Synthesis and structure of homochiral polymeric praseodymium tartrate

M. S. Zavakhina; M. P. Yutkin; D. G. Samsonenko; D. N. Dybtsev; V. P. Fedin

doi:10.1007/s11172-011-0373-7

Synthesis and structure of homochiral polymeric praseodymium tartrate

M. S. Zavakhina, M. P. Yutkin, D. G. Samsonenko, D. N. Dybtsev, V. P. Fedin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The homochiral metal-organic coordination polymer of the composition [{Pr(H ₂O) ₂} ₂-(D-tart) ₃] ·H ₂O was synthesized by heating an aqueous solution of praseodymium(III) chloride and d-tartaric acid (D-H ₂tart) in the presence of KOH. The crystal structure of the polymer was determined by X-ray crystallography and confirmed by IR spectroscopy, thermogravimetry, and elemental analysis.

Original language	English (US)
Pages (from-to)	2425-2428
Number of pages	4
Journal	Russian Chemical Bulletin
Volume	60
Issue number	11
DOIs	https://doi.org/10.1007/s11172-011-0373-7
State	Published - Nov 2011
Externally published	Yes

Keywords

X-ray crystallography
chiral complexes
coordination polymers
praseodymium(III) complexes
tartaric acid

ASJC Scopus subject areas

General Chemistry

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10.1007/s11172-011-0373-7

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title = "Synthesis and structure of homochiral polymeric praseodymium tartrate",

abstract = "The homochiral metal-organic coordination polymer of the composition [{Pr(H 2O) 2} 2-(D-tart) 3] ·H 2O was synthesized by heating an aqueous solution of praseodymium(III) chloride and d-tartaric acid (D-H 2tart) in the presence of KOH. The crystal structure of the polymer was determined by X-ray crystallography and confirmed by IR spectroscopy, thermogravimetry, and elemental analysis.",

keywords = "X-ray crystallography, chiral complexes, coordination polymers, praseodymium(III) complexes, tartaric acid",

author = "Zavakhina, {M. S.} and Yutkin, {M. P.} and Samsonenko, {D. G.} and Dybtsev, {D. N.} and Fedin, {V. P.}",

year = "2011",

month = nov,

doi = "10.1007/s11172-011-0373-7",

language = "English (US)",

volume = "60",

pages = "2425--2428",

journal = "Russian Chemical Bulletin",

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TY - JOUR

T1 - Synthesis and structure of homochiral polymeric praseodymium tartrate

AU - Zavakhina, M. S.

AU - Yutkin, M. P.

AU - Samsonenko, D. G.

AU - Dybtsev, D. N.

AU - Fedin, V. P.

PY - 2011/11

Y1 - 2011/11

N2 - The homochiral metal-organic coordination polymer of the composition [{Pr(H 2O) 2} 2-(D-tart) 3] ·H 2O was synthesized by heating an aqueous solution of praseodymium(III) chloride and d-tartaric acid (D-H 2tart) in the presence of KOH. The crystal structure of the polymer was determined by X-ray crystallography and confirmed by IR spectroscopy, thermogravimetry, and elemental analysis.

AB - The homochiral metal-organic coordination polymer of the composition [{Pr(H 2O) 2} 2-(D-tart) 3] ·H 2O was synthesized by heating an aqueous solution of praseodymium(III) chloride and d-tartaric acid (D-H 2tart) in the presence of KOH. The crystal structure of the polymer was determined by X-ray crystallography and confirmed by IR spectroscopy, thermogravimetry, and elemental analysis.

KW - X-ray crystallography

KW - chiral complexes

KW - coordination polymers

KW - praseodymium(III) complexes

KW - tartaric acid

UR - http://www.scopus.com/inward/record.url?scp=84865494170&partnerID=8YFLogxK

U2 - 10.1007/s11172-011-0373-7

DO - 10.1007/s11172-011-0373-7

M3 - Article

AN - SCOPUS:84865494170

SN - 1066-5285

VL - 60

SP - 2425

EP - 2428

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

IS - 11

ER -

Synthesis and structure of homochiral polymeric praseodymium tartrate

Abstract

Keywords

ASJC Scopus subject areas

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