Stability limits and NO emissions of premixed swirl ammonia-air flames enriched with hydrogen or methane at elevated pressures

Abdulrahman A. Khateeb, Thibault Guiberti, Guoqing Wang, Wesley Boyette, Mourad Younes, Aqil Jamal, William L. Roberts

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133 Scopus citations

Abstract

This study reports measurements of stability limits and exhaust NO mole fractions of technically-premixed swirl ammonia-air flames enriched with either methane or hydrogen. Experiments were conducted at different pressures from atmospheric to 5 bar, representative of commercial micro gas turbines. The full range of ammonia fractions in the fuel blend, xNH3, was considered, from 0 (pure methane or hydrogen) to 1 (pure ammonia), covering very lean (φ = 0.25) to rich (φ = 1.60) equivalence ratios. Results show that increasing pressure widens the range of stable equivalence ratios for pure ammonia-air flames. Regardless of pressure, there is a critical ammonia fraction above which the range of stable equivalence ratios suddenly widens. This is because flashback does not occur anymore when the equivalence ratio is progressively increased towards stoichiometric and rich blowout occurs instead. This critical ammonia fraction increases with pressure and is larger for ammonia-hydrogen than for ammonia-methane. Provided that enough hydrogen is blended with ammonia (xNH3 < 0.9), flames with very lean equivalence ratios (φ < 0.7) can be stabilized and these yield competitively low NO emissions (
Original languageEnglish (US)
JournalInternational Journal of Hydrogen Energy
DOIs
StatePublished - Jan 2021

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