TY - JOUR
T1 - Synthesis, structures and physical properties of new 3D lanthanide coordination polymers constructed from 1,2,4,5-benzenetetracarboxylic acid
AU - Zhang, Hua Bin
AU - Tian, Chong Bin
AU - Wu, Shu Ting
AU - Lin, Jian Di
AU - Li, Zhi Hua
AU - Du, Shao Wu
N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15
PY - 2011/1/31
Y1 - 2011/1/31
N2 - A series of new 3D coordination polymers Ln2(BTC) 1.5(H2O)(DMSO) (Ln=Eu(1), Gd(2), Tb(3), Dy(4), Ho(5)) (H4BTC = 1,2,4,5-benzenetetracarboxylic acid) have been solvothermal synthesized by the reactions of lanthanide ions with 1,2,4,5- benzenetetracarboxylic acid in a DMSO/H2O solution. These compounds possess the same 3D architectures based on dinuclear lanthanide SBUs {Tb 2O4} linked by BTC4- anions and exhibit unprecedented 3D topological nets. Compounds 1 and 3 are strong luminescent materials which display characteristic Eu3+ and Tb3+ emission bands in the visible region. The magnetic properties of 2-5 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. © 2010 Elsevier B.V. All rights reserved.
AB - A series of new 3D coordination polymers Ln2(BTC) 1.5(H2O)(DMSO) (Ln=Eu(1), Gd(2), Tb(3), Dy(4), Ho(5)) (H4BTC = 1,2,4,5-benzenetetracarboxylic acid) have been solvothermal synthesized by the reactions of lanthanide ions with 1,2,4,5- benzenetetracarboxylic acid in a DMSO/H2O solution. These compounds possess the same 3D architectures based on dinuclear lanthanide SBUs {Tb 2O4} linked by BTC4- anions and exhibit unprecedented 3D topological nets. Compounds 1 and 3 are strong luminescent materials which display characteristic Eu3+ and Tb3+ emission bands in the visible region. The magnetic properties of 2-5 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. © 2010 Elsevier B.V. All rights reserved.
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022286010008860
UR - http://www.scopus.com/inward/record.url?scp=78650680040&partnerID=8YFLogxK
U2 - 10.1016/j.molstruc.2010.11.020
DO - 10.1016/j.molstruc.2010.11.020
M3 - Article
SN - 0022-2860
VL - 985
SP - 355
EP - 360
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
IS - 2-3
ER -