Temperature and concentration control over interpenetration in a metal-organic material

Jian Jun Zhang; Lukasz Wojtas; Randy W. Larsen; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1021/ja906911q

Temperature and concentration control over interpenetration in a metal-organic material

Jian Jun Zhang, Lukasz Wojtas, Randy W. Larsen, Mohamed Eddaoudi, Michael J. Zaworotko

Physical Sciences and Engineering

Research output: Contribution to journal › Article › peer-review

376 Scopus citations

Abstract

(Figure Presented) A pillared framework formed from 4,4′-bipyridine (bipy) and sheets of dinuclear Cd₂ nodes and 1,4-benzenedicarboxylic acid (bdc) linkers can be prepared in both interpenetrated and noninterpenetrated forms by simply varying the temperature or concentration of the reaction. These results demonstrate that higher temperatures and concentrations favor interpenetration over the corresponding noninterpenetrating structure, an observation that could have broad implications for controlling the synthesis of metal-organic materials.

Original language	English (US)
Pages (from-to)	17040-17041
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	47
DOIs	https://doi.org/10.1021/ja906911q
State	Published - Dec 2 2009

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja906911q

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title = "Temperature and concentration control over interpenetration in a metal-organic material",

abstract = "(Figure Presented) A pillared framework formed from 4,4′-bipyridine (bipy) and sheets of dinuclear Cd2 nodes and 1,4-benzenedicarboxylic acid (bdc) linkers can be prepared in both interpenetrated and noninterpenetrated forms by simply varying the temperature or concentration of the reaction. These results demonstrate that higher temperatures and concentrations favor interpenetration over the corresponding noninterpenetrating structure, an observation that could have broad implications for controlling the synthesis of metal-organic materials.",

author = "Zhang, {Jian Jun} and Lukasz Wojtas and Larsen, {Randy W.} and Mohamed Eddaoudi and Zaworotko, {Michael J.}",

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T1 - Temperature and concentration control over interpenetration in a metal-organic material

AU - Zhang, Jian Jun

AU - Wojtas, Lukasz

AU - Larsen, Randy W.

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

PY - 2009/12/2

Y1 - 2009/12/2

N2 - (Figure Presented) A pillared framework formed from 4,4′-bipyridine (bipy) and sheets of dinuclear Cd2 nodes and 1,4-benzenedicarboxylic acid (bdc) linkers can be prepared in both interpenetrated and noninterpenetrated forms by simply varying the temperature or concentration of the reaction. These results demonstrate that higher temperatures and concentrations favor interpenetration over the corresponding noninterpenetrating structure, an observation that could have broad implications for controlling the synthesis of metal-organic materials.

AB - (Figure Presented) A pillared framework formed from 4,4′-bipyridine (bipy) and sheets of dinuclear Cd2 nodes and 1,4-benzenedicarboxylic acid (bdc) linkers can be prepared in both interpenetrated and noninterpenetrated forms by simply varying the temperature or concentration of the reaction. These results demonstrate that higher temperatures and concentrations favor interpenetration over the corresponding noninterpenetrating structure, an observation that could have broad implications for controlling the synthesis of metal-organic materials.

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U2 - 10.1021/ja906911q

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 47

ER -

Temperature and concentration control over interpenetration in a metal-organic material

Abstract

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