Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)

M. O. Barsukova; D. G. Samsonenko; S. A. Sapchenko; D. N. Dybtsev; V. P. Fedin

doi:10.1007/s11172-017-1910-9

Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)

M. O. Barsukova, D. G. Samsonenko, S. A. Sapchenko, D. N. Dybtsev, V. P. Fedin^*

^*Corresponding author for this work

Advanced Membranes and Porous Materials Center

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H₂O)(bpdc)(im)₂] (1, bpdc^2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH₃)₂NH₂]₄[Cd₆(dmf)(bpdc)₈]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.

Original language	English (US)
Pages (from-to)	1472-1477
Number of pages	6
Journal	Russian Chemical Bulletin
Volume	66
Issue number	8
DOIs	https://doi.org/10.1007/s11172-017-1910-9
State	Published - Aug 1 2017

Keywords

benzimidazole
cadmium
imidazole
metal–organic framework
X-ray diffraction

ASJC Scopus subject areas

General Chemistry

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10.1007/s11172-017-1910-9

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title = "Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)",

abstract = "The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.",

keywords = "benzimidazole, cadmium, imidazole, metal–organic framework, X-ray diffraction",

author = "Barsukova, {M. O.} and Samsonenko, {D. G.} and Sapchenko, {S. A.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

note = "Funding Information: The work was financially supported by the Russian Science Foundation (Project No. 14 23 00013). Publisher Copyright: {\textcopyright} 2017, Springer Science+Business Media, LLC, part of Springer Nature.",

year = "2017",

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doi = "10.1007/s11172-017-1910-9",

language = "English (US)",

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AU - Barsukova, M. O.

AU - Samsonenko, D. G.

AU - Sapchenko, S. A.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

N1 - Funding Information: The work was financially supported by the Russian Science Foundation (Project No. 14 23 00013). Publisher Copyright: © 2017, Springer Science+Business Media, LLC, part of Springer Nature.

PY - 2017/8/1

Y1 - 2017/8/1

N2 - The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.

AB - The influence of heterocyclic compounds on the formation of coordination polymers in the system of cadmium(II) nitrate tetrahydrate and biphenyl-4,4′-dicarboxylic acid is demonstrated. Two new coordination polymers [Cd(H2O)(bpdc)(im)2] (1, bpdc2– is biphenyl-4,4′-dicarboxylate, im is imidazole) and [(CH3)2NH2]4[Cd6(dmf)(bpdc)8]·10DMF (2) were obtained under solvothermal conditions in the presence of imidazole or benzimidazole, respectively. Product 1 has a chain structure, while compound 2 possesses a three-dimensional structure with the hex topology. The obtained compounds were characterized by IR spectroscopy, thermogravimetry, elemental analysis, and powder X-ray diffraction.

KW - benzimidazole

KW - cadmium

KW - imidazole

KW - metal–organic framework

KW - X-ray diffraction

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U2 - 10.1007/s11172-017-1910-9

DO - 10.1007/s11172-017-1910-9

M3 - Article

AN - SCOPUS:85037671924

SN - 1066-5285

VL - 66

SP - 1472

EP - 1477

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 8

ER -

Structure-forming role of heterocyclic compounds in the synthesis of metal-organic frameworks based on cadmium(II)

Abstract

Keywords

ASJC Scopus subject areas

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