TY - JOUR
T1 - Synthesis and immobilization of polystyreneb-polyvinyltriethoxysilane micelles
AU - Zhu, Saisai
AU - Zhu, Hui
AU - Xia, Ru
AU - Feng, Xiaoshuang
AU - Chen, Peng
AU - Qian, Jiasheng
AU - Cao, Ming
AU - Yang, Bin
AU - Miao, Jibin
AU - Su, Lifen
AU - Song, Changjiang
N1 - KAUST Repository Item: Exported on 2020-10-01
Acknowledgements: Funded by the National Natural Science Foundation of China (Nos. 51403001, 20804001, 20974001, 21174001, 51273001), the Research Fund for the Doctoral Program of Higher Education of China (No.20113401110003), “211 Project” and “Incubation Fund for Excellent Young Researcher” of Anhui University
PY - 2018/1/31
Y1 - 2018/1/31
N2 - Diblock copolymers polystyrene-block-polyvinyltriethoxysilane (PS-b-PVTES) were synthesized via atom transfer radical polymerization (ATRP), which self-assembled into spherical micelles in solvent of THF-methanol mixtures. The self-assembled micelles were immobilized by cross-linking reaction of VTES in a shell layer of micelles. The chemical structures of block copolymers and morphology of micelles were characterized in detail. It was found that the size of immobilized micelles was strongly affected by the copolymer concentration, composition of mixture solvent, and block ratios.
AB - Diblock copolymers polystyrene-block-polyvinyltriethoxysilane (PS-b-PVTES) were synthesized via atom transfer radical polymerization (ATRP), which self-assembled into spherical micelles in solvent of THF-methanol mixtures. The self-assembled micelles were immobilized by cross-linking reaction of VTES in a shell layer of micelles. The chemical structures of block copolymers and morphology of micelles were characterized in detail. It was found that the size of immobilized micelles was strongly affected by the copolymer concentration, composition of mixture solvent, and block ratios.
UR - http://hdl.handle.net/10754/627280
UR - http://link.springer.com/article/10.1007/s11595-018-1809-9
UR - http://www.scopus.com/inward/record.url?scp=85041289928&partnerID=8YFLogxK
U2 - 10.1007/s11595-018-1809-9
DO - 10.1007/s11595-018-1809-9
M3 - Article
SN - 1000-2413
VL - 33
SP - 221
EP - 225
JO - Journal of Wuhan University of Technology-Mater. Sci. Ed.
JF - Journal of Wuhan University of Technology-Mater. Sci. Ed.
IS - 1
ER -