Stable ordered mesoporous titanosilicates with active catalytic sites

Feng Shou Xiao; Yu Han; Xiangju Meng; Yi Yu; Miao Yang; Shuo Wu

doi:10.1016/S0167-2991(03)80446-9

Stable ordered mesoporous titanosilicates with active catalytic sites

Feng Shou Xiao^*, Yu Han, Xiangju Meng, Yi Yu, Miao Yang, Shuo Wu

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Stable ordered mesoporous titanosilicates with highly active catalytic sites (MTS-9) have been successfully synthesized from assembly of pre-formed titanosilicate precursors with polymer surfactant (P123) in strongly acidic media. Mesoporous MTS-9 shows good hydrothermal stability in boiling water (over 120 hours). Catalytic data show that MTS-9 is very active catalyst in catalytic conversion of both small molecule of phenol and bulky molecule of 2,3,6-trimethylphenol. The MTS-9 samples were characterized with infrared, UV-Raman, and TEM techniques. The results suggest that the good hydrothermal stability of MTS-9 is attributed to thicker mesoporous wall and zeolite-like connectivity of TO₄ (T=Si, Ti) in the mesostructure. The high catalytic activity of MTS-9 are due to the TS-1-like enviroment of the Ti species in MTS-9.

Original language	English (US)
Pages (from-to)	565-568
Number of pages	4
Journal	Studies in Surface Science and Catalysis
Volume	146
DOIs	https://doi.org/10.1016/S0167-2991(03)80446-9
State	Published - Jan 1 2003

ASJC Scopus subject areas

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/S0167-2991(03)80446-9

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title = "Stable ordered mesoporous titanosilicates with active catalytic sites",

abstract = "Stable ordered mesoporous titanosilicates with highly active catalytic sites (MTS-9) have been successfully synthesized from assembly of pre-formed titanosilicate precursors with polymer surfactant (P123) in strongly acidic media. Mesoporous MTS-9 shows good hydrothermal stability in boiling water (over 120 hours). Catalytic data show that MTS-9 is very active catalyst in catalytic conversion of both small molecule of phenol and bulky molecule of 2,3,6-trimethylphenol. The MTS-9 samples were characterized with infrared, UV-Raman, and TEM techniques. The results suggest that the good hydrothermal stability of MTS-9 is attributed to thicker mesoporous wall and zeolite-like connectivity of TO4 (T=Si, Ti) in the mesostructure. The high catalytic activity of MTS-9 are due to the TS-1-like enviroment of the Ti species in MTS-9.",

author = "Xiao, {Feng Shou} and Yu Han and Xiangju Meng and Yi Yu and Miao Yang and Shuo Wu",

year = "2003",

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doi = "10.1016/S0167-2991(03)80446-9",

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TY - JOUR

T1 - Stable ordered mesoporous titanosilicates with active catalytic sites

AU - Xiao, Feng Shou

AU - Han, Yu

AU - Meng, Xiangju

AU - Yu, Yi

AU - Yang, Miao

AU - Wu, Shuo

PY - 2003/1/1

Y1 - 2003/1/1

N2 - Stable ordered mesoporous titanosilicates with highly active catalytic sites (MTS-9) have been successfully synthesized from assembly of pre-formed titanosilicate precursors with polymer surfactant (P123) in strongly acidic media. Mesoporous MTS-9 shows good hydrothermal stability in boiling water (over 120 hours). Catalytic data show that MTS-9 is very active catalyst in catalytic conversion of both small molecule of phenol and bulky molecule of 2,3,6-trimethylphenol. The MTS-9 samples were characterized with infrared, UV-Raman, and TEM techniques. The results suggest that the good hydrothermal stability of MTS-9 is attributed to thicker mesoporous wall and zeolite-like connectivity of TO4 (T=Si, Ti) in the mesostructure. The high catalytic activity of MTS-9 are due to the TS-1-like enviroment of the Ti species in MTS-9.

AB - Stable ordered mesoporous titanosilicates with highly active catalytic sites (MTS-9) have been successfully synthesized from assembly of pre-formed titanosilicate precursors with polymer surfactant (P123) in strongly acidic media. Mesoporous MTS-9 shows good hydrothermal stability in boiling water (over 120 hours). Catalytic data show that MTS-9 is very active catalyst in catalytic conversion of both small molecule of phenol and bulky molecule of 2,3,6-trimethylphenol. The MTS-9 samples were characterized with infrared, UV-Raman, and TEM techniques. The results suggest that the good hydrothermal stability of MTS-9 is attributed to thicker mesoporous wall and zeolite-like connectivity of TO4 (T=Si, Ti) in the mesostructure. The high catalytic activity of MTS-9 are due to the TS-1-like enviroment of the Ti species in MTS-9.

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U2 - 10.1016/S0167-2991(03)80446-9

DO - 10.1016/S0167-2991(03)80446-9

M3 - Article

SN - 0167-2991

VL - 146

SP - 565

EP - 568

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

Stable ordered mesoporous titanosilicates with active catalytic sites

Abstract

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