Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity

Xiufang Wang; Liangfeng Yao; Yupeng Pan; Kuo-Wei Huang

doi:10.1016/j.jorganchem.2016.12.032

Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity

Xiufang Wang, Liangfeng Yao, Yupeng Pan, Kuo-Wei Huang

Research output: Contribution to journal › Article › peer-review

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Abstract

A post-modification strategy are used to synthesize a new class of diimine-amido PN3P-pincer group-10 transition metal complexes. The coordination chemistry and the thermal stabilities of their organometallic derivatives are characterized and investigated.

Original language	English (US)
Pages (from-to)	25-29
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	845
DOIs	https://doi.org/10.1016/j.jorganchem.2016.12.032
State	Published - Jan 1 2017

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10.1016/j.jorganchem.2016.12.032

https://repository.kaust.edu.sa/bitstream/10754/622628/1/1-s2.0-S0022328X16305939-main.pdf

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title = "Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity",

abstract = "A post-modification strategy are used to synthesize a new class of diimine-amido PN3P-pincer group-10 transition metal complexes. The coordination chemistry and the thermal stabilities of their organometallic derivatives are characterized and investigated.",

author = "Xiufang Wang and Liangfeng Yao and Yupeng Pan and Kuo-Wei Huang",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by King Abdullah University of Science and Technology (KAUST). We thank Dr. Jinsong Hu and Carolyn E. Unck for assistance with the manuscript preparation.",

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AU - Wang, Xiufang

AU - Yao, Liangfeng

AU - Pan, Yupeng

AU - Huang, Kuo-Wei

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: This work was supported by King Abdullah University of Science and Technology (KAUST). We thank Dr. Jinsong Hu and Carolyn E. Unck for assistance with the manuscript preparation.

PY - 2017/1/1

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N2 - A post-modification strategy are used to synthesize a new class of diimine-amido PN3P-pincer group-10 transition metal complexes. The coordination chemistry and the thermal stabilities of their organometallic derivatives are characterized and investigated.

AB - A post-modification strategy are used to synthesize a new class of diimine-amido PN3P-pincer group-10 transition metal complexes. The coordination chemistry and the thermal stabilities of their organometallic derivatives are characterized and investigated.

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity

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CCDC 1563150: Experimental Crystal Structure Determination : chloro-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-platinum(ii)

CCDC 1563148: Experimental Crystal Structure Determination : butyl-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-nickel(ii)

CCDC 1563149: Experimental Crystal Structure Determination : methyl-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-nickel(ii)

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Synthesis of group 10 metal complexes with a new unsymmetrical PN3P-pincer ligand through ligand post-modification: Structure and reactivity

Abstract

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Datasets

CCDC 1563150: Experimental Crystal Structure Determination : chloro-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-platinum(ii)

CCDC 1563148: Experimental Crystal Structure Determination : butyl-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-nickel(ii)

CCDC 1563149: Experimental Crystal Structure Determination : methyl-(N,N'-(3,3,5-triethylpyridine-2,6(1H,3H)-diylidene)bis[P,P-di-t-butyl(phosphinous amidato)])-nickel(ii)

Cite this