Synthesis and Reactivity of [Au(NHC)(Bpin)] Complexes

Steven P Nolan; Caroline Zinser; Laura Falivene; Fady Nahra; Marcel Brill; David Bradford Cordes; Alexandra Slawin; Luigi Cavallo; Catherine Cazin

doi:10.1039/c9cc03171e

Synthesis and Reactivity of [Au(NHC)(Bpin)] Complexes

Steven P Nolan, Caroline Zinser, Laura Falivene, Fady Nahra, Marcel Brill, David Bradford Cordes, Alexandra Slawin, Luigi Cavallo, Catherine Cazin

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.

Original language	English (US)
Pages (from-to)	6799-6802
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	47
DOIs	https://doi.org/10.1039/c9cc03171e
State	Published - 2019

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10.1039/c9cc03171e

https://repository.kaust.edu.sa/bitstream/10754/652936/1/c9cc03171e.pdf

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@article{ccd58fe876f34f2b9a842af1041104a9,

title = "Synthesis and Reactivity of [Au(NHC)(Bpin)] Complexes",

abstract = "A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.",

author = "Nolan, {Steven P} and Caroline Zinser and Laura Falivene and Fady Nahra and Marcel Brill and Cordes, {David Bradford} and Alexandra Slawin and Luigi Cavallo and Catherine Cazin",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): OSR-2015-CCF-1974-03 Acknowledgements: The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), AstraZeneca (Studenship to C.M.Z) and VLAIO (CO2PERATE) for support of this work. We thank King Saud University (DSF Program) and KAUST (Award No.OSR-2015-CCF-1974-03) for support.",

year = "2019",

doi = "10.1039/c9cc03171e",

language = "English (US)",

volume = "55",

pages = "6799--6802",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "47",

}

TY - JOUR

T1 - Synthesis and Reactivity of [Au(NHC)(Bpin)] Complexes

AU - Nolan, Steven P

AU - Zinser, Caroline

AU - Falivene, Laura

AU - Nahra, Fady

AU - Brill, Marcel

AU - Cordes, David Bradford

AU - Slawin, Alexandra

AU - Cavallo, Luigi

AU - Cazin, Catherine

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): OSR-2015-CCF-1974-03 Acknowledgements: The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), AstraZeneca (Studenship to C.M.Z) and VLAIO (CO2PERATE) for support of this work. We thank King Saud University (DSF Program) and KAUST (Award No.OSR-2015-CCF-1974-03) for support.

PY - 2019

Y1 - 2019

N2 - A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.

AB - A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.

UR - http://hdl.handle.net/10754/652936

UR - https://pubs.rsc.org/en/Content/ArticleLanding/2019/CC/C9CC03171E#!divAbstract

UR - http://www.scopus.com/inward/record.url?scp=85067074480&partnerID=8YFLogxK

U2 - 10.1039/c9cc03171e

DO - 10.1039/c9cc03171e

M3 - Article

C2 - 31123732

SN - 1359-7345

VL - 55

SP - 6799

EP - 6802

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

Synthesis and Reactivity of [Au(NHC)(Bpin)] Complexes

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CCDC 1838597: Experimental Crystal Structure Determination : {1,3-bis[2,6-bis(propan-2-yl)phenyl]-2,3-dihydro-1H-imidazol-2-ylidene}-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-gold tetrahydrofuran solvate

CCDC 1838600: Experimental Crystal Structure Determination : (mu-hydrido)-bis(1,3-bis[2,6-bis(propan-2-yl)phenyl]-2,3-dihydro-1H-imidazol-2-ylidene)-di-gold [2,3-dimethylbutane-2,3-diolato]bis(formato)borate formic acid solvate

CCDC 1838599: Experimental Crystal Structure Determination : {1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]-2,3-dihydro-1H-imidazol-2-ylidene}-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-gold

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Synthesis and Reactivity of [Au(NHC)(Bpin)] Complexes

Abstract

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CCDC 1838597: Experimental Crystal Structure Determination : {1,3-bis[2,6-bis(propan-2-yl)phenyl]-2,3-dihydro-1H-imidazol-2-ylidene}-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-gold tetrahydrofuran solvate

CCDC 1838600: Experimental Crystal Structure Determination : (mu-hydrido)-bis(1,3-bis[2,6-bis(propan-2-yl)phenyl]-2,3-dihydro-1H-imidazol-2-ylidene)-di-gold [2,3-dimethylbutane-2,3-diolato]bis(formato)borate formic acid solvate

CCDC 1838599: Experimental Crystal Structure Determination : {1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]-2,3-dihydro-1H-imidazol-2-ylidene}-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-gold

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