Tailor-Made Microporous Metal-Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion

Hao Wang; Xinglong Dong; Valentina Colombo; Qining Wang; Yanyao Liu; Wei Liu; Xin-Long Wang; Xiao-Ying Huang; Davide M. Proserpio; Angelo Sironi; Yu Han; Jing Li

doi:10.1002/adma.201805088

Tailor-Made Microporous Metal-Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion

Hao Wang, Xinglong Dong, Valentina Colombo, Qining Wang, Yanyao Liu, Wei Liu, Xin-Long Wang, Xiao-Ying Huang, Davide M. Proserpio, Angelo Sironi, Yu Han, Jing Li

Research output: Contribution to journal › Article › peer-review

254 Scopus citations

Abstract

Adsorptive separation of olefin/paraffin mixtures by porous solids can greatly reduce the energy consumption associated with the currently employed cryogenic distillation technique. Here, the complete separation of propane and propylene by a designer microporous metal-organic framework material is reported. The compound, Y6 (OH)8 (abtc)3 (H2 O)6 (DMA)2 (Y-abtc, abtc = 3,3',5,5'-azobenzene-tetracarboxylates; DMA = dimethylammonium), is rationally designed through topology-guided replacement of inorganic building units. Y-abtc is both thermally and hydrothermally robust, and possesses optimal pore window size for propane/propylene separation. It adsorbs propylene with fast kinetics under ambient temperature and pressure, but fully excludes propane, as a result of selective size exclusion. Multicomponent column breakthrough experiments confirm that polymer-grade propylene (99.5%) can be obtained by this process, demonstrating its true potential as an alternative sorbent for efficient separation of propane/propylene mixtures.

Original language	English (US)
Pages (from-to)	1805088
Journal	Advanced Materials
Volume	30
Issue number	49
DOIs	https://doi.org/10.1002/adma.201805088
State	Published - Oct 15 2018

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10.1002/adma.201805088

https://repository.kaust.edu.sa/bitstream/10754/629501/1/adma201805088.pdf

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@article{8bd6e2fd1b644ad68f081109d321a4a9,

title = "Tailor-Made Microporous Metal-Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion",

abstract = "Adsorptive separation of olefin/paraffin mixtures by porous solids can greatly reduce the energy consumption associated with the currently employed cryogenic distillation technique. Here, the complete separation of propane and propylene by a designer microporous metal-organic framework material is reported. The compound, Y6 (OH)8 (abtc)3 (H2 O)6 (DMA)2 (Y-abtc, abtc = 3,3',5,5'-azobenzene-tetracarboxylates; DMA = dimethylammonium), is rationally designed through topology-guided replacement of inorganic building units. Y-abtc is both thermally and hydrothermally robust, and possesses optimal pore window size for propane/propylene separation. It adsorbs propylene with fast kinetics under ambient temperature and pressure, but fully excludes propane, as a result of selective size exclusion. Multicomponent column breakthrough experiments confirm that polymer-grade propylene (99.5%) can be obtained by this process, demonstrating its true potential as an alternative sorbent for efficient separation of propane/propylene mixtures.",

author = "Hao Wang and Xinglong Dong and Valentina Colombo and Qining Wang and Yanyao Liu and Wei Liu and Xin-Long Wang and Xiao-Ying Huang and Proserpio, {Davide M.} and Angelo Sironi and Yu Han and Jing Li",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors would like to thank the financial support from the Materials Sciences and Engineering Division, Office of Basic Research Energy Sciences of the U.S. Department of Energy under Grant No. DE-FG02-08ER-46491 for the synthesis, characterization, and single-component adsorption work. Y.H. acknowledges the KAUST CCF fund for the breakthrough experiments. The RU team would also like to acknowledge Micromeritics Instrument Corp. for the award of a 3Flex system through its Instrument Grant program. V.C thanks the University of Milan for partial funding through the Development Plan of Athenaeum grant.",

year = "2018",

month = oct,

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doi = "10.1002/adma.201805088",

language = "English (US)",

volume = "30",

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journal = "Advanced Materials",

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T1 - Tailor-Made Microporous Metal-Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion

AU - Wang, Hao

AU - Dong, Xinglong

AU - Colombo, Valentina

AU - Wang, Qining

AU - Liu, Yanyao

AU - Liu, Wei

AU - Wang, Xin-Long

AU - Huang, Xiao-Ying

AU - Proserpio, Davide M.

AU - Sironi, Angelo

AU - Han, Yu

AU - Li, Jing

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledgements: The authors would like to thank the financial support from the Materials Sciences and Engineering Division, Office of Basic Research Energy Sciences of the U.S. Department of Energy under Grant No. DE-FG02-08ER-46491 for the synthesis, characterization, and single-component adsorption work. Y.H. acknowledges the KAUST CCF fund for the breakthrough experiments. The RU team would also like to acknowledge Micromeritics Instrument Corp. for the award of a 3Flex system through its Instrument Grant program. V.C thanks the University of Milan for partial funding through the Development Plan of Athenaeum grant.

PY - 2018/10/15

Y1 - 2018/10/15

N2 - Adsorptive separation of olefin/paraffin mixtures by porous solids can greatly reduce the energy consumption associated with the currently employed cryogenic distillation technique. Here, the complete separation of propane and propylene by a designer microporous metal-organic framework material is reported. The compound, Y6 (OH)8 (abtc)3 (H2 O)6 (DMA)2 (Y-abtc, abtc = 3,3',5,5'-azobenzene-tetracarboxylates; DMA = dimethylammonium), is rationally designed through topology-guided replacement of inorganic building units. Y-abtc is both thermally and hydrothermally robust, and possesses optimal pore window size for propane/propylene separation. It adsorbs propylene with fast kinetics under ambient temperature and pressure, but fully excludes propane, as a result of selective size exclusion. Multicomponent column breakthrough experiments confirm that polymer-grade propylene (99.5%) can be obtained by this process, demonstrating its true potential as an alternative sorbent for efficient separation of propane/propylene mixtures.

AB - Adsorptive separation of olefin/paraffin mixtures by porous solids can greatly reduce the energy consumption associated with the currently employed cryogenic distillation technique. Here, the complete separation of propane and propylene by a designer microporous metal-organic framework material is reported. The compound, Y6 (OH)8 (abtc)3 (H2 O)6 (DMA)2 (Y-abtc, abtc = 3,3',5,5'-azobenzene-tetracarboxylates; DMA = dimethylammonium), is rationally designed through topology-guided replacement of inorganic building units. Y-abtc is both thermally and hydrothermally robust, and possesses optimal pore window size for propane/propylene separation. It adsorbs propylene with fast kinetics under ambient temperature and pressure, but fully excludes propane, as a result of selective size exclusion. Multicomponent column breakthrough experiments confirm that polymer-grade propylene (99.5%) can be obtained by this process, demonstrating its true potential as an alternative sorbent for efficient separation of propane/propylene mixtures.

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U2 - 10.1002/adma.201805088

DO - 10.1002/adma.201805088

M3 - Article

C2 - 30368929

SN - 0935-9648

VL - 30

SP - 1805088

JO - Advanced Materials

JF - Advanced Materials

IS - 49

ER -

Tailor-Made Microporous Metal-Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion

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CCDC 1856158: Experimental Crystal Structure Determination : catena-[bis(dimethylammonium) tris(mu-3,3',5,5'-azobenzene-tetracarboxylato)-octakis(mu-hydroxo)-hexa-aqua-hexa-yttrium(iii)]

CCDC 1853121: Experimental Crystal Structure Determination : catena-[tetrakis(dimethylammonium) hexakis(mu-biphenyl-3,3',5,5'-tetracarboxylato)-hexadecakis(mu-hydroxo)-dodeca-aqua-dodeca-yttrium unknown solvate]

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Tailor-Made Microporous Metal-Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion

Abstract

UN SDGs

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Datasets

CCDC 1856158: Experimental Crystal Structure Determination : catena-[bis(dimethylammonium) tris(mu-3,3',5,5'-azobenzene-tetracarboxylato)-octakis(mu-hydroxo)-hexa-aqua-hexa-yttrium(iii)]

CCDC 1853121: Experimental Crystal Structure Determination : catena-[tetrakis(dimethylammonium) hexakis(mu-biphenyl-3,3',5,5'-tetracarboxylato)-hexadecakis(mu-hydroxo)-dodeca-aqua-dodeca-yttrium unknown solvate]

Cite this