Synthesis of Polycarboxylate Rh(II)-Metal-Organic Polyhedra and their use as Building Blocks for Highly-Connected Metal-Organic Frameworks.

Thais Grancha; Arnau Carne-Sanchez; Farnoosh Zarekarizi; Laura Hernández-López; Jorge Albalad; Akim Khobotov; Vincent Guillerm; Ali Morsali; Judith Juanhuix; Felipe Gándara; Inhar Imaz; Daniel Maspoch

doi:10.1002/anie.202013839

Synthesis of Polycarboxylate Rh(II)-Metal-Organic Polyhedra and their use as Building Blocks for Highly-Connected Metal-Organic Frameworks.

Thais Grancha, Arnau Carne-Sanchez, Farnoosh Zarekarizi, Laura Hernández-López, Jorge Albalad, Akim Khobotov, Vincent Guillerm, Ali Morsali, Judith Juanhuix, Felipe Gándara, Inhar Imaz, Daniel Maspoch

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

Use of preformed metal-organic polyhedra (MOPs) as supermolecular building blocks (SBBs) for the synthesis of metal-organic frameworks (MOFs) remains underexplored due to lack of robust functionalized MOPs. Herein we report the use of polycarboxylate cuboctahedral Rh(II)-MOPs for constructing highly-connected MOFs. Cuboctahedral MOPs were functionalized with carboxylic acid groups on their 12 vertices or 24 edges through coordinative or covalent post-synthetic routes, respectively. We then used each isolated polycarboxylate Rh(II)-MOP as 12-c cuboctahedral or 24-c rhombicuboctahedral SBBs that, upon linkage with metallic secondary building units (SBUs), afford bimetallic highly-connected MOFs. The assembly of a pre-synthesized 12-c SBB with a 4-c paddle-wheel SBU, and a 24-c SBB with a 3-c triangular Cu(II) SBU gave rise to bimetallic MOFs having ftw (4,12-c) or rht (3,24-c) topologies, respectively.

Original language	English (US)
Journal	Angewandte Chemie (International ed. in English)
DOIs	https://doi.org/10.1002/anie.202013839
State	Published - Dec 11 2020

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10.1002/anie.202013839

https://repository.kaust.edu.sa/bitstream/10754/666340/1/Synthesis%20of---_anie.202013839.pdf

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Grancha, T., Carne-Sanchez, A., Zarekarizi, F., Hernández-López, L., Albalad, J., Khobotov, A., Guillerm, V., Morsali, A., Juanhuix, J., Gándara, F., Imaz, I., & Maspoch, D. (2020). Synthesis of Polycarboxylate Rh(II)-Metal-Organic Polyhedra and their use as Building Blocks for Highly-Connected Metal-Organic Frameworks. Angewandte Chemie (International ed. in English). https://doi.org/10.1002/anie.202013839

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title = "Synthesis of Polycarboxylate Rh(II)-Metal-Organic Polyhedra and their use as Building Blocks for Highly-Connected Metal-Organic Frameworks.",

abstract = "Use of preformed metal-organic polyhedra (MOPs) as supermolecular building blocks (SBBs) for the synthesis of metal-organic frameworks (MOFs) remains underexplored due to lack of robust functionalized MOPs. Herein we report the use of polycarboxylate cuboctahedral Rh(II)-MOPs for constructing highly-connected MOFs. Cuboctahedral MOPs were functionalized with carboxylic acid groups on their 12 vertices or 24 edges through coordinative or covalent post-synthetic routes, respectively. We then used each isolated polycarboxylate Rh(II)-MOP as 12-c cuboctahedral or 24-c rhombicuboctahedral SBBs that, upon linkage with metallic secondary building units (SBUs), afford bimetallic highly-connected MOFs. The assembly of a pre-synthesized 12-c SBB with a 4-c paddle-wheel SBU, and a 24-c SBB with a 3-c triangular Cu(II) SBU gave rise to bimetallic MOFs having ftw (4,12-c) or rht (3,24-c) topologies, respectively.",

author = "Thais Grancha and Arnau Carne-Sanchez and Farnoosh Zarekarizi and Laura Hern{\'a}ndez-L{\'o}pez and Jorge Albalad and Akim Khobotov and Vincent Guillerm and Ali Morsali and Judith Juanhuix and Felipe G{\'a}ndara and Inhar Imaz and Daniel Maspoch",

note = "KAUST Repository Item: Exported on 2020-12-14",

year = "2020",

month = dec,

day = "11",

doi = "10.1002/anie.202013839",

language = "English (US)",

journal = "Angewandte Chemie (International ed. in English)",

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Grancha, T, Carne-Sanchez, A, Zarekarizi, F, Hernández-López, L, Albalad, J, Khobotov, A, Guillerm, V, Morsali, A, Juanhuix, J, Gándara, F, Imaz, I & Maspoch, D 2020, 'Synthesis of Polycarboxylate Rh(II)-Metal-Organic Polyhedra and their use as Building Blocks for Highly-Connected Metal-Organic Frameworks.', Angewandte Chemie (International ed. in English). https://doi.org/10.1002/anie.202013839

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T1 - Synthesis of Polycarboxylate Rh(II)-Metal-Organic Polyhedra and their use as Building Blocks for Highly-Connected Metal-Organic Frameworks.

AU - Grancha, Thais

AU - Carne-Sanchez, Arnau

AU - Zarekarizi, Farnoosh

AU - Hernández-López, Laura

AU - Albalad, Jorge

AU - Khobotov, Akim

AU - Guillerm, Vincent

AU - Morsali, Ali

AU - Juanhuix, Judith

AU - Gándara, Felipe

AU - Imaz, Inhar

AU - Maspoch, Daniel

N1 - KAUST Repository Item: Exported on 2020-12-14

PY - 2020/12/11

Y1 - 2020/12/11

N2 - Use of preformed metal-organic polyhedra (MOPs) as supermolecular building blocks (SBBs) for the synthesis of metal-organic frameworks (MOFs) remains underexplored due to lack of robust functionalized MOPs. Herein we report the use of polycarboxylate cuboctahedral Rh(II)-MOPs for constructing highly-connected MOFs. Cuboctahedral MOPs were functionalized with carboxylic acid groups on their 12 vertices or 24 edges through coordinative or covalent post-synthetic routes, respectively. We then used each isolated polycarboxylate Rh(II)-MOP as 12-c cuboctahedral or 24-c rhombicuboctahedral SBBs that, upon linkage with metallic secondary building units (SBUs), afford bimetallic highly-connected MOFs. The assembly of a pre-synthesized 12-c SBB with a 4-c paddle-wheel SBU, and a 24-c SBB with a 3-c triangular Cu(II) SBU gave rise to bimetallic MOFs having ftw (4,12-c) or rht (3,24-c) topologies, respectively.

AB - Use of preformed metal-organic polyhedra (MOPs) as supermolecular building blocks (SBBs) for the synthesis of metal-organic frameworks (MOFs) remains underexplored due to lack of robust functionalized MOPs. Herein we report the use of polycarboxylate cuboctahedral Rh(II)-MOPs for constructing highly-connected MOFs. Cuboctahedral MOPs were functionalized with carboxylic acid groups on their 12 vertices or 24 edges through coordinative or covalent post-synthetic routes, respectively. We then used each isolated polycarboxylate Rh(II)-MOP as 12-c cuboctahedral or 24-c rhombicuboctahedral SBBs that, upon linkage with metallic secondary building units (SBUs), afford bimetallic highly-connected MOFs. The assembly of a pre-synthesized 12-c SBB with a 4-c paddle-wheel SBU, and a 24-c SBB with a 3-c triangular Cu(II) SBU gave rise to bimetallic MOFs having ftw (4,12-c) or rht (3,24-c) topologies, respectively.

UR - http://hdl.handle.net/10754/666340

UR - https://onlinelibrary.wiley.com/doi/10.1002/anie.202013839

U2 - 10.1002/anie.202013839

DO - 10.1002/anie.202013839

M3 - Article

C2 - 33306243

SN - 1521-3773

JO - Angewandte Chemie (International ed. in English)

JF - Angewandte Chemie (International ed. in English)

ER -

Synthesis of Polycarboxylate Rh(II)-Metal-Organic Polyhedra and their use as Building Blocks for Highly-Connected Metal-Organic Frameworks.

Abstract

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CCDC 2031083: Experimental Crystal Structure Determination : tetracosakis(mu-5-hydroxybenzene-1,3-dicarboxylato)-dodecakis(4-carboxypyridine)-dodeca-aqua-tetracosa-rhodium(ii) tetracosakis(mu-5-hydroxybenzene-1,3-dicarboxylato)-decakis(4-carboxypyridine)-d

CCDC 2031082: Experimental Crystal Structure Determination : tetracosakis(mu-hydrogen benzene-1,3,5-tricarboxylato)-tetracosa-aqua-tetracosa-rhodium(ii) unknown solvate

CCDC 2031084: Experimental Crystal Structure Determination : catena-[bis(mu-pyridine-4-carboxylato)-tetrakis(mu-5-hydroxybenzene-1,3-dicarboxylato)-triaqua-copper(ii)-tetra-rhodium(ii) unknown solvate]

Cite this

Synthesis of Polycarboxylate Rh(II)-Metal-Organic Polyhedra and their use as Building Blocks for Highly-Connected Metal-Organic Frameworks.

Abstract

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Other files and links

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Datasets

CCDC 2031083: Experimental Crystal Structure Determination : tetracosakis(mu-5-hydroxybenzene-1,3-dicarboxylato)-dodecakis(4-carboxypyridine)-dodeca-aqua-tetracosa-rhodium(ii) tetracosakis(mu-5-hydroxybenzene-1,3-dicarboxylato)-decakis(4-carboxypyridine)-d

CCDC 2031082: Experimental Crystal Structure Determination : tetracosakis(mu-hydrogen benzene-1,3,5-tricarboxylato)-tetracosa-aqua-tetracosa-rhodium(ii) unknown solvate

CCDC 2031084: Experimental Crystal Structure Determination : catena-[bis(mu-pyridine-4-carboxylato)-tetrakis(mu-5-hydroxybenzene-1,3-dicarboxylato)-triaqua-copper(ii)-tetra-rhodium(ii) unknown solvate]

Cite this