Surface organometallic chemistry of tin: Grafting reactions on highly dehydroxylated silica

Manko Adachi; Frédéric Lefebvre; Jean Marie Basset

doi:10.1246/cl.1996.221

Surface organometallic chemistry of tin: Grafting reactions on highly dehydroxylated silica

Manko Adachi, Frédéric Lefebvre, Jean Marie Basset^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

A new grafting method of organotin complexes with the surface of highly dehydroxylated silica is reported. Characterisation was achieved by surface microanalysis, in situ IR, solid state ¹³C CP-MAS and ¹¹⁹Sn MAS NMR. Bu₃Sn-O-SnBu₃ reacts with the strained siloxanes and opens these bridges at room temperature. The reaction occurs also with the remaining hydroxyl groups and with less strained siloxane bridges, leading in all cases to the same surface organometallic fragment ≡Si-O-SnBu₃.

Original language	English (US)
Pages (from-to)	221-222
Number of pages	2
Journal	Chemistry Letters
Issue number	3
DOIs	https://doi.org/10.1246/cl.1996.221
State	Published - 1996
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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10.1246/cl.1996.221

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title = "Surface organometallic chemistry of tin: Grafting reactions on highly dehydroxylated silica",

abstract = "A new grafting method of organotin complexes with the surface of highly dehydroxylated silica is reported. Characterisation was achieved by surface microanalysis, in situ IR, solid state 13C CP-MAS and 119Sn MAS NMR. Bu3Sn-O-SnBu3 reacts with the strained siloxanes and opens these bridges at room temperature. The reaction occurs also with the remaining hydroxyl groups and with less strained siloxane bridges, leading in all cases to the same surface organometallic fragment ≡Si-O-SnBu3.",

author = "Manko Adachi and Fr{\'e}d{\'e}ric Lefebvre and Basset, {Jean Marie}",

year = "1996",

doi = "10.1246/cl.1996.221",

language = "English (US)",

pages = "221--222",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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T1 - Surface organometallic chemistry of tin

T2 - Grafting reactions on highly dehydroxylated silica

AU - Adachi, Manko

AU - Lefebvre, Frédéric

AU - Basset, Jean Marie

PY - 1996

Y1 - 1996

N2 - A new grafting method of organotin complexes with the surface of highly dehydroxylated silica is reported. Characterisation was achieved by surface microanalysis, in situ IR, solid state 13C CP-MAS and 119Sn MAS NMR. Bu3Sn-O-SnBu3 reacts with the strained siloxanes and opens these bridges at room temperature. The reaction occurs also with the remaining hydroxyl groups and with less strained siloxane bridges, leading in all cases to the same surface organometallic fragment ≡Si-O-SnBu3.

AB - A new grafting method of organotin complexes with the surface of highly dehydroxylated silica is reported. Characterisation was achieved by surface microanalysis, in situ IR, solid state 13C CP-MAS and 119Sn MAS NMR. Bu3Sn-O-SnBu3 reacts with the strained siloxanes and opens these bridges at room temperature. The reaction occurs also with the remaining hydroxyl groups and with less strained siloxane bridges, leading in all cases to the same surface organometallic fragment ≡Si-O-SnBu3.

UR - http://www.scopus.com/inward/record.url?scp=0030525504&partnerID=8YFLogxK

U2 - 10.1246/cl.1996.221

DO - 10.1246/cl.1996.221

M3 - Article

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SP - 221

EP - 222

JO - Chemistry Letters

JF - Chemistry Letters

IS - 3

ER -

Surface organometallic chemistry of tin: Grafting reactions on highly dehydroxylated silica

Abstract

ASJC Scopus subject areas

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