Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins

Zhenjie Zhang; Linping Zhang; Łukasz Wojtas; Mohamed Eddaoudi; Michael J. Zaworotko

doi:10.1021/ja208256u

Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins

Zhenjie Zhang, Linping Zhang, Łukasz Wojtas, Mohamed Eddaoudi, Michael J. Zaworotko

Research output: Contribution to journal › Article › peer-review

170 Scopus citations

Abstract

meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins. © 2011 American Chemical Society.

Original language	English (US)
Pages (from-to)	928-933
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	134
Issue number	2
DOIs	https://doi.org/10.1021/ja208256u
State	Published - Dec 29 2011

ASJC Scopus subject areas

Biochemistry
Colloid and Surface Chemistry
General Chemistry
Catalysis

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10.1021/ja208256u

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@article{8b0d4dc29a35421c9452b1cfed9cc374,

title = "Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins",

abstract = "meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins. {\textcopyright} 2011 American Chemical Society.",

author = "Zhenjie Zhang and Linping Zhang and {\L}ukasz Wojtas and Mohamed Eddaoudi and Zaworotko, {Michael J.}",

note = "KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/06 Acknowledgements: This publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST). The data for porph@MOM-5, -6, and -9 were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation and the Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.",

year = "2011",

month = dec,

day = "29",

doi = "10.1021/ja208256u",

language = "English (US)",

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T1 - Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins

AU - Zhang, Zhenjie

AU - Zhang, Linping

AU - Wojtas, Łukasz

AU - Eddaoudi, Mohamed

AU - Zaworotko, Michael J.

N1 - KAUST Repository Item: Exported on 2020-10-01 Acknowledged KAUST grant number(s): FIC/2010/06 Acknowledgements: This publication is based on work supported by Award FIC/2010/06 made by King Abdullah University of Science and Technology (KAUST). The data for porph@MOM-5, -6, and -9 were collected at the Advanced Photon Source on beamline 15ID-C of ChemMatCARS Sector 15, which is principally supported by the National Science Foundation and the Department of Energy under Grant NSF/CHE-0822838. The Advanced Photon Source is supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, under Contract DE-AC02-06CH11357.

PY - 2011/12/29

Y1 - 2011/12/29

N2 - meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins. © 2011 American Chemical Society.

AB - meso-Tetra(N-methyl-4-pyridyl)porphine tetratosylate (TMPyP) templates the synthesis of six new metal-organic materials by the reaction of benzene-1,3,5-tricarboxylate with transition metals, five of which exhibit HKUST-1 or tbo topology (M = Fe, Mn, Co, Ni, Mg). The resulting materials, porph@MOMs, selectively encapsulate the corresponding metalloporphyrins in octahemioctahedral cages and can serve as size-selective heterogeneous catalysts for oxidation of olefins. © 2011 American Chemical Society.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 2

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Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins

Abstract

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CCDC 877427: Experimental Crystal Structure Determination : catena-(octakis(mu~6~-Benzene-1,3,5-tricarboxylato)-dodeca-aqua-dodeca-manganese (5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato)-manganese chloride)

CCDC 877431: Experimental Crystal Structure Determination : catena-(octakis(mu~6~-Benzene-1,3,5-tricarboxylato)-dodeca-aqua-dodeca-cobalt (5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato)-cobalt chloride hydrate)

CCDC 877430: Experimental Crystal Structure Determination : catena-(octakis(mu~6~-Benzene-1,3,5-tricarboxylato)-dodeca-aqua-dodeca-iron hemikis((5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato)-iron) chloride)

Cite this

Template-directed synthesis of nets based upon octahemioctahedral cages that encapsulate catalytically active metalloporphyrins

Abstract

ASJC Scopus subject areas

Access to Document

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Fingerprint

Datasets

CCDC 877427: Experimental Crystal Structure Determination : catena-(octakis(mu~6~-Benzene-1,3,5-tricarboxylato)-dodeca-aqua-dodeca-manganese (5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato)-manganese chloride)

CCDC 877431: Experimental Crystal Structure Determination : catena-(octakis(mu~6~-Benzene-1,3,5-tricarboxylato)-dodeca-aqua-dodeca-cobalt (5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato)-cobalt chloride hydrate)

CCDC 877430: Experimental Crystal Structure Determination : catena-(octakis(mu~6~-Benzene-1,3,5-tricarboxylato)-dodeca-aqua-dodeca-iron hemikis((5,10,15,20-tetrakis(N-methylpyridinium-4-yl)porphyrinato)-iron) chloride)

Cite this