Synthesis of gold(I)-trifluoromethyl complexes and their role in generating spectroscopic evidence for a gold(I)-difluorocarbene species.

Steven Patrick Nolan, Sofie M P Vanden Broeck, David J Nelson, Alba Collado, Laura Falivene, Luigi Cavallo, David B Cordes, Alexandra M Z Slawin, Kristof Van Hecke, Fady Nahra, Catherine S J Cazin

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

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CCDC 2023143: Experimental Crystal Structure Determination : bis(1,3-bis[2,6-bis(propan-2-yl)phenyl]-4-(trimethylsilyl)imidazol-2-ylidene)-gold tetrafluoroborate chloroform solvate
Falivene, L. (Creator), Cavallo, L. (Creator), Nolan, S. P. (Creator), Vanden Broeck, S. M. P. (Creator), Nelson, D. J. (Creator), Collado, A. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator), Van Hecke, K. (Creator), Nahra, F. (Creator) & Cazin, C. S. J. (Creator), Cambridge Crystallographic Data Centre, Jun 30 2021
DOI: 10.5517/ccdc.csd.cc25x7p1, http://hdl.handle.net/10754/687093
Dataset
CCDC 2023144: Experimental Crystal Structure Determination : (1,3-bis[2,6-bis(propan-2-yl)phenyl]-4-(trimethylsilyl)imidazol-2-ylidene)-(trifluoromethyl)-gold
Falivene, L. (Creator), Cavallo, L. (Creator), Nolan, S. P. (Creator), Vanden Broeck, S. M. P. (Creator), Nelson, D. J. (Creator), Collado, A. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator), Van Hecke, K. (Creator), Nahra, F. (Creator) & Cazin, C. S. J. (Creator), Cambridge Crystallographic Data Centre, Jun 30 2021
DOI: 10.5517/ccdc.csd.cc25x7q2, http://hdl.handle.net/10754/687094
Dataset
CCDC 2023145: Experimental Crystal Structure Determination : (1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]imidazol-2-ylidene)-(trifluoromethyl)-gold tetrahydrofuran solvate
Falivene, L. (Creator), Cavallo, L. (Creator), Nolan, S. P. (Creator), Vanden Broeck, S. M. P. (Creator), Nelson, D. J. (Creator), Collado, A. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator), Van Hecke, K. (Creator), Nahra, F. (Creator) & Cazin, C. S. J. (Creator), Cambridge Crystallographic Data Centre, Jun 30 2021
DOI: 10.5517/ccdc.csd.cc25x7r3, http://hdl.handle.net/10754/687095
Dataset
CCDC 2023147: Experimental Crystal Structure Determination : (4,5-dichloro-1,3-bis[2,6-bis(propan-2-yl)phenyl]imidazol-2-ylidene)-(trifluoromethyl)-gold
Falivene, L. (Creator), Cavallo, L. (Creator), Nolan, S. P. (Creator), Vanden Broeck, S. M. P. (Creator), Nelson, D. J. (Creator), Collado, A. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator), Van Hecke, K. (Creator), Nahra, F. (Creator) & Cazin, C. S. J. (Creator), Cambridge Crystallographic Data Centre, Jun 30 2021
DOI: 10.5517/ccdc.csd.cc25x7t5, http://hdl.handle.net/10754/687097
Dataset
CCDC 2023146: Experimental Crystal Structure Determination : (1,3-bis[2,6-bis(propan-2-yl)phenyl]-4,5-dimethylimidazol-2-ylidene)-(trifluoromethyl)-gold
Falivene, L. (Creator), Cavallo, L. (Creator), Nolan, S. P. (Creator), Vanden Broeck, S. M. P. (Creator), Nelson, D. J. (Creator), Collado, A. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator), Van Hecke, K. (Creator), Nahra, F. (Creator) & Cazin, C. S. J. (Creator), Cambridge Crystallographic Data Centre, Jun 30 2021
DOI: 10.5517/ccdc.csd.cc25x7s4, http://hdl.handle.net/10754/687096
Dataset

Synthesis of gold(I)-trifluoromethyl complexes and their role in generating spectroscopic evidence for a gold(I)-difluorocarbene species.

Datasets

Search results

CCDC 2023143: Experimental Crystal Structure Determination : bis(1,3-bis[2,6-bis(propan-2-yl)phenyl]-4-(trimethylsilyl)imidazol-2-ylidene)-gold tetrafluoroborate chloroform solvate

CCDC 2023144: Experimental Crystal Structure Determination : (1,3-bis[2,6-bis(propan-2-yl)phenyl]-4-(trimethylsilyl)imidazol-2-ylidene)-(trifluoromethyl)-gold

CCDC 2023145: Experimental Crystal Structure Determination : (1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]imidazol-2-ylidene)-(trifluoromethyl)-gold tetrahydrofuran solvate

CCDC 2023147: Experimental Crystal Structure Determination : (4,5-dichloro-1,3-bis[2,6-bis(propan-2-yl)phenyl]imidazol-2-ylidene)-(trifluoromethyl)-gold

CCDC 2023146: Experimental Crystal Structure Determination : (1,3-bis[2,6-bis(propan-2-yl)phenyl]-4,5-dimethylimidazol-2-ylidene)-(trifluoromethyl)-gold