The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle x-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations

Maarten Goesten; Eli Stavitski; Evgeny A. Pidko; Canan Gücüyener; Bart Boshuizen; Steven N. Ehrlich; Emiel J.M. Hensen; Freek Kapteijn; Jorge Gascon

doi:10.1002/chem.201204638

The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle x-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations

Maarten Goesten, Eli Stavitski, Evgeny A. Pidko, Canan Gücüyener, Bart Boshuizen, Steven N. Ehrlich, Emiel J.M. Hensen, Freek Kapteijn, Jorge Gascon^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

We present an in situ small- and wide-angle X-ray scattering (SAXS/WAXS) and quick-scanning extended X-ray absorption fine-structure (QEXAFS) spectroscopy study on the crystallization of the metal-organic framework ZIF-7. In combination with DFT calculations, the self-assembly and growth of ZIF-7 microrods together with the chemical function of the crystal growth modulator (diethylamine) are revealed at all relevant length scales, from the atomic to the full crystal size.

Original language	English (US)
Pages (from-to)	7809-7816
Number of pages	8
Journal	Chemistry - A European Journal
Volume	19
Issue number	24
DOIs	https://doi.org/10.1002/chem.201204638
State	Published - Jun 10 2013
Externally published	Yes

Keywords

X-ray absorption spectroscopy
crystal engineering
density functional calculations
metal-organic frameworks
self-assembly

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201204638

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Goesten, M., Stavitski, E., Pidko, E. A., Gücüyener, C., Boshuizen, B., Ehrlich, S. N., Hensen, E. J. M., Kapteijn, F., & Gascon, J. (2013). The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle x-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations. Chemistry - A European Journal, 19(24), 7809-7816. https://doi.org/10.1002/chem.201204638

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title = "The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle x-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations",

abstract = "We present an in situ small- and wide-angle X-ray scattering (SAXS/WAXS) and quick-scanning extended X-ray absorption fine-structure (QEXAFS) spectroscopy study on the crystallization of the metal-organic framework ZIF-7. In combination with DFT calculations, the self-assembly and growth of ZIF-7 microrods together with the chemical function of the crystal growth modulator (diethylamine) are revealed at all relevant length scales, from the atomic to the full crystal size.",

keywords = "X-ray absorption spectroscopy, crystal engineering, density functional calculations, metal-organic frameworks, self-assembly",

author = "Maarten Goesten and Eli Stavitski and Pidko, {Evgeny A.} and Canan G{\"u}c{\"u}yener and Bart Boshuizen and Ehrlich, {Steven N.} and Hensen, {Emiel J.M.} and Freek Kapteijn and Jorge Gascon",

year = "2013",

month = jun,

day = "10",

doi = "10.1002/chem.201204638",

language = "English (US)",

volume = "19",

pages = "7809--7816",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley",

number = "24",

}

Goesten, M, Stavitski, E, Pidko, EA, Gücüyener, C, Boshuizen, B, Ehrlich, SN, Hensen, EJM, Kapteijn, F & Gascon, J 2013, 'The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle x-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations', Chemistry - A European Journal, vol. 19, no. 24, pp. 7809-7816. https://doi.org/10.1002/chem.201204638

The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle x-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations. / Goesten, Maarten; Stavitski, Eli; Pidko, Evgeny A. et al.
In: Chemistry - A European Journal, Vol. 19, No. 24, 10.06.2013, p. 7809-7816.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle x-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations

AU - Goesten, Maarten

AU - Stavitski, Eli

AU - Pidko, Evgeny A.

AU - Gücüyener, Canan

AU - Boshuizen, Bart

AU - Ehrlich, Steven N.

AU - Hensen, Emiel J.M.

AU - Kapteijn, Freek

AU - Gascon, Jorge

PY - 2013/6/10

Y1 - 2013/6/10

N2 - We present an in situ small- and wide-angle X-ray scattering (SAXS/WAXS) and quick-scanning extended X-ray absorption fine-structure (QEXAFS) spectroscopy study on the crystallization of the metal-organic framework ZIF-7. In combination with DFT calculations, the self-assembly and growth of ZIF-7 microrods together with the chemical function of the crystal growth modulator (diethylamine) are revealed at all relevant length scales, from the atomic to the full crystal size.

AB - We present an in situ small- and wide-angle X-ray scattering (SAXS/WAXS) and quick-scanning extended X-ray absorption fine-structure (QEXAFS) spectroscopy study on the crystallization of the metal-organic framework ZIF-7. In combination with DFT calculations, the self-assembly and growth of ZIF-7 microrods together with the chemical function of the crystal growth modulator (diethylamine) are revealed at all relevant length scales, from the atomic to the full crystal size.

KW - X-ray absorption spectroscopy

KW - crystal engineering

KW - density functional calculations

KW - metal-organic frameworks

KW - self-assembly

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The molecular pathway to ZIF-7 microrods revealed by in situ time-resolved small- and wide-angle x-ray scattering, quick-scanning extended X-ray absorption spectroscopy, and DFT calculations

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