Synthesis and crystal structure of a new metal-organic coordination polymer [Fe(4,4′-bpy)3(H2O)2] (PF6)2·2(4,4′-bpy)·5 H 2O with nanosized channels clathrate large organic molecules

Natalia V. Izarova; Maxim N. Sokolov; Alexander Rothenberger; Lukasz Ponikiewski; Dieter Fenske; Vladimir P. Fedin

doi:10.1016/j.crci.2004.11.006

Synthesis and crystal structure of a new metal-organic coordination polymer [Fe(4,4′-bpy)₃(H₂O)₂] (PF₆)₂·2(4,4′-bpy)·5 H ₂O with nanosized channels clathrate large organic molecules

Natalia V. Izarova, Maxim N. Sokolov, Alexander Rothenberger, Lukasz Ponikiewski, Dieter Fenske, Vladimir P. Fedin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A new metal-organic coordination polymer [Fe(4,4′-bpy)₃ (H₂O)₂](PF₆)₂ ·2(4,4′-bpy)·5 H₂O (1) (bpy = bipyridine) was prepared. X-ray structural analysis reveals that 1 is a three-dimensional network with nanosized channels constructed from one-dimensional coordination chains via non-covalent interactions between the pyridile rings. The channels clathrate large molecules of free 4,4′-bpy. Magnetic susceptibility measurement confirms the presence of isolated high-spin Fe(II) in 1.

Original language	English (US)
Pages (from-to)	1005-1010
Number of pages	6
Journal	Comptes Rendus Chimie
Volume	8
Issue number	6-7 SPEC. ISS.
DOIs	https://doi.org/10.1016/j.crci.2004.11.006
State	Published - Jun 2005
Externally published	Yes

Keywords

4,4′-Bipyridine
Coordination polymer
Crystal structure
Iron(II)
Supramolecular chemistry

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering

Access to Document

10.1016/j.crci.2004.11.006

Cite this

Izarova, N. V., Sokolov, M. N., Rothenberger, A., Ponikiewski, L., Fenske, D., & Fedin, V. P. (2005). Synthesis and crystal structure of a new metal-organic coordination polymer [Fe(4,4′-bpy)₃(H₂O)₂] (PF₆)₂·2(4,4′-bpy)·5 H ₂O with nanosized channels clathrate large organic molecules. Comptes Rendus Chimie, 8(6-7 SPEC. ISS.), 1005-1010. https://doi.org/10.1016/j.crci.2004.11.006

@article{6d421fec1a4e4830ae66f11e3f882ef2,

title = "Synthesis and crystal structure of a new metal-organic coordination polymer [Fe(4,4′-bpy)3(H2O)2] (PF6)2·2(4,4′-bpy)·5 H 2O with nanosized channels clathrate large organic molecules",

abstract = "A new metal-organic coordination polymer [Fe(4,4′-bpy)3 (H2O)2](PF6)2 ·2(4,4′-bpy)·5 H2O (1) (bpy = bipyridine) was prepared. X-ray structural analysis reveals that 1 is a three-dimensional network with nanosized channels constructed from one-dimensional coordination chains via non-covalent interactions between the pyridile rings. The channels clathrate large molecules of free 4,4′-bpy. Magnetic susceptibility measurement confirms the presence of isolated high-spin Fe(II) in 1.",

keywords = "4,4′-Bipyridine, Coordination polymer, Crystal structure, Iron(II), Supramolecular chemistry",

author = "Izarova, {Natalia V.} and Sokolov, {Maxim N.} and Alexander Rothenberger and Lukasz Ponikiewski and Dieter Fenske and Fedin, {Vladimir P.}",

year = "2005",

month = jun,

doi = "10.1016/j.crci.2004.11.006",

language = "English (US)",

volume = "8",

pages = "1005--1010",

journal = "Comptes Rendus Chimie",

issn = "1631-0748",

publisher = "Elsevier Masson",

number = "6-7 SPEC. ISS.",

}

Izarova, NV, Sokolov, MN, Rothenberger, A, Ponikiewski, L, Fenske, D & Fedin, VP 2005, 'Synthesis and crystal structure of a new metal-organic coordination polymer [Fe(4,4′-bpy)₃(H₂O)₂] (PF₆)₂·2(4,4′-bpy)·5 H ₂O with nanosized channels clathrate large organic molecules', Comptes Rendus Chimie, vol. 8, no. 6-7 SPEC. ISS., pp. 1005-1010. https://doi.org/10.1016/j.crci.2004.11.006

Synthesis and crystal structure of a new metal-organic coordination polymer [Fe(4,4′-bpy)₃(H₂O)₂] (PF₆)₂·2(4,4′-bpy)·5 H ₂O with nanosized channels clathrate large organic molecules. / Izarova, Natalia V.; Sokolov, Maxim N.; Rothenberger, Alexander et al.
In: Comptes Rendus Chimie, Vol. 8, No. 6-7 SPEC. ISS., 06.2005, p. 1005-1010.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and crystal structure of a new metal-organic coordination polymer [Fe(4,4′-bpy)3(H2O)2] (PF6)2·2(4,4′-bpy)·5 H 2O with nanosized channels clathrate large organic molecules

AU - Izarova, Natalia V.

AU - Sokolov, Maxim N.

AU - Rothenberger, Alexander

AU - Ponikiewski, Lukasz

AU - Fenske, Dieter

AU - Fedin, Vladimir P.

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AB - A new metal-organic coordination polymer [Fe(4,4′-bpy)3 (H2O)2](PF6)2 ·2(4,4′-bpy)·5 H2O (1) (bpy = bipyridine) was prepared. X-ray structural analysis reveals that 1 is a three-dimensional network with nanosized channels constructed from one-dimensional coordination chains via non-covalent interactions between the pyridile rings. The channels clathrate large molecules of free 4,4′-bpy. Magnetic susceptibility measurement confirms the presence of isolated high-spin Fe(II) in 1.

KW - 4,4′-Bipyridine

KW - Coordination polymer

KW - Crystal structure

KW - Iron(II)

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