the value of 8.8 reported previously for poly(n-butyl methacrylate) and reflects the greater bulkiness of the tert-butyl substituent and also, possibly, tacticity effects.",

author = "Anthony Karandinos and Mays, {Jimmy W.} and Nikos Hadjichristidis",

year = "1990",

month = aug,

doi = "10.1007/BF00297326",

language = "English (US)",

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pages = "251--254",

journal = "Polymer Bulletin",

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T1 - Solution properties and characteristic ratio of near-monodisperse poly(tert-butyl methacrylate)

AU - Karandinos, Anthony

AU - Mays, Jimmy W.

AU - Hadjichristidis, Nikos

PY - 1990/8

Y1 - 1990/8

N2 - The dilute solution properties of six near-monodisperse samples of poly(tert-butyl methacrylate) covering the molecular weight range {Mathematical expression} are reported. Unperturbed chain dimensions were derived from a combination of light scattering and intrinsic viscosity data. A characteristic ratio (C∞) of 12.0 was obtained in the theta solvent cyclohexane at 10°C. This C∞ value is considerably larger than the value of 8.8 reported previously for poly(n-butyl methacrylate) and reflects the greater bulkiness of the tert-butyl substituent and also, possibly, tacticity effects.

AB - The dilute solution properties of six near-monodisperse samples of poly(tert-butyl methacrylate) covering the molecular weight range {Mathematical expression} are reported. Unperturbed chain dimensions were derived from a combination of light scattering and intrinsic viscosity data. A characteristic ratio (C∞) of 12.0 was obtained in the theta solvent cyclohexane at 10°C. This C∞ value is considerably larger than the value of 8.8 reported previously for poly(n-butyl methacrylate) and reflects the greater bulkiness of the tert-butyl substituent and also, possibly, tacticity effects.

UR - http://www.scopus.com/inward/record.url?scp=0025469280&partnerID=8YFLogxK

U2 - 10.1007/BF00297326

DO - 10.1007/BF00297326

M3 - Article

AN - SCOPUS:0025469280

SN - 0170-0839

VL - 24

SP - 251

EP - 254

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 2

ER -

Solution properties and characteristic ratio of near-monodisperse poly(tert-butyl methacrylate)

Abstract

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