Synthesis and characterization of diaminodithio- and aminotrithiophosphoric acid esters

Patrice Marchand; Anca Meffre; Bruno Donnadieu; Daniel Taton; Yves Gnanou; Mathias Destarac; Frédéric Leising; Anne Marie Caminade; Jean Pierre Majoral

doi:10.1080/10426500601160694

Synthesis and characterization of diaminodithio- and aminotrithiophosphoric acid esters

Patrice Marchand, Anca Meffre, Bruno Donnadieu, Daniel Taton, Yves Gnanou, Mathias Destarac, Frédéric Leising, Anne Marie Caminade^*, Jean Pierre Majoral

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The synthesis and characterization of a series of five new diaminodithiophosphoric acid esters (R1R2N)2P(S)SR and five new aminotrithiophosphoric acid esters (R1R2N)P(S)(SR)2 are described. The structure of two of these compounds, the diaminodithio derivative (iPr2N)2P(S)SCH2Ph and the aminotrithio derivative (iPr2N)P(S)(SCH2Ph)2, has been determined by single crystal X-ray diffraction. These series of compounds are potentially usable as agents for reversible addition-fragmentation chain transfer polymerization.

Original language	English (US)
Pages (from-to)	1233-1244
Number of pages	12
Journal	Phosphorus, Sulfur and Silicon and the Related Elements
Volume	182
Issue number	6
DOIs	https://doi.org/10.1080/10426500601160694
State	Published - Jun 2007
Externally published	Yes

Keywords

Amines
Aminotrithiophosphoric acid esters
Diaminodithiophosphoric acid esters
Reversible addition-fragmentation chain transfer (RAFT) agents
Thiols

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Inorganic Chemistry

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10.1080/10426500601160694

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title = "Synthesis and characterization of diaminodithio- and aminotrithiophosphoric acid esters",

abstract = "The synthesis and characterization of a series of five new diaminodithiophosphoric acid esters (R1R2N)2P(S)SR and five new aminotrithiophosphoric acid esters (R1R2N)P(S)(SR)2 are described. The structure of two of these compounds, the diaminodithio derivative (iPr2N)2P(S)SCH2Ph and the aminotrithio derivative (iPr2N)P(S)(SCH2Ph)2, has been determined by single crystal X-ray diffraction. These series of compounds are potentially usable as agents for reversible addition-fragmentation chain transfer polymerization.",

keywords = "Amines, Aminotrithiophosphoric acid esters, Diaminodithiophosphoric acid esters, Reversible addition-fragmentation chain transfer (RAFT) agents, Thiols",

author = "Patrice Marchand and Anca Meffre and Bruno Donnadieu and Daniel Taton and Yves Gnanou and Mathias Destarac and Fr{\'e}d{\'e}ric Leising and Caminade, {Anne Marie} and Majoral, {Jean Pierre}",

year = "2007",

month = jun,

doi = "10.1080/10426500601160694",

language = "English (US)",

volume = "182",

pages = "1233--1244",

journal = "Phosphorus, Sulfur and Silicon and the Related Elements",

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publisher = "Taylor & Francis",

number = "6",

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TY - JOUR

T1 - Synthesis and characterization of diaminodithio- and aminotrithiophosphoric acid esters

AU - Marchand, Patrice

AU - Meffre, Anca

AU - Donnadieu, Bruno

AU - Taton, Daniel

AU - Gnanou, Yves

AU - Destarac, Mathias

AU - Leising, Frédéric

AU - Caminade, Anne Marie

AU - Majoral, Jean Pierre

PY - 2007/6

Y1 - 2007/6

N2 - The synthesis and characterization of a series of five new diaminodithiophosphoric acid esters (R1R2N)2P(S)SR and five new aminotrithiophosphoric acid esters (R1R2N)P(S)(SR)2 are described. The structure of two of these compounds, the diaminodithio derivative (iPr2N)2P(S)SCH2Ph and the aminotrithio derivative (iPr2N)P(S)(SCH2Ph)2, has been determined by single crystal X-ray diffraction. These series of compounds are potentially usable as agents for reversible addition-fragmentation chain transfer polymerization.

AB - The synthesis and characterization of a series of five new diaminodithiophosphoric acid esters (R1R2N)2P(S)SR and five new aminotrithiophosphoric acid esters (R1R2N)P(S)(SR)2 are described. The structure of two of these compounds, the diaminodithio derivative (iPr2N)2P(S)SCH2Ph and the aminotrithio derivative (iPr2N)P(S)(SCH2Ph)2, has been determined by single crystal X-ray diffraction. These series of compounds are potentially usable as agents for reversible addition-fragmentation chain transfer polymerization.

KW - Amines

KW - Aminotrithiophosphoric acid esters

KW - Diaminodithiophosphoric acid esters

KW - Reversible addition-fragmentation chain transfer (RAFT) agents

KW - Thiols

UR - http://www.scopus.com/inward/record.url?scp=34247477645&partnerID=8YFLogxK

U2 - 10.1080/10426500601160694

DO - 10.1080/10426500601160694

M3 - Article

AN - SCOPUS:34247477645

SN - 1042-6507

VL - 182

SP - 1233

EP - 1244

JO - Phosphorus, Sulfur and Silicon and the Related Elements

JF - Phosphorus, Sulfur and Silicon and the Related Elements

IS - 6

ER -

Synthesis and characterization of diaminodithio- and aminotrithiophosphoric acid esters

Abstract

Keywords

ASJC Scopus subject areas

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