Synthesis, characterization and catalytic properties of a highly stereoselective olefin metathesis catalyst

Bouchra Rhers; Eva Grinenval; Mostafa Taoufik; Fabienne Fache; Eberhardt Herdtweck; Jean Marie Basset; Frédéric Lefebvre

doi:10.1016/j.catcom.2009.01.009

Synthesis, characterization and catalytic properties of a highly stereoselective olefin metathesis catalyst

Bouchra Rhers, Eva Grinenval, Mostafa Taoufik, Fabienne Fache, Eberhardt Herdtweck, Jean Marie Basset, Frédéric Lefebvre^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The X-ray determination of a tungsten based complex allowed to definitively assign its structure and chemical formula to W(OC₆H₃PhC₆H₄)(OAr) (=CHC(CH₃)₃)Cl with Ar = 2,6-Ph₂C₆H₃. This complex is a catalytic system which displays high metathesis activity and high stereoselectivity even for bulky functional olefins.

Original language	English (US)
Pages (from-to)	1111-1116
Number of pages	6
Journal	Catalysis Communications
Volume	10
Issue number	7
DOIs	https://doi.org/10.1016/j.catcom.2009.01.009
State	Published - Mar 10 2009
Externally published	Yes

Keywords

Carbenes
Homogeneous catalysis
Metathesis
Stereoselectivity
Tungsten

ASJC Scopus subject areas

Catalysis
General Chemistry
Process Chemistry and Technology

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10.1016/j.catcom.2009.01.009

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title = "Synthesis, characterization and catalytic properties of a highly stereoselective olefin metathesis catalyst",

abstract = "The X-ray determination of a tungsten based complex allowed to definitively assign its structure and chemical formula to W(OC6H3PhC6H4)(OAr) (=CHC(CH3)3)Cl with Ar = 2,6-Ph2C6H3. This complex is a catalytic system which displays high metathesis activity and high stereoselectivity even for bulky functional olefins.",

keywords = "Carbenes, Homogeneous catalysis, Metathesis, Stereoselectivity, Tungsten",

author = "Bouchra Rhers and Eva Grinenval and Mostafa Taoufik and Fabienne Fache and Eberhardt Herdtweck and Basset, {Jean Marie} and Fr{\'e}d{\'e}ric Lefebvre",

year = "2009",

month = mar,

day = "10",

doi = "10.1016/j.catcom.2009.01.009",

language = "English (US)",

volume = "10",

pages = "1111--1116",

journal = "Catalysis Communications",

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T1 - Synthesis, characterization and catalytic properties of a highly stereoselective olefin metathesis catalyst

AU - Rhers, Bouchra

AU - Grinenval, Eva

AU - Taoufik, Mostafa

AU - Fache, Fabienne

AU - Herdtweck, Eberhardt

AU - Basset, Jean Marie

AU - Lefebvre, Frédéric

PY - 2009/3/10

Y1 - 2009/3/10

N2 - The X-ray determination of a tungsten based complex allowed to definitively assign its structure and chemical formula to W(OC6H3PhC6H4)(OAr) (=CHC(CH3)3)Cl with Ar = 2,6-Ph2C6H3. This complex is a catalytic system which displays high metathesis activity and high stereoselectivity even for bulky functional olefins.

AB - The X-ray determination of a tungsten based complex allowed to definitively assign its structure and chemical formula to W(OC6H3PhC6H4)(OAr) (=CHC(CH3)3)Cl with Ar = 2,6-Ph2C6H3. This complex is a catalytic system which displays high metathesis activity and high stereoselectivity even for bulky functional olefins.

KW - Carbenes

KW - Homogeneous catalysis

KW - Metathesis

KW - Stereoselectivity

KW - Tungsten

UR - http://www.scopus.com/inward/record.url?scp=61349182495&partnerID=8YFLogxK

U2 - 10.1016/j.catcom.2009.01.009

DO - 10.1016/j.catcom.2009.01.009

M3 - Article

AN - SCOPUS:61349182495

SN - 1566-7367

VL - 10

SP - 1111

EP - 1116

JO - Catalysis Communications

JF - Catalysis Communications

IS - 7

ER -

Synthesis, characterization and catalytic properties of a highly stereoselective olefin metathesis catalyst

Abstract

Keywords

ASJC Scopus subject areas

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