tert-Butyllithium, a selective and convenient reagent for the reductive intercalation of interstitial solids: A novel room temperature synthesis of (LiMo3Se3)n, a soluble polymeric chevrel cluster compound

J. H. Golden; F. J. DiSalvo; J. M.J. Frechet

tert-Butyllithium, a selective and convenient reagent for the reductive intercalation of interstitial solids: A novel room temperature synthesis of (LiMo₃Se₃)_n, a soluble polymeric chevrel cluster compound

J. H. Golden^*, F. J. DiSalvo, J. M.J. Frechet

^*Corresponding author for this work

Research output: Contribution to journal › Conference article › peer-review

3 Scopus citations

Abstract

As part of our ongoing study of the polar solvent soluble inorganic polymer (LiMo₃Se₃)_n, we have investigated its synthesis via the heterogenous reductive intercalation of (InMo₃Se₃)_n with a variety of organolithium reagents at room temperature. Herein we describe the results of our investigation of the soft chemical synthesis of (LiMo₃Se₃)_n, and the determination of the reducing potential of tert-butyllithium vs. the intercalable rutile solid WO₂.

Original language	English (US)
Pages (from-to)	209-212
Number of pages	4
Journal	Materials Science Forum
Volume	152-5
State	Published - 1994
Externally published	Yes
Event	Proceedings of the International Symposium on Soft Chemistry Routes to New Materials - Nantes, Fr Duration: Sep 6 1993 → Sep 10 1993

ASJC Scopus subject areas

Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
General Materials Science

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@article{a26e175725164ecf8113d2c1d2938078,

title = "tert-Butyllithium, a selective and convenient reagent for the reductive intercalation of interstitial solids: A novel room temperature synthesis of (LiMo3Se3)n, a soluble polymeric chevrel cluster compound",

abstract = "As part of our ongoing study of the polar solvent soluble inorganic polymer (LiMo3Se3)n, we have investigated its synthesis via the heterogenous reductive intercalation of (InMo3Se3)n with a variety of organolithium reagents at room temperature. Herein we describe the results of our investigation of the soft chemical synthesis of (LiMo3Se3)n, and the determination of the reducing potential of tert-butyllithium vs. the intercalable rutile solid WO2.",

author = "Golden, {J. H.} and DiSalvo, {F. J.} and Frechet, {J. M.J.}",

year = "1994",

language = "English (US)",

volume = "152-5",

pages = "209--212",

journal = "Materials Science Forum",

issn = "0255-5476",

publisher = "Trans Tech Publications Ltd",

note = "Proceedings of the International Symposium on Soft Chemistry Routes to New Materials ; Conference date: 06-09-1993 Through 10-09-1993",

}

tert-Butyllithium, a selective and convenient reagent for the reductive intercalation of interstitial solids: A novel room temperature synthesis of (LiMo₃Se₃)_n, a soluble polymeric chevrel cluster compound. / Golden, J. H.; DiSalvo, F. J.; Frechet, J. M.J.
In: Materials Science Forum, Vol. 152-5, 1994, p. 209-212.

Research output: Contribution to journal › Conference article › peer-review

TY - JOUR

T1 - tert-Butyllithium, a selective and convenient reagent for the reductive intercalation of interstitial solids

T2 - Proceedings of the International Symposium on Soft Chemistry Routes to New Materials

AU - Golden, J. H.

AU - DiSalvo, F. J.

AU - Frechet, J. M.J.

PY - 1994

Y1 - 1994

N2 - As part of our ongoing study of the polar solvent soluble inorganic polymer (LiMo3Se3)n, we have investigated its synthesis via the heterogenous reductive intercalation of (InMo3Se3)n with a variety of organolithium reagents at room temperature. Herein we describe the results of our investigation of the soft chemical synthesis of (LiMo3Se3)n, and the determination of the reducing potential of tert-butyllithium vs. the intercalable rutile solid WO2.

AB - As part of our ongoing study of the polar solvent soluble inorganic polymer (LiMo3Se3)n, we have investigated its synthesis via the heterogenous reductive intercalation of (InMo3Se3)n with a variety of organolithium reagents at room temperature. Herein we describe the results of our investigation of the soft chemical synthesis of (LiMo3Se3)n, and the determination of the reducing potential of tert-butyllithium vs. the intercalable rutile solid WO2.

UR - http://www.scopus.com/inward/record.url?scp=0028666351&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0028666351

SN - 0255-5476

VL - 152-5

SP - 209

EP - 212

JO - Materials Science Forum

JF - Materials Science Forum

Y2 - 6 September 1993 through 10 September 1993