Synthesis of asymmetric star-branched polymers containing poly(dimethylsiloxane) using 1,1-diphenylethylene derivatives

Takurou Sakurai; Yosuke Matsunaga; Akira Hirao; Panagiota G. Fragouli; Hermis Latrou; Nikos Hadjichristidis

Synthesis of asymmetric star-branched polymers containing poly(dimethylsiloxane) using 1,1-diphenylethylene derivatives

Takurou Sakurai^*, Yosuke Matsunaga, Akira Hirao, Panagiota G. Fragouli, Hermis Latrou, Nikos Hadjichristidis

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

We have developed the synthetic strategy of well-defined asymmetric star-branched polymers containing poly(dimethylsiloxane) segments by a coupling reaction of polymer bearing an anionized 1,1-diphenylethylene moiety and in-chain-functionalized poly(dimethylsiloxane) with a benzyl chloride group. Expectedly, 4-arm A₂B₂, ABC₂, and 5-arm AB ₂C₂ asymmetric star-branched polymers containing poly(dimethylsiloxane) were quantitatively synthesized by the coupling reactions. Their high degrees of compositional and architectural homogeneity were confirmed by the analytical results of SEC, ¹H NMR, and RALLS.

Original language	English (US)
Title of host publication	Polymer Preprints, Japan - 55th SPSJ Annual Meeting
Pages	414
Number of pages	1
Volume	55
Edition	1
State	Published - 2006
Externally published	Yes
Event	55th SPSJ Annual Meeting - Nagoya, Japan Duration: May 24 2006 → May 26 2006

Other

Other	55th SPSJ Annual Meeting
Country/Territory	Japan
City	Nagoya
Period	05/24/06 → 05/26/06

Keywords

1,1-diphenylethylene
Living anionic polymerization
Poly(dimethylsiloxane)
Star-branched polymer
Well-defined architecture

ASJC Scopus subject areas

Engineering(all)

Cite this

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title = "Synthesis of asymmetric star-branched polymers containing poly(dimethylsiloxane) using 1,1-diphenylethylene derivatives",

abstract = "We have developed the synthetic strategy of well-defined asymmetric star-branched polymers containing poly(dimethylsiloxane) segments by a coupling reaction of polymer bearing an anionized 1,1-diphenylethylene moiety and in-chain-functionalized poly(dimethylsiloxane) with a benzyl chloride group. Expectedly, 4-arm A2B2, ABC2, and 5-arm AB 2C2 asymmetric star-branched polymers containing poly(dimethylsiloxane) were quantitatively synthesized by the coupling reactions. Their high degrees of compositional and architectural homogeneity were confirmed by the analytical results of SEC, 1H NMR, and RALLS.",

keywords = "1,1-diphenylethylene, Living anionic polymerization, Poly(dimethylsiloxane), Star-branched polymer, Well-defined architecture",

author = "Takurou Sakurai and Yosuke Matsunaga and Akira Hirao and Fragouli, {Panagiota G.} and Hermis Latrou and Nikos Hadjichristidis",

year = "2006",

language = "English (US)",

volume = "55",

pages = "414",

booktitle = "Polymer Preprints, Japan - 55th SPSJ Annual Meeting",

edition = "1",

note = "55th SPSJ Annual Meeting ; Conference date: 24-05-2006 Through 26-05-2006",

}

TY - GEN

T1 - Synthesis of asymmetric star-branched polymers containing poly(dimethylsiloxane) using 1,1-diphenylethylene derivatives

AU - Sakurai, Takurou

AU - Matsunaga, Yosuke

AU - Hirao, Akira

AU - Fragouli, Panagiota G.

AU - Latrou, Hermis

AU - Hadjichristidis, Nikos

PY - 2006

Y1 - 2006

N2 - We have developed the synthetic strategy of well-defined asymmetric star-branched polymers containing poly(dimethylsiloxane) segments by a coupling reaction of polymer bearing an anionized 1,1-diphenylethylene moiety and in-chain-functionalized poly(dimethylsiloxane) with a benzyl chloride group. Expectedly, 4-arm A2B2, ABC2, and 5-arm AB 2C2 asymmetric star-branched polymers containing poly(dimethylsiloxane) were quantitatively synthesized by the coupling reactions. Their high degrees of compositional and architectural homogeneity were confirmed by the analytical results of SEC, 1H NMR, and RALLS.

AB - We have developed the synthetic strategy of well-defined asymmetric star-branched polymers containing poly(dimethylsiloxane) segments by a coupling reaction of polymer bearing an anionized 1,1-diphenylethylene moiety and in-chain-functionalized poly(dimethylsiloxane) with a benzyl chloride group. Expectedly, 4-arm A2B2, ABC2, and 5-arm AB 2C2 asymmetric star-branched polymers containing poly(dimethylsiloxane) were quantitatively synthesized by the coupling reactions. Their high degrees of compositional and architectural homogeneity were confirmed by the analytical results of SEC, 1H NMR, and RALLS.

KW - 1,1-diphenylethylene

KW - Living anionic polymerization

KW - Poly(dimethylsiloxane)

KW - Star-branched polymer

KW - Well-defined architecture

UR - http://www.scopus.com/inward/record.url?scp=33749664138&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:33749664138

VL - 55

SP - 414

BT - Polymer Preprints, Japan - 55th SPSJ Annual Meeting

T2 - 55th SPSJ Annual Meeting

Y2 - 24 May 2006 through 26 May 2006

ER -

Synthesis of asymmetric star-branched polymers containing poly(dimethylsiloxane) using 1,1-diphenylethylene derivatives

Abstract

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Keywords

ASJC Scopus subject areas

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