TY - JOUR
T1 - Synthesis and Characterization of Cationic Tetramethyl Tantalum(V) Complex
AU - Dey, Raju
AU - Mohandas, Janet Chakkamadathil
AU - Samantaray, Manoja
AU - Hamieh, Ali Imad Ali
AU - Kavitake, Santosh Giridhar
AU - Chen, Yin
AU - Abou-Hamad, Edy
AU - Cavallo, Luigi
AU - Poater, Albert
AU - Basset, Jean-Marie
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: This work was supported by funds from King Abdullah University of Science and Technology (KAUST) office of sponsored research (OSR). R.D. thanks National Institute of Technology, Calicut for financial support. A.P. thanks the Spanish MINECO for a project CTQ2014-59832-JIN. The authors acknowledge the KAUST Nuclear Magnetic Resonance Core Lab and the technical assistance of Xianrong Guo.
PY - 2018/11/1
Y1 - 2018/11/1
N2 - A novel method for the synthesis of the homogeneous homoleptic cationic tantalum(V)tetramethyl complex [(TaMe4)+ MeB(C6F5)3−] from neutral tantalumpentamethyl (TaMe5) has been described, by direct demethylation using B(C6F5)3 reagent. The aforesaid higher valent cationic tantalum complex was characterized precisely by liquid state 1H-NMR, 13C-NMR, and 1H-13C-NMR correlation spectroscopy.
AB - A novel method for the synthesis of the homogeneous homoleptic cationic tantalum(V)tetramethyl complex [(TaMe4)+ MeB(C6F5)3−] from neutral tantalumpentamethyl (TaMe5) has been described, by direct demethylation using B(C6F5)3 reagent. The aforesaid higher valent cationic tantalum complex was characterized precisely by liquid state 1H-NMR, 13C-NMR, and 1H-13C-NMR correlation spectroscopy.
UR - http://hdl.handle.net/10754/629596
UR - https://www.mdpi.com/2073-4344/8/11/507
UR - http://www.scopus.com/inward/record.url?scp=85056362874&partnerID=8YFLogxK
U2 - 10.3390/catal8110507
DO - 10.3390/catal8110507
M3 - Article
SN - 2073-4344
VL - 8
SP - 507
JO - Catalysts
JF - Catalysts
IS - 11
ER -