Surfactant media to grow new crystalline cobalt 1,3,5-benzenetricarboxylate metal-organic frameworks

Haisheng Lu; Linlu Bai; Weiwei Xiong; Peizhou Li; Junfeng Ding; Guodong Zhang; Tao Wu; Yanli Zhao; Jongmin Lee; Yanhui Yang; Baoyou Geng; Qichun Zhang

doi:10.1021/ic5011133

Surfactant media to grow new crystalline cobalt 1,3,5-benzenetricarboxylate metal-organic frameworks

Haisheng Lu, Linlu Bai, Weiwei Xiong, Peizhou Li, Junfeng Ding, Guodong Zhang, Tao Wu, Yanli Zhao, Jongmin Lee, Yanhui Yang, Baoyou Geng, Qichun Zhang

Research output: Contribution to journal › Article › peer-review

142 Scopus citations

Abstract

In this report, three new metal-organic frameworks (MOFs), [Co 3(μ3-OH)(HBTC)(BTC)2Co(HBTC)]·(HTEA) 3·H2O (NTU-Z30), [Co(BTC)] ·HTEA·H2O (NTU-Z31), [Co3(BTC) 4]·(HTEA)4 (NTU-Z32), where H3BTC = 1,3,5-benzenetricarboxylic acid, TEA = triethylamine, and NTU = Nanyang Technological University, have been successfully synthesized under surfactant media and have been carefully characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis, and IR spectromtry. NTU-Z30 has an unusual trimeric [Co3(μ3-OH)(COO) 7] secondary building unit (SBU), which is different from the well-known trimeric [Co3O(COO)6] SBU. The topology studies indicate that NTU-Z30 and NTU-Z32 possess two new topologies, 3,3,6,7-c net and 2,8-c net, respectively, while NTU-Z31 has a known topology rtl type (3,6-c net). Magnetic analyses show that all three materials have weak antiferromagnetic behavior. Furthermore, NTU-Z30 has been selected as the heterogeneous catalyst for the aerobic epoxidation of alkene, and our results show that this material exhibits excellent catalytic activity as well as good stability. Our success in growing new crystalline cobalt 1,3,5- benzenetricarboxylate MOFs under surfactant media could pave a new road to preparing new diverse crystalline inorganic materials through a surfactant-thermal method. © 2014 American Chemical Society.

Original language	English (US)
Pages (from-to)	8529-8537
Number of pages	9
Journal	Inorganic Chemistry
Volume	53
Issue number	16
DOIs	https://doi.org/10.1021/ic5011133
State	Published - Aug 7 2014

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

Access to Document

10.1021/ic5011133

Cite this

@article{38ecec618cea4c09a2168fb27a495827,

title = "Surfactant media to grow new crystalline cobalt 1,3,5-benzenetricarboxylate metal-organic frameworks",

abstract = "In this report, three new metal-organic frameworks (MOFs), [Co 3(μ3-OH)(HBTC)(BTC)2Co(HBTC)]·(HTEA) 3·H2O (NTU-Z30), [Co(BTC)] ·HTEA·H2O (NTU-Z31), [Co3(BTC) 4]·(HTEA)4 (NTU-Z32), where H3BTC = 1,3,5-benzenetricarboxylic acid, TEA = triethylamine, and NTU = Nanyang Technological University, have been successfully synthesized under surfactant media and have been carefully characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis, and IR spectromtry. NTU-Z30 has an unusual trimeric [Co3(μ3-OH)(COO) 7] secondary building unit (SBU), which is different from the well-known trimeric [Co3O(COO)6] SBU. The topology studies indicate that NTU-Z30 and NTU-Z32 possess two new topologies, 3,3,6,7-c net and 2,8-c net, respectively, while NTU-Z31 has a known topology rtl type (3,6-c net). Magnetic analyses show that all three materials have weak antiferromagnetic behavior. Furthermore, NTU-Z30 has been selected as the heterogeneous catalyst for the aerobic epoxidation of alkene, and our results show that this material exhibits excellent catalytic activity as well as good stability. Our success in growing new crystalline cobalt 1,3,5- benzenetricarboxylate MOFs under surfactant media could pave a new road to preparing new diverse crystalline inorganic materials through a surfactant-thermal method. {\textcopyright} 2014 American Chemical Society.",

author = "Haisheng Lu and Linlu Bai and Weiwei Xiong and Peizhou Li and Junfeng Ding and Guodong Zhang and Tao Wu and Yanli Zhao and Jongmin Lee and Yanhui Yang and Baoyou Geng and Qichun Zhang",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors thank Prof. Tao Wu and Jian Lin for topology analysis. Q.Z. acknowledges AcRF Tier 1 (RG 16/12) and Tier 2 (ARC 2/13 and ARC 20/12) from MOE and the CREATE program (Nanomaterials for Energy and Water Management) from NRF Singapore. This work was also supported by the National Natural Science Foundation of China (Grant 21271009).",

year = "2014",

month = aug,

day = "7",

doi = "10.1021/ic5011133",

language = "English (US)",

volume = "53",

pages = "8529--8537",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "16",

}

TY - JOUR

T1 - Surfactant media to grow new crystalline cobalt 1,3,5-benzenetricarboxylate metal-organic frameworks

AU - Lu, Haisheng

AU - Bai, Linlu

AU - Xiong, Weiwei

AU - Li, Peizhou

AU - Ding, Junfeng

AU - Zhang, Guodong

AU - Wu, Tao

AU - Zhao, Yanli

AU - Lee, Jongmin

AU - Yang, Yanhui

AU - Geng, Baoyou

AU - Zhang, Qichun

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors thank Prof. Tao Wu and Jian Lin for topology analysis. Q.Z. acknowledges AcRF Tier 1 (RG 16/12) and Tier 2 (ARC 2/13 and ARC 20/12) from MOE and the CREATE program (Nanomaterials for Energy and Water Management) from NRF Singapore. This work was also supported by the National Natural Science Foundation of China (Grant 21271009).

PY - 2014/8/7

Y1 - 2014/8/7

N2 - In this report, three new metal-organic frameworks (MOFs), [Co 3(μ3-OH)(HBTC)(BTC)2Co(HBTC)]·(HTEA) 3·H2O (NTU-Z30), [Co(BTC)] ·HTEA·H2O (NTU-Z31), [Co3(BTC) 4]·(HTEA)4 (NTU-Z32), where H3BTC = 1,3,5-benzenetricarboxylic acid, TEA = triethylamine, and NTU = Nanyang Technological University, have been successfully synthesized under surfactant media and have been carefully characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis, and IR spectromtry. NTU-Z30 has an unusual trimeric [Co3(μ3-OH)(COO) 7] secondary building unit (SBU), which is different from the well-known trimeric [Co3O(COO)6] SBU. The topology studies indicate that NTU-Z30 and NTU-Z32 possess two new topologies, 3,3,6,7-c net and 2,8-c net, respectively, while NTU-Z31 has a known topology rtl type (3,6-c net). Magnetic analyses show that all three materials have weak antiferromagnetic behavior. Furthermore, NTU-Z30 has been selected as the heterogeneous catalyst for the aerobic epoxidation of alkene, and our results show that this material exhibits excellent catalytic activity as well as good stability. Our success in growing new crystalline cobalt 1,3,5- benzenetricarboxylate MOFs under surfactant media could pave a new road to preparing new diverse crystalline inorganic materials through a surfactant-thermal method. © 2014 American Chemical Society.

AB - In this report, three new metal-organic frameworks (MOFs), [Co 3(μ3-OH)(HBTC)(BTC)2Co(HBTC)]·(HTEA) 3·H2O (NTU-Z30), [Co(BTC)] ·HTEA·H2O (NTU-Z31), [Co3(BTC) 4]·(HTEA)4 (NTU-Z32), where H3BTC = 1,3,5-benzenetricarboxylic acid, TEA = triethylamine, and NTU = Nanyang Technological University, have been successfully synthesized under surfactant media and have been carefully characterized by single-crystal X-ray diffraction, powder X-ray diffraction, thermogravimetric analysis, and IR spectromtry. NTU-Z30 has an unusual trimeric [Co3(μ3-OH)(COO) 7] secondary building unit (SBU), which is different from the well-known trimeric [Co3O(COO)6] SBU. The topology studies indicate that NTU-Z30 and NTU-Z32 possess two new topologies, 3,3,6,7-c net and 2,8-c net, respectively, while NTU-Z31 has a known topology rtl type (3,6-c net). Magnetic analyses show that all three materials have weak antiferromagnetic behavior. Furthermore, NTU-Z30 has been selected as the heterogeneous catalyst for the aerobic epoxidation of alkene, and our results show that this material exhibits excellent catalytic activity as well as good stability. Our success in growing new crystalline cobalt 1,3,5- benzenetricarboxylate MOFs under surfactant media could pave a new road to preparing new diverse crystalline inorganic materials through a surfactant-thermal method. © 2014 American Chemical Society.

UR - http://hdl.handle.net/10754/563706

UR - https://pubs.acs.org/doi/10.1021/ic5011133

UR - http://www.scopus.com/inward/record.url?scp=84906245625&partnerID=8YFLogxK

U2 - 10.1021/ic5011133

DO - 10.1021/ic5011133

M3 - Article

SN - 0020-1669

VL - 53

SP - 8529

EP - 8537

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 16

ER -

Surfactant media to grow new crystalline cobalt 1,3,5-benzenetricarboxylate metal-organic frameworks

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CCDC 1029960: Experimental Crystal Structure Determination : catena-[triethylammonium (mu-1,3,5-benzenetricarboxylato)-cobalt(ii) monohydrate]

CCDC 1029958: Experimental Crystal Structure Determination : catena-[tetrakis(triethylammonium) tetrakis(mu-1,3,5-benzenetricarboxylato)-tri-cobalt]

CCDC 1029959: Experimental Crystal Structure Determination : catena-[tris(triethylammonium) (mu-hydroxo)-bis(mu-1,3,5-benzenetricarboxylato)-bis(mu-5-carboxybenzene-1,3-dicarboxylato)-tetra-cobalt monohydrate]

Cite this

Surfactant media to grow new crystalline cobalt 1,3,5-benzenetricarboxylate metal-organic frameworks

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1029960: Experimental Crystal Structure Determination : catena-[triethylammonium (mu-1,3,5-benzenetricarboxylato)-cobalt(ii) monohydrate]

CCDC 1029958: Experimental Crystal Structure Determination : catena-[tetrakis(triethylammonium) tetrakis(mu-1,3,5-benzenetricarboxylato)-tri-cobalt]

CCDC 1029959: Experimental Crystal Structure Determination : catena-[tris(triethylammonium) (mu-hydroxo)-bis(mu-1,3,5-benzenetricarboxylato)-bis(mu-5-carboxybenzene-1,3-dicarboxylato)-tetra-cobalt monohydrate]

Cite this