Surface Organometallic Chemistry on Metals: Role of A Surface Organometallic Fragment Sn(n-C4H9)x on the Selective Hydrogenation of Citral with a Rh/SiO2 Catalyst

B. Didillon; A. El Mansour; Jean-Pierre Candy; J. M. Basset; F. Le Peletier; J. P. Boitiaux

doi:10.1016/S0167-2991(08)64302-5

Surface Organometallic Chemistry on Metals: Role of A Surface Organometallic Fragment Sn(n-C₄H₉)x on the Selective Hydrogenation of Citral with a Rh/SiO₂ Catalyst

B. Didillon, A. El Mansour, Jean-Pierre Candy, J. M. Basset, F. Le Peletier, J. P. Boitiaux

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A bi-metallic Rh_sSn(C₄H₉)₂/SiO₂ catalyst can be obtained by partial hydrogenolysis, at 373 K, of Sn(n-C₄H₉)₄ on the surface of a Rh⁽⁰⁾ particle supported on SiO₂. The catalyst has been found to be extremely active and selective in the hydrogenation of citral (cis and trans) to the corresponding unsaturated alcohols (geraniol and nerol): 96% of selectivity at 100% conversion.

Original language	English (US)
Pages (from-to)	2371-2374
Number of pages	4
Journal	Studies in Surface Science and Catalysis
Volume	75
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(08)64302-5
State	Published - Jan 1 1993
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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Didillon, B., El Mansour, A., Candy, J.-P., Basset, J. M., Le Peletier, F., & Boitiaux, J. P. (1993). Surface Organometallic Chemistry on Metals: Role of A Surface Organometallic Fragment Sn(n-C₄H₉)x on the Selective Hydrogenation of Citral with a Rh/SiO₂ Catalyst. Studies in Surface Science and Catalysis, 75(C), 2371-2374. https://doi.org/10.1016/S0167-2991(08)64302-5

@article{107ab05296e84f9580358a3fd3d6c76c,

title = "Surface Organometallic Chemistry on Metals: Role of A Surface Organometallic Fragment Sn(n-C4H9)x on the Selective Hydrogenation of Citral with a Rh/SiO2 Catalyst",

abstract = "A bi-metallic RhsSn(C4H9)2/SiO2 catalyst can be obtained by partial hydrogenolysis, at 373 K, of Sn(n-C4H9)4 on the surface of a Rh(0) particle supported on SiO2. The catalyst has been found to be extremely active and selective in the hydrogenation of citral (cis and trans) to the corresponding unsaturated alcohols (geraniol and nerol): 96% of selectivity at 100% conversion.",

author = "B. Didillon and {El Mansour}, A. and Jean-Pierre Candy and Basset, {J. M.} and {Le Peletier}, F. and Boitiaux, {J. P.}",

year = "1993",

month = jan,

day = "1",

doi = "10.1016/S0167-2991(08)64302-5",

language = "English (US)",

volume = "75",

pages = "2371--2374",

journal = "Studies in Surface Science and Catalysis",

issn = "0167-2991",

publisher = "Elsevier BV",

number = "C",

}

Didillon, B, El Mansour, A, Candy, J-P, Basset, JM, Le Peletier, F & Boitiaux, JP 1993, 'Surface Organometallic Chemistry on Metals: Role of A Surface Organometallic Fragment Sn(n-C₄H₉)x on the Selective Hydrogenation of Citral with a Rh/SiO₂ Catalyst', Studies in Surface Science and Catalysis, vol. 75, no. C, pp. 2371-2374. https://doi.org/10.1016/S0167-2991(08)64302-5

Surface Organometallic Chemistry on Metals: Role of A Surface Organometallic Fragment Sn(n-C₄H₉)x on the Selective Hydrogenation of Citral with a Rh/SiO₂ Catalyst. / Didillon, B.; El Mansour, A.; Candy, Jean-Pierre et al.
In: Studies in Surface Science and Catalysis, Vol. 75, No. C, 01.01.1993, p. 2371-2374.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Surface Organometallic Chemistry on Metals

T2 - Role of A Surface Organometallic Fragment Sn(n-C4H9)x on the Selective Hydrogenation of Citral with a Rh/SiO2 Catalyst

AU - Didillon, B.

AU - El Mansour, A.

AU - Candy, Jean-Pierre

AU - Basset, J. M.

AU - Le Peletier, F.

AU - Boitiaux, J. P.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - A bi-metallic RhsSn(C4H9)2/SiO2 catalyst can be obtained by partial hydrogenolysis, at 373 K, of Sn(n-C4H9)4 on the surface of a Rh(0) particle supported on SiO2. The catalyst has been found to be extremely active and selective in the hydrogenation of citral (cis and trans) to the corresponding unsaturated alcohols (geraniol and nerol): 96% of selectivity at 100% conversion.

AB - A bi-metallic RhsSn(C4H9)2/SiO2 catalyst can be obtained by partial hydrogenolysis, at 373 K, of Sn(n-C4H9)4 on the surface of a Rh(0) particle supported on SiO2. The catalyst has been found to be extremely active and selective in the hydrogenation of citral (cis and trans) to the corresponding unsaturated alcohols (geraniol and nerol): 96% of selectivity at 100% conversion.

UR - http://www.scopus.com/inward/record.url?scp=0011053367&partnerID=8YFLogxK

U2 - 10.1016/S0167-2991(08)64302-5

DO - 10.1016/S0167-2991(08)64302-5

M3 - Article

AN - SCOPUS:0011053367

SN - 0167-2991

VL - 75

SP - 2371

EP - 2374

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

IS - C

ER -

Surface Organometallic Chemistry on Metals: Role of A Surface Organometallic Fragment Sn(n-C₄H₉)x on the Selective Hydrogenation of Citral with a Rh/SiO₂ Catalyst

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