The First Direct Formation of a Grignard Reagent on an Insoluble Polymer

S. Itsuno; G. D. Darling; H. D.H. Stöver; J. M.J. Frechét

doi:10.1021/jo00229a052

The First Direct Formation of a Grignard Reagent on an Insoluble Polymer

S. Itsuno, G. D. Darling, H. D.H. Stöver, J. M.J. Frechét^*

^*Corresponding author for this work

Research output: Contribution to journal › Letter › peer-review

32 Scopus citations

Abstract

Reaction of the normally mutually unreactive magnesium and solid halogenated polymers has been accomplished by using a magnesium-anthracene/THF complex to afford a high yield of the reactive Grignard polymers.

Original language	English (US)
Pages (from-to)	4644-4645
Number of pages	2
Journal	Journal of Organic Chemistry
Volume	52
Issue number	20
DOIs	https://doi.org/10.1021/jo00229a052
State	Published - Oct 1 1987
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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@article{97ccdfbfe2724845a73f7ef87ce9235d,

title = "The First Direct Formation of a Grignard Reagent on an Insoluble Polymer",

abstract = "Reaction of the normally mutually unreactive magnesium and solid halogenated polymers has been accomplished by using a magnesium-anthracene/THF complex to afford a high yield of the reactive Grignard polymers.",

author = "S. Itsuno and Darling, {G. D.} and St{\"o}ver, {H. D.H.} and Frech{\'e}t, {J. M.J.}",

year = "1987",

month = oct,

day = "1",

doi = "10.1021/jo00229a052",

language = "English (US)",

volume = "52",

pages = "4644--4645",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "20",

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T1 - The First Direct Formation of a Grignard Reagent on an Insoluble Polymer

AU - Itsuno, S.

AU - Darling, G. D.

AU - Stöver, H. D.H.

AU - Frechét, J. M.J.

PY - 1987/10/1

Y1 - 1987/10/1

N2 - Reaction of the normally mutually unreactive magnesium and solid halogenated polymers has been accomplished by using a magnesium-anthracene/THF complex to afford a high yield of the reactive Grignard polymers.

AB - Reaction of the normally mutually unreactive magnesium and solid halogenated polymers has been accomplished by using a magnesium-anthracene/THF complex to afford a high yield of the reactive Grignard polymers.

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U2 - 10.1021/jo00229a052

DO - 10.1021/jo00229a052

M3 - Letter

AN - SCOPUS:33845283136

SN - 0022-3263

VL - 52

SP - 4644

EP - 4645

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 20

ER -

The First Direct Formation of a Grignard Reagent on an Insoluble Polymer

Abstract

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