Synthesis of a New Family of Water-Soluble Clusters: RMCO)-12-xLx, (x = 1–3), Os3(CO)10L2, and Ir4(CO)9L3 (L = Trisodium Salt (Hydrated) of Tris (m -sulfonatophenyl) phosphine)

B. Fontal; J. Orlewski; C. C. Santini; J. M. Basset

doi:10.1021/ic00244a003

Synthesis of a New Family of Water-Soluble Clusters: RMCO)-12-xLx, (x = 1–3), Os₃(CO)₁₀L₂, and Ir₄(CO)₉L₃ (L = Trisodium Salt (Hydrated) of Tris (m -sulfonatophenyl) phosphine)

B. Fontal, J. Orlewski, C. C. Santini, J. M. Basset

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The synthesis of water-soluble clusters is of interest for their possible use as homogeneous catalysts in this solvent. There are several advantages for carrying out catalytic reactions in water; easy recovery of the costly transition metal in a biphasic system (e.g. in hydroformylation of olefins with rhodium), use of water as a reagent (as in the Wacker process), and/or obtention of a better regioselectivity with amphiphilic compounds. A better understanding of the chemical behavior and stability of transition metals, especially low-valent group VIII (groups 8–10²¹) complexes, in water is important for the development of homogeneous catalysis in this solvent. We describe here the synthesis and characterization of a new family of water-soluble metal clusters based on the hydrosoluble ligand L = P[C₆H₄-m-S0₃^-Na⁺(H₂0)]3 first described by Kuntz.

Original language	English (US)
Pages (from-to)	4320-4322
Number of pages	3
Journal	Inorganic chemistry
Volume	25
Issue number	24
DOIs	https://doi.org/10.1021/ic00244a003
State	Published - 1986
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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@article{2bddb79fa0ad463481ce257dd14a402c,

title = "Synthesis of a New Family of Water-Soluble Clusters: RMCO)-12-xLx, (x = 1–3), Os3(CO)10L2, and Ir4(CO)9L3 (L = Trisodium Salt (Hydrated) of Tris (m -sulfonatophenyl) phosphine)",

abstract = "The synthesis of water-soluble clusters is of interest for their possible use as homogeneous catalysts in this solvent. There are several advantages for carrying out catalytic reactions in water; easy recovery of the costly transition metal in a biphasic system (e.g. in hydroformylation of olefins with rhodium), use of water as a reagent (as in the Wacker process), and/or obtention of a better regioselectivity with amphiphilic compounds. A better understanding of the chemical behavior and stability of transition metals, especially low-valent group VIII (groups 8–1021) complexes, in water is important for the development of homogeneous catalysis in this solvent. We describe here the synthesis and characterization of a new family of water-soluble metal clusters based on the hydrosoluble ligand L = P[C6H4-m-S03-Na+(H20)]3 first described by Kuntz.",

author = "B. Fontal and J. Orlewski and Santini, {C. C.} and Basset, {J. M.}",

year = "1986",

doi = "10.1021/ic00244a003",

language = "English (US)",

volume = "25",

pages = "4320--4322",

journal = "Inorganic chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Synthesis of a New Family of Water-Soluble Clusters

T2 - RMCO)-12-xLx, (x = 1–3), Os3(CO)10L2, and Ir4(CO)9L3 (L = Trisodium Salt (Hydrated) of Tris (m -sulfonatophenyl) phosphine)

AU - Fontal, B.

AU - Orlewski, J.

AU - Santini, C. C.

AU - Basset, J. M.

PY - 1986

Y1 - 1986

N2 - The synthesis of water-soluble clusters is of interest for their possible use as homogeneous catalysts in this solvent. There are several advantages for carrying out catalytic reactions in water; easy recovery of the costly transition metal in a biphasic system (e.g. in hydroformylation of olefins with rhodium), use of water as a reagent (as in the Wacker process), and/or obtention of a better regioselectivity with amphiphilic compounds. A better understanding of the chemical behavior and stability of transition metals, especially low-valent group VIII (groups 8–1021) complexes, in water is important for the development of homogeneous catalysis in this solvent. We describe here the synthesis and characterization of a new family of water-soluble metal clusters based on the hydrosoluble ligand L = P[C6H4-m-S03-Na+(H20)]3 first described by Kuntz.

AB - The synthesis of water-soluble clusters is of interest for their possible use as homogeneous catalysts in this solvent. There are several advantages for carrying out catalytic reactions in water; easy recovery of the costly transition metal in a biphasic system (e.g. in hydroformylation of olefins with rhodium), use of water as a reagent (as in the Wacker process), and/or obtention of a better regioselectivity with amphiphilic compounds. A better understanding of the chemical behavior and stability of transition metals, especially low-valent group VIII (groups 8–1021) complexes, in water is important for the development of homogeneous catalysis in this solvent. We describe here the synthesis and characterization of a new family of water-soluble metal clusters based on the hydrosoluble ligand L = P[C6H4-m-S03-Na+(H20)]3 first described by Kuntz.

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U2 - 10.1021/ic00244a003

DO - 10.1021/ic00244a003

M3 - Article

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SN - 0020-1669

VL - 25

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JO - Inorganic chemistry

JF - Inorganic chemistry

IS - 24

ER -

Synthesis of a New Family of Water-Soluble Clusters: RMCO)-12-xLx, (x = 1–3), Os₃(CO)₁₀L₂, and Ir₄(CO)₉L₃ (L = Trisodium Salt (Hydrated) of Tris (m -sulfonatophenyl) phosphine)

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