Synthesis and structures of new hybrid fluorides templated by tetraprotonated pentaerythrityl tetramine

K. Adil; E. Goreshnik; S. Courant; G. Dujardin; M. Leblanc; V. Maisonneuve

doi:10.1016/j.solidstatesciences.2004.07.032

Synthesis and structures of new hybrid fluorides templated by tetraprotonated pentaerythrityl tetramine

K. Adil, E. Goreshnik, S. Courant, G. Dujardin, M. Leblanc, V. Maisonneuve

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A new route to synthetize the pentaerythrityl tetramine (tetra), C(CH ₂NH ₂) ₄, is established with a good overall yield (75-80%) and four hybrid fluorides, templated by tetra, are synthetized by hydrothermal technique and microwave heating: cis-[H ₄tetra] •(AlF ₅) ₂ (I), trans-[H ₄tetra] •(AlF ₅) ₂ (II), [H ₄tetra]•(AlF ₆)•(Cl) (III) and (H ₃O)•[H ₄tetra] ₂•(Ga(OH) ₂F ₄)•(GaF ₆) ₂•2H ₂O (IV). Structural determinations are performed from single crystal X-ray diffraction data. Structures of I and II are built up from infinite (AlF5)2-∞ chains of corner sharing AlF ₆ octahedra; the octahedra are cis-connected in I and trans-connected in II. III and IV are molecular phases and consist of isolated AlF ₆ (III) or Ga(OH) ₂F ₄ and GaF ₆ (IV) octahedra. Isolated chloride ions are found in III. Charge balance is ensured by tetraprotonated amine [H4tetra]4+ and the cohesion between inorganic and organic parts is due to hydrogen bonds.

Original language	English (US)
Pages (from-to)	1229-1235
Number of pages	7
Journal	Solid State Sciences
Volume	6
Issue number	11
DOIs	https://doi.org/10.1016/j.solidstatesciences.2004.07.032
State	Published - Nov 2004
Externally published	Yes

Keywords

Fluoride
Hybrid
Pentaerythrityltetramine
X-ray diffraction

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1016/j.solidstatesciences.2004.07.032

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title = "Synthesis and structures of new hybrid fluorides templated by tetraprotonated pentaerythrityl tetramine",

abstract = "A new route to synthetize the pentaerythrityl tetramine (tetra), C(CH 2NH 2) 4, is established with a good overall yield (75-80%) and four hybrid fluorides, templated by tetra, are synthetized by hydrothermal technique and microwave heating: cis-[H 4tetra] •(AlF 5) 2 (I), trans-[H 4tetra] •(AlF 5) 2 (II), [H 4tetra]•(AlF 6)•(Cl) (III) and (H 3O)•[H 4tetra] 2•(Ga(OH) 2F 4)•(GaF 6) 2•2H 2O (IV). Structural determinations are performed from single crystal X-ray diffraction data. Structures of I and II are built up from infinite (AlF5)2-∞ chains of corner sharing AlF 6 octahedra; the octahedra are cis-connected in I and trans-connected in II. III and IV are molecular phases and consist of isolated AlF 6 (III) or Ga(OH) 2F 4 and GaF 6 (IV) octahedra. Isolated chloride ions are found in III. Charge balance is ensured by tetraprotonated amine [H4tetra]4+ and the cohesion between inorganic and organic parts is due to hydrogen bonds.",

keywords = "Fluoride, Hybrid, Pentaerythrityltetramine, X-ray diffraction",

author = "K. Adil and E. Goreshnik and S. Courant and G. Dujardin and M. Leblanc and V. Maisonneuve",

year = "2004",

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T1 - Synthesis and structures of new hybrid fluorides templated by tetraprotonated pentaerythrityl tetramine

AU - Adil, K.

AU - Goreshnik, E.

AU - Courant, S.

AU - Dujardin, G.

AU - Leblanc, M.

AU - Maisonneuve, V.

PY - 2004/11

Y1 - 2004/11

N2 - A new route to synthetize the pentaerythrityl tetramine (tetra), C(CH 2NH 2) 4, is established with a good overall yield (75-80%) and four hybrid fluorides, templated by tetra, are synthetized by hydrothermal technique and microwave heating: cis-[H 4tetra] •(AlF 5) 2 (I), trans-[H 4tetra] •(AlF 5) 2 (II), [H 4tetra]•(AlF 6)•(Cl) (III) and (H 3O)•[H 4tetra] 2•(Ga(OH) 2F 4)•(GaF 6) 2•2H 2O (IV). Structural determinations are performed from single crystal X-ray diffraction data. Structures of I and II are built up from infinite (AlF5)2-∞ chains of corner sharing AlF 6 octahedra; the octahedra are cis-connected in I and trans-connected in II. III and IV are molecular phases and consist of isolated AlF 6 (III) or Ga(OH) 2F 4 and GaF 6 (IV) octahedra. Isolated chloride ions are found in III. Charge balance is ensured by tetraprotonated amine [H4tetra]4+ and the cohesion between inorganic and organic parts is due to hydrogen bonds.

AB - A new route to synthetize the pentaerythrityl tetramine (tetra), C(CH 2NH 2) 4, is established with a good overall yield (75-80%) and four hybrid fluorides, templated by tetra, are synthetized by hydrothermal technique and microwave heating: cis-[H 4tetra] •(AlF 5) 2 (I), trans-[H 4tetra] •(AlF 5) 2 (II), [H 4tetra]•(AlF 6)•(Cl) (III) and (H 3O)•[H 4tetra] 2•(Ga(OH) 2F 4)•(GaF 6) 2•2H 2O (IV). Structural determinations are performed from single crystal X-ray diffraction data. Structures of I and II are built up from infinite (AlF5)2-∞ chains of corner sharing AlF 6 octahedra; the octahedra are cis-connected in I and trans-connected in II. III and IV are molecular phases and consist of isolated AlF 6 (III) or Ga(OH) 2F 4 and GaF 6 (IV) octahedra. Isolated chloride ions are found in III. Charge balance is ensured by tetraprotonated amine [H4tetra]4+ and the cohesion between inorganic and organic parts is due to hydrogen bonds.

KW - Fluoride

KW - Hybrid

KW - Pentaerythrityltetramine

KW - X-ray diffraction

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Synthesis and structures of new hybrid fluorides templated by tetraprotonated pentaerythrityl tetramine

Abstract

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