TY - JOUR
T1 - Suzuki-Miyaura cross-coupling reactions in aqueous media: Green and sustainable syntheses of biaryls
AU - Polshettiwar, Vivek
AU - Decottignies, Audrey
AU - Len, Christophe
AU - Fihri, Aziz
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: We thank G. Santini for his support of this work and the Region Picardie for their financial support.
PY - 2010/2/28
Y1 - 2010/2/28
N2 - Carbon-carbon cross-coupling reactions are among the most important processes in organic chemistry, and Suzuki-Miyaura reactions are among the most widely used protocols for the formation of carbon-carbon bonds. These reactions are generally catalyzed by soluble palladium complexes with various ligands. However, the use of toxic organic solvents remains a scientific challenge and an aspect of economical and ecological relevance. This Review will summarize various recently developed significant methods by which the Suzuki-Miyaura coupling was conducted in aqueous media, and analyzes if they are "real green" protocols. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
AB - Carbon-carbon cross-coupling reactions are among the most important processes in organic chemistry, and Suzuki-Miyaura reactions are among the most widely used protocols for the formation of carbon-carbon bonds. These reactions are generally catalyzed by soluble palladium complexes with various ligands. However, the use of toxic organic solvents remains a scientific challenge and an aspect of economical and ecological relevance. This Review will summarize various recently developed significant methods by which the Suzuki-Miyaura coupling was conducted in aqueous media, and analyzes if they are "real green" protocols. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
UR - http://hdl.handle.net/10754/575537
UR - http://doi.wiley.com/10.1002/cssc.200900221
UR - http://www.scopus.com/inward/record.url?scp=77954813245&partnerID=8YFLogxK
U2 - 10.1002/cssc.200900221
DO - 10.1002/cssc.200900221
M3 - Article
C2 - 20191633
SN - 1864-5631
VL - 3
SP - 502
EP - 522
JO - ChemSusChem
JF - ChemSusChem
IS - 5
ER -