Synthesis, structures and physical properties of new 3D lanthanide coordination polymers constructed from 1,2,4,5-benzenetetracarboxylic acid

Hua Bin Zhang; Chong Bin Tian; Shu Ting Wu; Jian Di Lin; Zhi Hua Li; Shao Wu Du

doi:10.1016/j.molstruc.2010.11.020

Synthesis, structures and physical properties of new 3D lanthanide coordination polymers constructed from 1,2,4,5-benzenetetracarboxylic acid

Hua Bin Zhang, Chong Bin Tian, Shu Ting Wu, Jian Di Lin, Zhi Hua Li, Shao Wu Du

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A series of new 3D coordination polymers Ln2(BTC) 1.5(H2O)(DMSO) (Ln=Eu(1), Gd(2), Tb(3), Dy(4), Ho(5)) (H4BTC = 1,2,4,5-benzenetetracarboxylic acid) have been solvothermal synthesized by the reactions of lanthanide ions with 1,2,4,5- benzenetetracarboxylic acid in a DMSO/H2O solution. These compounds possess the same 3D architectures based on dinuclear lanthanide SBUs {Tb 2O4} linked by BTC4- anions and exhibit unprecedented 3D topological nets. Compounds 1 and 3 are strong luminescent materials which display characteristic Eu3+ and Tb3+ emission bands in the visible region. The magnetic properties of 2-5 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. © 2010 Elsevier B.V. All rights reserved.

Original language	English (US)
Pages (from-to)	355-360
Number of pages	6
Journal	Journal of Molecular Structure
Volume	985
Issue number	2-3
DOIs	https://doi.org/10.1016/j.molstruc.2010.11.020
State	Published - Jan 31 2011
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry
Spectroscopy
Analytical Chemistry
Inorganic Chemistry

Access to Document

10.1016/j.molstruc.2010.11.020

Cite this

@article{01c38ea7575c4ece943aab68b22e221e,

title = "Synthesis, structures and physical properties of new 3D lanthanide coordination polymers constructed from 1,2,4,5-benzenetetracarboxylic acid",

abstract = "A series of new 3D coordination polymers Ln2(BTC) 1.5(H2O)(DMSO) (Ln=Eu(1), Gd(2), Tb(3), Dy(4), Ho(5)) (H4BTC = 1,2,4,5-benzenetetracarboxylic acid) have been solvothermal synthesized by the reactions of lanthanide ions with 1,2,4,5- benzenetetracarboxylic acid in a DMSO/H2O solution. These compounds possess the same 3D architectures based on dinuclear lanthanide SBUs {Tb 2O4} linked by BTC4- anions and exhibit unprecedented 3D topological nets. Compounds 1 and 3 are strong luminescent materials which display characteristic Eu3+ and Tb3+ emission bands in the visible region. The magnetic properties of 2-5 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. {\textcopyright} 2010 Elsevier B.V. All rights reserved.",

author = "Zhang, {Hua Bin} and Tian, {Chong Bin} and Wu, {Shu Ting} and Lin, {Jian Di} and Li, {Zhi Hua} and Du, {Shao Wu}",

note = "Generated from Scopus record by KAUST IRTS on 2022-09-15",

year = "2011",

month = jan,

day = "31",

doi = "10.1016/j.molstruc.2010.11.020",

language = "English (US)",

volume = "985",

pages = "355--360",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

number = "2-3",

}

TY - JOUR

T1 - Synthesis, structures and physical properties of new 3D lanthanide coordination polymers constructed from 1,2,4,5-benzenetetracarboxylic acid

AU - Zhang, Hua Bin

AU - Tian, Chong Bin

AU - Wu, Shu Ting

AU - Lin, Jian Di

AU - Li, Zhi Hua

AU - Du, Shao Wu

N1 - Generated from Scopus record by KAUST IRTS on 2022-09-15

PY - 2011/1/31

Y1 - 2011/1/31

N2 - A series of new 3D coordination polymers Ln2(BTC) 1.5(H2O)(DMSO) (Ln=Eu(1), Gd(2), Tb(3), Dy(4), Ho(5)) (H4BTC = 1,2,4,5-benzenetetracarboxylic acid) have been solvothermal synthesized by the reactions of lanthanide ions with 1,2,4,5- benzenetetracarboxylic acid in a DMSO/H2O solution. These compounds possess the same 3D architectures based on dinuclear lanthanide SBUs {Tb 2O4} linked by BTC4- anions and exhibit unprecedented 3D topological nets. Compounds 1 and 3 are strong luminescent materials which display characteristic Eu3+ and Tb3+ emission bands in the visible region. The magnetic properties of 2-5 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. © 2010 Elsevier B.V. All rights reserved.

AB - A series of new 3D coordination polymers Ln2(BTC) 1.5(H2O)(DMSO) (Ln=Eu(1), Gd(2), Tb(3), Dy(4), Ho(5)) (H4BTC = 1,2,4,5-benzenetetracarboxylic acid) have been solvothermal synthesized by the reactions of lanthanide ions with 1,2,4,5- benzenetetracarboxylic acid in a DMSO/H2O solution. These compounds possess the same 3D architectures based on dinuclear lanthanide SBUs {Tb 2O4} linked by BTC4- anions and exhibit unprecedented 3D topological nets. Compounds 1 and 3 are strong luminescent materials which display characteristic Eu3+ and Tb3+ emission bands in the visible region. The magnetic properties of 2-5 have also been investigated through the measurement of their magnetic susceptibilities over the temperature range of 2-300 K. © 2010 Elsevier B.V. All rights reserved.

UR - https://linkinghub.elsevier.com/retrieve/pii/S0022286010008860

UR - http://www.scopus.com/inward/record.url?scp=78650680040&partnerID=8YFLogxK

U2 - 10.1016/j.molstruc.2010.11.020

DO - 10.1016/j.molstruc.2010.11.020

M3 - Article

SN - 0022-2860

VL - 985

SP - 355

EP - 360

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 2-3

ER -

Synthesis, structures and physical properties of new 3D lanthanide coordination polymers constructed from 1,2,4,5-benzenetetracarboxylic acid

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this