TY - JOUR
T1 - The reaction of tungsten(VI) alkylidyne complexes with inorganic oxides
T2 - Involvement of the resulting alkylidene ligand in olefin metathesis
AU - Buffon, Regina
AU - Leconte, Michael
AU - Choplin, Agnès
AU - Basset, Jean-Marie Maurice
PY - 1993/12/1
Y1 - 1993/12/1
N2 - Although Schrock-type tungsten alkylidyne complexes react with inorganic oxides with formation of surface tungsten alkylidene species, the high catalytic activity of W(CCMe3)(CH2CMe3) 3/Nb2O5 for the metathesis of Z-pent-2-ene does not seem to be correlated to the concentration of the alkylidene ligand, measured by specific reactions.
AB - Although Schrock-type tungsten alkylidyne complexes react with inorganic oxides with formation of surface tungsten alkylidene species, the high catalytic activity of W(CCMe3)(CH2CMe3) 3/Nb2O5 for the metathesis of Z-pent-2-ene does not seem to be correlated to the concentration of the alkylidene ligand, measured by specific reactions.
UR - http://www.scopus.com/inward/record.url?scp=37049080034&partnerID=8YFLogxK
U2 - 10.1039/C39930000361
DO - 10.1039/C39930000361
M3 - Article
AN - SCOPUS:37049080034
SN - 0577-6171
SP - 361
EP - 362
JO - Journal of the Chemical Society D: Chemical Communications
JF - Journal of the Chemical Society D: Chemical Communications
IS - 4
ER -