Synthesis of single-crystal-like nanoporous carbon membranes and their application in overall water splitting

Hong Wang; Shixiong Min; Chun Ma; Zhixiong Liu; Weiyi Zhang; Qiang Wang; Debao Li; Yangyang Li; Stuart Turner; Yu Han; Haibo Zhu; Edy Abou-Hamad; Mohamed N. Hedhili; Jun Pan; Weili Yu; Kuo-Wei Huang; Lain-Jong Li; Jiayin Yuan; Markus Antonietti; Tao Wu

doi:10.1038/ncomms13592

Synthesis of single-crystal-like nanoporous carbon membranes and their application in overall water splitting

Hong Wang, Shixiong Min, Chun Ma, Zhixiong Liu, Weiyi Zhang, Qiang Wang, Debao Li, Yangyang Li, Stuart Turner, Yu Han, Haibo Zhu, Edy Abou-Hamad, Mohamed N. Hedhili, Jun Pan, Weili Yu, Kuo-Wei Huang, Lain-Jong Li, Jiayin Yuan, Markus Antonietti, Tao Wu

Research output: Contribution to journal › Article › peer-review

157 Scopus citations

Abstract

Nanoporous graphitic carbon membranes with defined chemical composition and pore architecture are novel nanomaterials that are actively pursued. Compared with easy-to-make porous carbon powders that dominate the porous carbon research and applications in energy generation/conversion and environmental remediation, porous carbon membranes are synthetically more challenging though rather appealing from an application perspective due to their structural integrity, interconnectivity and purity. Here we report a simple bottom–up approach to fabricate large-size, freestanding and porous carbon membranes that feature an unusual single-crystal-like graphitic order and hierarchical pore architecture plus favourable nitrogen doping. When loaded with cobalt nanoparticles, such carbon membranes serve as high-performance carbon-based non-noble metal electrocatalyst for overall water splitting.

Original language	English (US)
Journal	Nature Communications
Volume	8
Issue number	1
DOIs	https://doi.org/10.1038/ncomms13592
State	Published - Jan 4 2017

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Wang, H., Min, S., Ma, C., Liu, Z., Zhang, W., Wang, Q., Li, D., Li, Y., Turner, S., Han, Y., Zhu, H., Abou-Hamad, E., Hedhili, M. N., Pan, J., Yu, W., Huang, K.-W., Li, L.-J., Yuan, J., Antonietti, M., & Wu, T. (2017). Synthesis of single-crystal-like nanoporous carbon membranes and their application in overall water splitting. Nature Communications, 8(1). https://doi.org/10.1038/ncomms13592

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title = "Synthesis of single-crystal-like nanoporous carbon membranes and their application in overall water splitting",

abstract = "Nanoporous graphitic carbon membranes with defined chemical composition and pore architecture are novel nanomaterials that are actively pursued. Compared with easy-to-make porous carbon powders that dominate the porous carbon research and applications in energy generation/conversion and environmental remediation, porous carbon membranes are synthetically more challenging though rather appealing from an application perspective due to their structural integrity, interconnectivity and purity. Here we report a simple bottom–up approach to fabricate large-size, freestanding and porous carbon membranes that feature an unusual single-crystal-like graphitic order and hierarchical pore architecture plus favourable nitrogen doping. When loaded with cobalt nanoparticles, such carbon membranes serve as high-performance carbon-based non-noble metal electrocatalyst for overall water splitting.",

author = "Hong Wang and Shixiong Min and Chun Ma and Zhixiong Liu and Weiyi Zhang and Qiang Wang and Debao Li and Yangyang Li and Stuart Turner and Yu Han and Haibo Zhu and Edy Abou-Hamad and Hedhili, {Mohamed N.} and Jun Pan and Weili Yu and Kuo-Wei Huang and Lain-Jong Li and Jiayin Yuan and Markus Antonietti and Tao Wu",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We thank the King Abdullah University of Science and Technology (KAUST) for financial support. J.Y. is grateful for financial support from the Max Planck society, Germany, and the ERC (European Research Council) Starting Grant (project number 639720-NAPOLI).",

year = "2017",

month = jan,

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doi = "10.1038/ncomms13592",

language = "English (US)",

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Wang, H, Min, S, Ma, C, Liu, Z, Zhang, W, Wang, Q, Li, D, Li, Y, Turner, S, Han, Y, Zhu, H, Abou-Hamad, E, Hedhili, MN, Pan, J, Yu, W, Huang, K-W, Li, L-J, Yuan, J, Antonietti, M & Wu, T 2017, 'Synthesis of single-crystal-like nanoporous carbon membranes and their application in overall water splitting', Nature Communications, vol. 8, no. 1. https://doi.org/10.1038/ncomms13592

TY - JOUR

T1 - Synthesis of single-crystal-like nanoporous carbon membranes and their application in overall water splitting

AU - Wang, Hong

AU - Min, Shixiong

AU - Ma, Chun

AU - Liu, Zhixiong

AU - Zhang, Weiyi

AU - Wang, Qiang

AU - Li, Debao

AU - Li, Yangyang

AU - Turner, Stuart

AU - Han, Yu

AU - Zhu, Haibo

AU - Abou-Hamad, Edy

AU - Hedhili, Mohamed N.

AU - Pan, Jun

AU - Yu, Weili

AU - Huang, Kuo-Wei

AU - Li, Lain-Jong

AU - Yuan, Jiayin

AU - Antonietti, Markus

AU - Wu, Tao

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: We thank the King Abdullah University of Science and Technology (KAUST) for financial support. J.Y. is grateful for financial support from the Max Planck society, Germany, and the ERC (European Research Council) Starting Grant (project number 639720-NAPOLI).

PY - 2017/1/4

Y1 - 2017/1/4

N2 - Nanoporous graphitic carbon membranes with defined chemical composition and pore architecture are novel nanomaterials that are actively pursued. Compared with easy-to-make porous carbon powders that dominate the porous carbon research and applications in energy generation/conversion and environmental remediation, porous carbon membranes are synthetically more challenging though rather appealing from an application perspective due to their structural integrity, interconnectivity and purity. Here we report a simple bottom–up approach to fabricate large-size, freestanding and porous carbon membranes that feature an unusual single-crystal-like graphitic order and hierarchical pore architecture plus favourable nitrogen doping. When loaded with cobalt nanoparticles, such carbon membranes serve as high-performance carbon-based non-noble metal electrocatalyst for overall water splitting.

AB - Nanoporous graphitic carbon membranes with defined chemical composition and pore architecture are novel nanomaterials that are actively pursued. Compared with easy-to-make porous carbon powders that dominate the porous carbon research and applications in energy generation/conversion and environmental remediation, porous carbon membranes are synthetically more challenging though rather appealing from an application perspective due to their structural integrity, interconnectivity and purity. Here we report a simple bottom–up approach to fabricate large-size, freestanding and porous carbon membranes that feature an unusual single-crystal-like graphitic order and hierarchical pore architecture plus favourable nitrogen doping. When loaded with cobalt nanoparticles, such carbon membranes serve as high-performance carbon-based non-noble metal electrocatalyst for overall water splitting.

UR - http://hdl.handle.net/10754/622671

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VL - 8

JO - Nature Communications

JF - Nature Communications

IS - 1

ER -

Synthesis of single-crystal-like nanoporous carbon membranes and their application in overall water splitting

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