Synthesis and crystal structures of octahedral metal complexes containing the new dianion [PhP(Se,O)Se-Se(O,Se)PPh]2-

Weifeng Shi; Le Zhang; Maryam Shafaei-Fallah; Alexander Rothenberger

doi:10.1002/zaac.200600297

Synthesis and crystal structures of octahedral metal complexes containing the new dianion [PhP(Se,O)Se-Se(O,Se)PPh]^2-

Weifeng Shi^*, Le Zhang, Maryam Shafaei-Fallah, Alexander Rothenberger

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

The synthesis and structures of three new compounds are reported. [Mg ₂{PhP(Se,O)Se-Se(O,Se)PPh}₂(thf)₇(H ₂O)₃] (1), [Mg{PhP(Se,O)Se-Se(O,Se)PPh}(thf) ₃(H₂O)] (2), and [Mn{PhP(Se,O)Se-Se(O,Se)PPh}(thf) ₃(H₂O)] (3) were prepared by treatment of Woollins' reagent [PhP(Se)(μ-Se)]₂ with the corresponding hydrated metal acetates.

Original language	English (US)
Pages (from-to)	440-442
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	633
Issue number	3
DOIs	https://doi.org/10.1002/zaac.200600297
State	Published - Mar 5 2007

Keywords

Crystal structure
Magnesium
Manganese
Phosphorus
Selenium

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/zaac.200600297

Cite this

@article{4dfc267978c34737b4987f3fb55de14f,

title = "Synthesis and crystal structures of octahedral metal complexes containing the new dianion [PhP(Se,O)Se-Se(O,Se)PPh]2-",

abstract = "The synthesis and structures of three new compounds are reported. [Mg 2{PhP(Se,O)Se-Se(O,Se)PPh}2(thf)7(H 2O)3] (1), [Mg{PhP(Se,O)Se-Se(O,Se)PPh}(thf) 3(H2O)] (2), and [Mn{PhP(Se,O)Se-Se(O,Se)PPh}(thf) 3(H2O)] (3) were prepared by treatment of Woollins' reagent [PhP(Se)(μ-Se)]2 with the corresponding hydrated metal acetates.",

keywords = "Crystal structure, Magnesium, Manganese, Phosphorus, Selenium",

author = "Weifeng Shi and Le Zhang and Maryam Shafaei-Fallah and Alexander Rothenberger",

year = "2007",

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language = "English (US)",

volume = "633",

pages = "440--442",

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TY - JOUR

T1 - Synthesis and crystal structures of octahedral metal complexes containing the new dianion [PhP(Se,O)Se-Se(O,Se)PPh]2-

AU - Shi, Weifeng

AU - Zhang, Le

AU - Shafaei-Fallah, Maryam

AU - Rothenberger, Alexander

PY - 2007/3/5

Y1 - 2007/3/5

N2 - The synthesis and structures of three new compounds are reported. [Mg 2{PhP(Se,O)Se-Se(O,Se)PPh}2(thf)7(H 2O)3] (1), [Mg{PhP(Se,O)Se-Se(O,Se)PPh}(thf) 3(H2O)] (2), and [Mn{PhP(Se,O)Se-Se(O,Se)PPh}(thf) 3(H2O)] (3) were prepared by treatment of Woollins' reagent [PhP(Se)(μ-Se)]2 with the corresponding hydrated metal acetates.

AB - The synthesis and structures of three new compounds are reported. [Mg 2{PhP(Se,O)Se-Se(O,Se)PPh}2(thf)7(H 2O)3] (1), [Mg{PhP(Se,O)Se-Se(O,Se)PPh}(thf) 3(H2O)] (2), and [Mn{PhP(Se,O)Se-Se(O,Se)PPh}(thf) 3(H2O)] (3) were prepared by treatment of Woollins' reagent [PhP(Se)(μ-Se)]2 with the corresponding hydrated metal acetates.

KW - Crystal structure

KW - Magnesium

KW - Manganese

KW - Phosphorus

KW - Selenium

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