Synthesis, structure, and polymerization activity of a titanium complex with a chelating [(hydroxy-κO)amino-κN]phenolato(2-)-κO ligand

Bradley M. Kraft; Kuo Wei Huang; Adam P. Cole; Robert M. Waymouth

doi:10.1002/hlca.200690159

Synthesis, structure, and polymerization activity of a titanium complex with a chelating [(hydroxy-κO)amino-κN]phenolato(2-)-κO ligand

Bradley M. Kraft, Kuo Wei Huang, Adam P. Cole, Robert M. Waymouth^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A novel titanium complex with a chelating nitroxide ligand, dichloro-2-{[(hydroxy-κO)phenylamino-κN)phenylmethyl]phenolato(2-) -2κO}(tetrahydrofuran)titanium (1), was synthesized and characterized by NMR spectroscopy, elemental analysis, and single-crystal X-ray crystallography. In the presence of methylaluminoxane (MAO), 1 displayed moderate activity for the polymerization of propylene.

Original language	English (US)
Pages (from-to)	1589-1595
Number of pages	7
Journal	Helvetica Chimica Acta
Volume	89
Issue number	8
DOIs	https://doi.org/10.1002/hlca.200690159
State	Published - 2006
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Biochemistry
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1002/hlca.200690159

Cite this

@article{c72a9c0504ea4cad8f57ae9946f8ccd2,

title = "Synthesis, structure, and polymerization activity of a titanium complex with a chelating [(hydroxy-κO)amino-κN]phenolato(2-)-κO ligand",

abstract = "A novel titanium complex with a chelating nitroxide ligand, dichloro-2-{[(hydroxy-κO)phenylamino-κN)phenylmethyl]phenolato(2-) -2κO}(tetrahydrofuran)titanium (1), was synthesized and characterized by NMR spectroscopy, elemental analysis, and single-crystal X-ray crystallography. In the presence of methylaluminoxane (MAO), 1 displayed moderate activity for the polymerization of propylene.",

author = "Kraft, {Bradley M.} and Huang, {Kuo Wei} and Cole, {Adam P.} and Waymouth, {Robert M.}",

year = "2006",

doi = "10.1002/hlca.200690159",

language = "English (US)",

volume = "89",

pages = "1589--1595",

journal = "Helvetica Chimica Acta",

issn = "0018-019X",

publisher = "Wiley-Blackwell",

number = "8",

}

TY - JOUR

T1 - Synthesis, structure, and polymerization activity of a titanium complex with a chelating [(hydroxy-κO)amino-κN]phenolato(2-)-κO ligand

AU - Kraft, Bradley M.

AU - Huang, Kuo Wei

AU - Cole, Adam P.

AU - Waymouth, Robert M.

PY - 2006

Y1 - 2006

N2 - A novel titanium complex with a chelating nitroxide ligand, dichloro-2-{[(hydroxy-κO)phenylamino-κN)phenylmethyl]phenolato(2-) -2κO}(tetrahydrofuran)titanium (1), was synthesized and characterized by NMR spectroscopy, elemental analysis, and single-crystal X-ray crystallography. In the presence of methylaluminoxane (MAO), 1 displayed moderate activity for the polymerization of propylene.

AB - A novel titanium complex with a chelating nitroxide ligand, dichloro-2-{[(hydroxy-κO)phenylamino-κN)phenylmethyl]phenolato(2-) -2κO}(tetrahydrofuran)titanium (1), was synthesized and characterized by NMR spectroscopy, elemental analysis, and single-crystal X-ray crystallography. In the presence of methylaluminoxane (MAO), 1 displayed moderate activity for the polymerization of propylene.

UR - http://www.scopus.com/inward/record.url?scp=33748453386&partnerID=8YFLogxK

U2 - 10.1002/hlca.200690159

DO - 10.1002/hlca.200690159

M3 - Article

AN - SCOPUS:33748453386

SN - 0018-019X

VL - 89

SP - 1589

EP - 1595

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 8

ER -

Synthesis, structure, and polymerization activity of a titanium complex with a chelating [(hydroxy-κO)amino-κN]phenolato(2-)-κO ligand

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this