Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups

Chun Qing Liu; Yang Liu; Ping Xie; Rong Ben Zhang; Chao Bin He; Neal Tai Shung Chung

Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups

Chun Qing Liu, Yang Liu, Ping Xie, Rong Ben Zhang^*, Chao Bin He, Neal Tai Shung Chung

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer, 3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS), was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp₂PtCl₂) catalyst in high yield. The synthesized polynitroorganosiloxane, which has potential application as a precursor for synthesizing advanced functional polymers, was characterized by FTIR, ¹H-NMR, ¹³C-NMR, ²⁹Si-NMR, vapor pressure osmometry (VPO) and gel permeation chromatography (GPC).

Original language	English (US)
Pages (from-to)	1-6
Number of pages	6
Journal	Chinese Journal of Polymer Science (English Edition)
Volume	19
Issue number	1
State	Published - 2001
Externally published	Yes

Keywords

Characterization
Equilibration polymerization
Hydrosilylation
Polyorganosiloxane

ASJC Scopus subject areas

General Chemical Engineering
Polymers and Plastics
Organic Chemistry

Cite this

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title = "Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups",

abstract = "A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer, 3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS), was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtCl2) catalyst in high yield. The synthesized polynitroorganosiloxane, which has potential application as a precursor for synthesizing advanced functional polymers, was characterized by FTIR, 1H-NMR, 13C-NMR, 29Si-NMR, vapor pressure osmometry (VPO) and gel permeation chromatography (GPC).",

keywords = "Characterization, Equilibration polymerization, Hydrosilylation, Polyorganosiloxane",

author = "Liu, {Chun Qing} and Yang Liu and Ping Xie and Zhang, {Rong Ben} and He, {Chao Bin} and Chung, {Neal Tai Shung}",

year = "2001",

language = "English (US)",

volume = "19",

pages = "1--6",

journal = "Chinese Journal of Polymer Science (English Edition)",

issn = "0256-7679",

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TY - JOUR

T1 - Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups

AU - Liu, Chun Qing

AU - Liu, Yang

AU - Xie, Ping

AU - Zhang, Rong Ben

AU - He, Chao Bin

AU - Chung, Neal Tai Shung

PY - 2001

Y1 - 2001

N2 - A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer, 3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS), was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtCl2) catalyst in high yield. The synthesized polynitroorganosiloxane, which has potential application as a precursor for synthesizing advanced functional polymers, was characterized by FTIR, 1H-NMR, 13C-NMR, 29Si-NMR, vapor pressure osmometry (VPO) and gel permeation chromatography (GPC).

AB - A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer, 3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS), was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtCl2) catalyst in high yield. The synthesized polynitroorganosiloxane, which has potential application as a precursor for synthesizing advanced functional polymers, was characterized by FTIR, 1H-NMR, 13C-NMR, 29Si-NMR, vapor pressure osmometry (VPO) and gel permeation chromatography (GPC).

KW - Characterization

KW - Equilibration polymerization

KW - Hydrosilylation

KW - Polyorganosiloxane

UR - http://www.scopus.com/inward/record.url?scp=0035579040&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0035579040

SN - 0256-7679

VL - 19

SP - 1

EP - 6

JO - Chinese Journal of Polymer Science (English Edition)

JF - Chinese Journal of Polymer Science (English Edition)

IS - 1

ER -

Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups

Abstract

Keywords

ASJC Scopus subject areas

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