Synthesis of new high molecular weight and reactive ladderlike polysilsesquioxanes

Huai Zhong Pan; Chun Qing Liu; Ming Cao; Ping Xie; Rong Ben Zhang; Yu Hui Lin; Neal Tai Sheng Chung

Synthesis of new high molecular weight and reactive ladderlike polysilsesquioxanes

Huai Zhong Pan, Chun Qing Liu, Ming Cao, Ping Xie, Rong Ben Zhang^*, Yu Hui Lin, Neal Tai Sheng Chung

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by "stepwise coupling polymerization". The molecular weight of CP-T is as high as 1.7 × 10⁵. It is a tough, elastic reactive ladderlike polymer and has good heat-resistant and adhesive properties. CP-T can further react with many nucleophilic reagents to generate new ladderlike reactive polysilsesquioxanes, which can be used as potential precursors in the synthesis of functional ladderlike polymers.

Original language	English (US)
Pages (from-to)	459-463
Number of pages	5
Journal	Chinese Journal of Polymer Science (English Edition)
Volume	18
Issue number	5
State	Published - Sep 2000
Externally published	Yes

Keywords

Nucleophilic substitution
Reactive ladderlike polymer
Stepwise coupling polymerization

ASJC Scopus subject areas

General Chemical Engineering
Organic Chemistry
Polymers and Plastics

Cite this

@article{d122c2bc49154caaa87a8fd9d9b6a205,

title = "Synthesis of new high molecular weight and reactive ladderlike polysilsesquioxanes",

abstract = "Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by {"}stepwise coupling polymerization{"}. The molecular weight of CP-T is as high as 1.7 × 105. It is a tough, elastic reactive ladderlike polymer and has good heat-resistant and adhesive properties. CP-T can further react with many nucleophilic reagents to generate new ladderlike reactive polysilsesquioxanes, which can be used as potential precursors in the synthesis of functional ladderlike polymers.",

keywords = "Nucleophilic substitution, Reactive ladderlike polymer, Stepwise coupling polymerization",

author = "Pan, {Huai Zhong} and Liu, {Chun Qing} and Ming Cao and Ping Xie and Zhang, {Rong Ben} and Lin, {Yu Hui} and Chung, {Neal Tai Sheng}",

year = "2000",

month = sep,

language = "English (US)",

volume = "18",

pages = "459--463",

journal = "Chinese Journal of Polymer Science (English Edition)",

issn = "0256-7679",

publisher = "Springer Verlag",

number = "5",

}

TY - JOUR

T1 - Synthesis of new high molecular weight and reactive ladderlike polysilsesquioxanes

AU - Pan, Huai Zhong

AU - Liu, Chun Qing

AU - Cao, Ming

AU - Xie, Ping

AU - Zhang, Rong Ben

AU - Lin, Yu Hui

AU - Chung, Neal Tai Sheng

PY - 2000/9

Y1 - 2000/9

N2 - Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by "stepwise coupling polymerization". The molecular weight of CP-T is as high as 1.7 × 105. It is a tough, elastic reactive ladderlike polymer and has good heat-resistant and adhesive properties. CP-T can further react with many nucleophilic reagents to generate new ladderlike reactive polysilsesquioxanes, which can be used as potential precursors in the synthesis of functional ladderlike polymers.

AB - Ladderlike polychloropropylsilsesquioxane (CP-T) was first synthesized by "stepwise coupling polymerization". The molecular weight of CP-T is as high as 1.7 × 105. It is a tough, elastic reactive ladderlike polymer and has good heat-resistant and adhesive properties. CP-T can further react with many nucleophilic reagents to generate new ladderlike reactive polysilsesquioxanes, which can be used as potential precursors in the synthesis of functional ladderlike polymers.

KW - Nucleophilic substitution

KW - Reactive ladderlike polymer

KW - Stepwise coupling polymerization

UR - http://www.scopus.com/inward/record.url?scp=0034374060&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0034374060

SN - 0256-7679

VL - 18

SP - 459

EP - 463

JO - Chinese Journal of Polymer Science (English Edition)

JF - Chinese Journal of Polymer Science (English Edition)

IS - 5

ER -

Synthesis of new high molecular weight and reactive ladderlike polysilsesquioxanes

Abstract

Keywords

ASJC Scopus subject areas

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