Synthesis of Heteroatom Substituted SBA-15 by the "pH-Adjusting" Method

Shuo Wu; Yu Han; Yong Cun Zou; Jiang Wei Song; Lan Zhao; Yan Di; Shu Zhen Liu; Feng Shou Xiao

doi:10.1021/cm0343857

Synthesis of Heteroatom Substituted SBA-15 by the "pH-Adjusting" Method

Shuo Wu, Yu Han, Yong Cun Zou, Jiang Wei Song, Lan Zhao, Yan Di, Shu Zhen Liu, Feng Shou Xiao^*

^*Corresponding author for this work

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

292 Citations (SciVal)

Abstract

A simple and effective method denoted "pH-adjusting" is used to graft a large amount of heteroatoms such as Al and Ti to mesoporous silica material SBA-15. The products prepared by this method show highly ordered mesostructures with large surface areas and uniform mesopore size distribution. The results of ICP, EDX, ²⁷Al NMR, calcium ion-exchange capacity, and UV-vis spectra show that almost all the heteroatoms added into the initial reaction mixture can be introduced into the products, and moreover, the heteroatoms introduced by this route locate at mainly tetrahedrally coordinated sites.

Original language	English (US)
Pages (from-to)	486-492
Number of pages	7
Journal	Chemistry of Materials
Volume	16
Issue number	3
DOIs	https://doi.org/10.1021/cm0343857
State	Published - Feb 10 2004

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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abstract = "A simple and effective method denoted {"}pH-adjusting{"} is used to graft a large amount of heteroatoms such as Al and Ti to mesoporous silica material SBA-15. The products prepared by this method show highly ordered mesostructures with large surface areas and uniform mesopore size distribution. The results of ICP, EDX, 27Al NMR, calcium ion-exchange capacity, and UV-vis spectra show that almost all the heteroatoms added into the initial reaction mixture can be introduced into the products, and moreover, the heteroatoms introduced by this route locate at mainly tetrahedrally coordinated sites.",

author = "Shuo Wu and Yu Han and Zou, {Yong Cun} and Song, {Jiang Wei} and Lan Zhao and Yan Di and Liu, {Shu Zhen} and Xiao, {Feng Shou}",

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AU - Wu, Shuo

AU - Han, Yu

AU - Zou, Yong Cun

AU - Song, Jiang Wei

AU - Zhao, Lan

AU - Di, Yan

AU - Liu, Shu Zhen

AU - Xiao, Feng Shou

PY - 2004/2/10

Y1 - 2004/2/10

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AB - A simple and effective method denoted "pH-adjusting" is used to graft a large amount of heteroatoms such as Al and Ti to mesoporous silica material SBA-15. The products prepared by this method show highly ordered mesostructures with large surface areas and uniform mesopore size distribution. The results of ICP, EDX, 27Al NMR, calcium ion-exchange capacity, and UV-vis spectra show that almost all the heteroatoms added into the initial reaction mixture can be introduced into the products, and moreover, the heteroatoms introduced by this route locate at mainly tetrahedrally coordinated sites.

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JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 3

ER -

Synthesis of Heteroatom Substituted SBA-15 by the "pH-Adjusting" Method

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