TY - JOUR
T1 - Synthesis and characterization of star polymers initiated by hexafunctional discotic initiator through atom transfer radical polymerization
AU - Feng, Xiao Shuang
AU - Pan, Cai Yuan
N1 - Generated from Scopus record by KAUST IRTS on 2023-09-21
PY - 2001/7/1
Y1 - 2001/7/1
N2 - A novel hexafunctional discotic initiator, 2,3,6,7,11,12-hexakis(2-bromobutyryloxy)triphenylene was synthesized by the esterification of 2,3,6,7,11,12-hexahydroxytriphenylene with 2-bromobutyryl chloride. Atom transfer radical polymerizations of styrene, methyl acrylate, and n-butyl acrylate were carried out in 50 vol % tetrahydrofuran with HBTP/copper(I) bromide/2,2′-bipyridyl as an initiation system. The polymers produced had well-controlled molecular weights and narrow molecular weight distributions (
AB - A novel hexafunctional discotic initiator, 2,3,6,7,11,12-hexakis(2-bromobutyryloxy)triphenylene was synthesized by the esterification of 2,3,6,7,11,12-hexahydroxytriphenylene with 2-bromobutyryl chloride. Atom transfer radical polymerizations of styrene, methyl acrylate, and n-butyl acrylate were carried out in 50 vol % tetrahydrofuran with HBTP/copper(I) bromide/2,2′-bipyridyl as an initiation system. The polymers produced had well-controlled molecular weights and narrow molecular weight distributions (
UR - https://onlinelibrary.wiley.com/doi/10.1002/pola.1200
UR - http://www.scopus.com/inward/record.url?scp=0035398383&partnerID=8YFLogxK
U2 - 10.1002/pola.1200
DO - 10.1002/pola.1200
M3 - Article
SN - 0887-624X
VL - 39
SP - 2233
EP - 2243
JO - Journal of Polymer Science, Part A: Polymer Chemistry
JF - Journal of Polymer Science, Part A: Polymer Chemistry
IS - 13
ER -