Synthesis and catalytic properties of W(OAr)2Cl 2(CHCMe3)(OR2) and W(OAr) 2Cl(CHCMe3)(CH2CMe3)(OR 2) (Ar = 2,6-disubstituted phenyl; R = Et or Pri), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups

Francoise Quignard; Michel Leconte; Jean Marie Basset

doi:10.1039/c39850001816

Synthesis and catalytic properties of W(OAr)₂Cl ₂(CHCMe₃)(OR₂) and W(OAr) ₂Cl(CHCMe₃)(CH₂CMe₃)(OR ₂) (Ar = 2,6-disubstituted phenyl; R = Et or Prⁱ), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups

Francoise Quignard^*, Michel Leconte, Jean Marie Basset

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

63 Scopus citations

Abstract

The synthesis of W(OAr)₂Cl(CHR)(CH₂R ¹)(OR²₂) (Ar = 2,6-disubstituted phenyl; R ² = Et or Prⁱ) illustrates one of the first examples of a well defined, Lewis acid-free, homogeneous olefin metathesis catalyst, for which the activity and stereoselectivity can be governed by the nature of the aryloxide ligands and of the co-ordinated ether and which shows a wide range of potential applications.

Original language	English (US)
Pages (from-to)	1816-1817
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/c39850001816
State	Published - 1985
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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Quignard, F., Leconte, M., & Basset, J. M. (1985). Synthesis and catalytic properties of W(OAr)₂Cl ₂(CHCMe₃)(OR₂) and W(OAr) ₂Cl(CHCMe₃)(CH₂CMe₃)(OR ₂) (Ar = 2,6-disubstituted phenyl; R = Et or Prⁱ), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups. Journal of the Chemical Society, Chemical Communications, (24), 1816-1817. https://doi.org/10.1039/c39850001816

Quignard, Francoise ; Leconte, Michel ; Basset, Jean Marie. / Synthesis and catalytic properties of W(OAr)₂Cl ₂(CHCMe₃)(OR₂) and W(OAr) ₂Cl(CHCMe₃)(CH₂CMe₃)(OR ₂) (Ar = 2,6-disubstituted phenyl; R = Et or Prⁱ), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups. In: Journal of the Chemical Society, Chemical Communications. 1985 ; No. 24. pp. 1816-1817.

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title = "Synthesis and catalytic properties of W(OAr)2Cl 2(CHCMe3)(OR2) and W(OAr) 2Cl(CHCMe3)(CH2CMe3)(OR 2) (Ar = 2,6-disubstituted phenyl; R = Et or Pri), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups",

abstract = "The synthesis of W(OAr)2Cl(CHR)(CH2R 1)(OR22) (Ar = 2,6-disubstituted phenyl; R 2 = Et or Pri) illustrates one of the first examples of a well defined, Lewis acid-free, homogeneous olefin metathesis catalyst, for which the activity and stereoselectivity can be governed by the nature of the aryloxide ligands and of the co-ordinated ether and which shows a wide range of potential applications.",

author = "Francoise Quignard and Michel Leconte and Basset, {Jean Marie}",

year = "1985",

doi = "10.1039/c39850001816",

language = "English (US)",

pages = "1816--1817",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "24",

}

Quignard, F, Leconte, M & Basset, JM 1985, 'Synthesis and catalytic properties of W(OAr)₂Cl ₂(CHCMe₃)(OR₂) and W(OAr) ₂Cl(CHCMe₃)(CH₂CMe₃)(OR ₂) (Ar = 2,6-disubstituted phenyl; R = Et or Prⁱ), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups', Journal of the Chemical Society, Chemical Communications, no. 24, pp. 1816-1817. https://doi.org/10.1039/c39850001816

Synthesis and catalytic properties of W(OAr)₂Cl ₂(CHCMe₃)(OR₂) and W(OAr) ₂Cl(CHCMe₃)(CH₂CMe₃)(OR ₂) (Ar = 2,6-disubstituted phenyl; R = Et or Prⁱ), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups. / Quignard, Francoise; Leconte, Michel; Basset, Jean Marie.
In: Journal of the Chemical Society, Chemical Communications, No. 24, 1985, p. 1816-1817.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and catalytic properties of W(OAr)2Cl 2(CHCMe3)(OR2) and W(OAr) 2Cl(CHCMe3)(CH2CMe3)(OR 2) (Ar = 2,6-disubstituted phenyl; R = Et or Pri), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups

AU - Quignard, Francoise

AU - Leconte, Michel

AU - Basset, Jean Marie

PY - 1985

Y1 - 1985

N2 - The synthesis of W(OAr)2Cl(CHR)(CH2R 1)(OR22) (Ar = 2,6-disubstituted phenyl; R 2 = Et or Pri) illustrates one of the first examples of a well defined, Lewis acid-free, homogeneous olefin metathesis catalyst, for which the activity and stereoselectivity can be governed by the nature of the aryloxide ligands and of the co-ordinated ether and which shows a wide range of potential applications.

AB - The synthesis of W(OAr)2Cl(CHR)(CH2R 1)(OR22) (Ar = 2,6-disubstituted phenyl; R 2 = Et or Pri) illustrates one of the first examples of a well defined, Lewis acid-free, homogeneous olefin metathesis catalyst, for which the activity and stereoselectivity can be governed by the nature of the aryloxide ligands and of the co-ordinated ether and which shows a wide range of potential applications.

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U2 - 10.1039/c39850001816

DO - 10.1039/c39850001816

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SN - 0022-4936

SP - 1816

EP - 1817

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

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ER -

Quignard F, Leconte M, Basset JM. Synthesis and catalytic properties of W(OAr)₂Cl ₂(CHCMe₃)(OR₂) and W(OAr) ₂Cl(CHCMe₃)(CH₂CMe₃)(OR ₂) (Ar = 2,6-disubstituted phenyl; R = Et or Prⁱ), new uni-component catalysts for metathesis of acyclic and cyclic olefins, with or without functional groups. Journal of the Chemical Society, Chemical Communications. 1985;(24):1816-1817. doi: 10.1039/c39850001816