Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

Bin Gu; Chenglin Sun; James C. Fettinger; William H. Casey; Alla Dikhtiarenko; Jorge Gascon; Kamila Koichumanova; Karthick Babu Sai Sankar Gupta; Hero Jan Heeres; Songbo He

doi:10.1039/c8cc01363b

Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

Bin Gu, Chenglin Sun, James C. Fettinger, William H. Casey, Alla Dikhtiarenko, Jorge Gascon, Kamila Koichumanova, Karthick Babu Sai Sankar Gupta, Hero Jan Heeres, Songbo He

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Herein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.

Original language	English (US)
Pages (from-to)	4148-4151
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	33
DOIs	https://doi.org/10.1039/c8cc01363b
State	Published - 2018

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10.1039/c8cc01363b

https://repository.kaust.edu.sa/bitstream/10754/627418/1/Gu%20et%20al.pdf

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@article{18af4e6e98a74c4bab6042c91fc9344d,

title = "Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride",

abstract = "Herein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.",

author = "Bin Gu and Chenglin Sun and Fettinger, {James C.} and Casey, {William H.} and Alla Dikhtiarenko and Jorge Gascon and Kamila Koichumanova and {Babu Sai Sankar Gupta}, Karthick and {Jan Heeres}, Hero and Songbo He",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: S. He thanks financial support from National Natural Science Foundation of China (No. 21206161). WHC acknowledges financial support by the NSF Phase-3 CCI, Center for Sustainable Materials Chemistry (NSF CHE-1606982). WHC and JCF thank the National Science Foundation (Grant CHE-1531193) for the dual-source X-ray diffractometer.",

year = "2018",

doi = "10.1039/c8cc01363b",

language = "English (US)",

volume = "54",

pages = "4148--4151",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "33",

}

TY - JOUR

T1 - Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

AU - Gu, Bin

AU - Sun, Chenglin

AU - Fettinger, James C.

AU - Casey, William H.

AU - Dikhtiarenko, Alla

AU - Gascon, Jorge

AU - Koichumanova, Kamila

AU - Babu Sai Sankar Gupta, Karthick

AU - Jan Heeres, Hero

AU - He, Songbo

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: S. He thanks financial support from National Natural Science Foundation of China (No. 21206161). WHC acknowledges financial support by the NSF Phase-3 CCI, Center for Sustainable Materials Chemistry (NSF CHE-1606982). WHC and JCF thank the National Science Foundation (Grant CHE-1531193) for the dual-source X-ray diffractometer.

PY - 2018

Y1 - 2018

N2 - Herein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.

AB - Herein we present the first example of a glycol-coordinated ε-Keggin Al13 chloride (gl-ε-Al13), which is the first chelated version since discovery of Al13 in 1960. The molecular structure consists of [AlO4Al12(OH)12(OC2H4OH)12]Cl7·H2O units with chelating mono-anionic ethylene glycol units replacing one bridging and one terminal oxygen site.

UR - http://hdl.handle.net/10754/627418

UR - http://pubs.rsc.org/en/content/articlehtml/2018/cc/c8cc01363b

UR - http://www.scopus.com/inward/record.url?scp=85045836872&partnerID=8YFLogxK

U2 - 10.1039/c8cc01363b

DO - 10.1039/c8cc01363b

M3 - Article

C2 - 29623969

SN - 1359-7345

VL - 54

SP - 4148

EP - 4151

JO - Chemical Communications

JF - Chemical Communications

IS - 33

ER -

Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

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CCDC 1813736: Experimental Crystal Structure Determination : tetrakis(mu-oxido)-dodecakis(mu-2-hydroxyethan-1-olato)-dodecakis(mu-hydroxo)-trideca-aluminium(iii) heptakis(chloride) monohydrate unknown solvate

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Synthesis, characterization and properties of a glycol-coordinated ε-Keggin-type Al13 chloride

Abstract

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CCDC 1813736: Experimental Crystal Structure Determination : tetrakis(mu-oxido)-dodecakis(mu-2-hydroxyethan-1-olato)-dodecakis(mu-hydroxo)-trideca-aluminium(iii) heptakis(chloride) monohydrate unknown solvate

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