Synthesen und kristallstrukturen von Cu- und Ag-komplexen mit dithiophosphinat- und trithiophosphonat-liganden

Dieter Fenske; Alexander Rothenberger; Maryam Shafaei Fallah

doi:10.1002/zaac.200400049

Synthesen und kristallstrukturen von Cu- und Ag-komplexen mit dithiophosphinat- und trithiophosphonat-liganden

Translated title of the contribution: Syntheses and crystal structures of copper and silver complexes containing dithiophosphinato and trithiophosphonato ligands

Dieter Fenske^*, Alexander Rothenberger, Maryam Shafaei Fallah

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

The reactions of Cu¹ and Ag¹ salts with diphenyldithiophosphinic acid trimethylsilylester in the presence of tertiary phosphines yield the complexes [Cu(μ-S)SPPh₂(PR₃)] ₂ (R = Me 1a, ⁱPr 1b), [Ag(μ-S)SPPh₂(P ⁿPr₃)]₂ (2), [Ag(S₂PPh ₂)(PEt₃)]₂ (3), and [Cu₈(μ ₈-S)(S₂PPh₂)₆] (4). The cage complex [(PhPS₃)₂Cu₄(PMe₃)₅] (5) is obtained by the reaction of phenyltrithiophosphonic acid trimethylester. All compounds were structurally characterised by X-ray crystallography.

Translated title of the contribution	Syntheses and crystal structures of copper and silver complexes containing dithiophosphinato and trithiophosphonato ligands
Original language	German
Pages (from-to)	943-947
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	630
Issue number	6
DOIs	https://doi.org/10.1002/zaac.200400049
State	Published - 2004
Externally published	Yes

Keywords

Copper
Crystal structures
P Ligands
S Ligands
Silver

ASJC Scopus subject areas

Inorganic Chemistry

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10.1002/zaac.200400049

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title = "Synthesen und kristallstrukturen von Cu- und Ag-komplexen mit dithiophosphinat- und trithiophosphonat-liganden",

abstract = "The reactions of Cu1 and Ag1 salts with diphenyldithiophosphinic acid trimethylsilylester in the presence of tertiary phosphines yield the complexes [Cu(μ-S)SPPh2(PR3)] 2 (R = Me 1a, iPr 1b), [Ag(μ-S)SPPh2(P nPr3)]2 (2), [Ag(S2PPh 2)(PEt3)]2 (3), and [Cu8(μ 8-S)(S2PPh2)6] (4). The cage complex [(PhPS3)2Cu4(PMe3)5] (5) is obtained by the reaction of phenyltrithiophosphonic acid trimethylester. All compounds were structurally characterised by X-ray crystallography.",

keywords = "Copper, Crystal structures, P Ligands, S Ligands, Silver",

author = "Dieter Fenske and Alexander Rothenberger and Fallah, {Maryam Shafaei}",

year = "2004",

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T1 - Synthesen und kristallstrukturen von Cu- und Ag-komplexen mit dithiophosphinat- und trithiophosphonat-liganden

AU - Fenske, Dieter

AU - Rothenberger, Alexander

AU - Fallah, Maryam Shafaei

PY - 2004

Y1 - 2004

N2 - The reactions of Cu1 and Ag1 salts with diphenyldithiophosphinic acid trimethylsilylester in the presence of tertiary phosphines yield the complexes [Cu(μ-S)SPPh2(PR3)] 2 (R = Me 1a, iPr 1b), [Ag(μ-S)SPPh2(P nPr3)]2 (2), [Ag(S2PPh 2)(PEt3)]2 (3), and [Cu8(μ 8-S)(S2PPh2)6] (4). The cage complex [(PhPS3)2Cu4(PMe3)5] (5) is obtained by the reaction of phenyltrithiophosphonic acid trimethylester. All compounds were structurally characterised by X-ray crystallography.

AB - The reactions of Cu1 and Ag1 salts with diphenyldithiophosphinic acid trimethylsilylester in the presence of tertiary phosphines yield the complexes [Cu(μ-S)SPPh2(PR3)] 2 (R = Me 1a, iPr 1b), [Ag(μ-S)SPPh2(P nPr3)]2 (2), [Ag(S2PPh 2)(PEt3)]2 (3), and [Cu8(μ 8-S)(S2PPh2)6] (4). The cage complex [(PhPS3)2Cu4(PMe3)5] (5) is obtained by the reaction of phenyltrithiophosphonic acid trimethylester. All compounds were structurally characterised by X-ray crystallography.

KW - Copper

KW - Crystal structures

KW - P Ligands

KW - S Ligands

KW - Silver

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DO - 10.1002/zaac.200400049

M3 - Article

AN - SCOPUS:4544239432

SN - 0044-2313

VL - 630

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EP - 947

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 6

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Synthesen und kristallstrukturen von Cu- und Ag-komplexen mit dithiophosphinat- und trithiophosphonat-liganden

Abstract

Keywords

ASJC Scopus subject areas

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