The generation of hydroxide and methoxide ions by photo-irradiation: Use of aromatization to stabilize ionic photo-products from acridine derivatives

Aaron J. Ackmann; Jean M.J. Fréchet

doi:10.1039/CC9960000605

The generation of hydroxide and methoxide ions by photo-irradiation: Use of aromatization to stabilize ionic photo-products from acridine derivatives

Aaron J. Ackmann, Jean M.J. Fréchet^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The photolysis of 9-hydroxy-10-methyl-9-phenyl-9,10-dihydroacridine 1 or its 9-methoxy derivative 2 occurs with heterolytic cleavage of a C-O bond and formation of the desired strong base together with a cation that stabilizes itself through aromatization.

Original language	English (US)
Pages (from-to)	605-606
Number of pages	2
Journal	CHEMICAL COMMUNICATIONS
Issue number	5
DOIs	https://doi.org/10.1039/CC9960000605
State	Published - 1996
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/CC9960000605

Cite this

@article{6483f5035a6b4d0d8aa72607a7ea2485,

title = "The generation of hydroxide and methoxide ions by photo-irradiation: Use of aromatization to stabilize ionic photo-products from acridine derivatives",

abstract = "The photolysis of 9-hydroxy-10-methyl-9-phenyl-9,10-dihydroacridine 1 or its 9-methoxy derivative 2 occurs with heterolytic cleavage of a C-O bond and formation of the desired strong base together with a cation that stabilizes itself through aromatization.",

author = "Ackmann, {Aaron J.} and Fr{\'e}chet, {Jean M.J.}",

year = "1996",

doi = "10.1039/CC9960000605",

language = "English (US)",

pages = "605--606",

journal = "CHEMICAL COMMUNICATIONS",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

number = "5",

}

TY - JOUR

T1 - The generation of hydroxide and methoxide ions by photo-irradiation

T2 - Use of aromatization to stabilize ionic photo-products from acridine derivatives

AU - Ackmann, Aaron J.

AU - Fréchet, Jean M.J.

PY - 1996

Y1 - 1996

N2 - The photolysis of 9-hydroxy-10-methyl-9-phenyl-9,10-dihydroacridine 1 or its 9-methoxy derivative 2 occurs with heterolytic cleavage of a C-O bond and formation of the desired strong base together with a cation that stabilizes itself through aromatization.

AB - The photolysis of 9-hydroxy-10-methyl-9-phenyl-9,10-dihydroacridine 1 or its 9-methoxy derivative 2 occurs with heterolytic cleavage of a C-O bond and formation of the desired strong base together with a cation that stabilizes itself through aromatization.

UR - http://www.scopus.com/inward/record.url?scp=19244364550&partnerID=8YFLogxK

U2 - 10.1039/CC9960000605

DO - 10.1039/CC9960000605

M3 - Article

AN - SCOPUS:19244364550

SN - 1359-7345

SP - 605

EP - 606

JO - CHEMICAL COMMUNICATIONS

JF - CHEMICAL COMMUNICATIONS

IS - 5

ER -

The generation of hydroxide and methoxide ions by photo-irradiation: Use of aromatization to stabilize ionic photo-products from acridine derivatives

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this