The stability of inclusion compounds under heating: PPart I. Inclusion compounds of microporous manganese formate with included dioxane {Mn(HCOO )•21/3C4H8O2} and tetrahydrofurane {Mn(HCOO)•21/3C4H8O}

V. Logvinenko; D. Dybtsev; V. Fedin; V. Drebushchak; M. Yutkin

doi:10.1007/s10973-006-7683-2

The stability of inclusion compounds under heating: PPart I. Inclusion compounds of microporous manganese formate with included dioxane {Mn(HCOO ₎•21/3_C4_H8_O2} and tetrahydrofurane {Mn(HCOO₎•21/3_C4_H8O}

V. Logvinenko^*, D. Dybtsev, V. Fedin, V. Drebushchak, M. Yutkin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The thermal decomposition of two inclusion compounds Mn(HCOO) ₂•1/3C₄H₈O₂ and Mn(HCOO) ₂•1/3C₄H₈O was studied in the inert atmosphere. The process of both dioxane, and tetrahydrofurane removal has two steps; the intermediate phase is unstable and kinetically hindered. Manganese formate is stable up to 330°C. Thermogravimetric data (obtained at different rates of linear heating) were processed with computer program (with 'Model free' approach). Kinetic parameters were calculated for the first decomposition step, and the process is described by equation of n-order reaction with autocatalysis.

Original language	English (US)
Pages (from-to)	463-467
Number of pages	5
Journal	Journal of Thermal Analysis and Calorimetry
Volume	90
Issue number	2
DOIs	https://doi.org/10.1007/s10973-006-7683-2
State	Published - Nov 2007
Externally published	Yes

Keywords

'model free' kinetics
Coordination compounds
Inclusion compounds

ASJC Scopus subject areas

Condensed Matter Physics
Physical and Theoretical Chemistry

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Logvinenko, V., Dybtsev, D., Fedin, V., Drebushchak, V., & Yutkin, M. (2007). The stability of inclusion compounds under heating: PPart I. Inclusion compounds of microporous manganese formate with included dioxane {Mn(HCOO ₎•21/3_C4_H8_O2} and tetrahydrofurane {Mn(HCOO₎•21/3_C4_H8O}. Journal of Thermal Analysis and Calorimetry, 90(2), 463-467. https://doi.org/10.1007/s10973-006-7683-2

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title = "The stability of inclusion compounds under heating: PPart I. Inclusion compounds of microporous manganese formate with included dioxane {Mn(HCOO )•21/3C4H8O2} and tetrahydrofurane {Mn(HCOO)•21/3C4H8O}",

abstract = "The thermal decomposition of two inclusion compounds Mn(HCOO) 2•1/3C4H8O2 and Mn(HCOO) 2•1/3C4H8O was studied in the inert atmosphere. The process of both dioxane, and tetrahydrofurane removal has two steps; the intermediate phase is unstable and kinetically hindered. Manganese formate is stable up to 330°C. Thermogravimetric data (obtained at different rates of linear heating) were processed with computer program (with 'Model free' approach). Kinetic parameters were calculated for the first decomposition step, and the process is described by equation of n-order reaction with autocatalysis.",

keywords = "'model free' kinetics, Coordination compounds, Inclusion compounds",

author = "V. Logvinenko and D. Dybtsev and V. Fedin and V. Drebushchak and M. Yutkin",

year = "2007",

month = nov,

doi = "10.1007/s10973-006-7683-2",

language = "English (US)",

volume = "90",

pages = "463--467",

journal = "Journal of Thermal Analysis and Calorimetry",

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Logvinenko, V, Dybtsev, D, Fedin, V, Drebushchak, V & Yutkin, M 2007, 'The stability of inclusion compounds under heating: PPart I. Inclusion compounds of microporous manganese formate with included dioxane {Mn(HCOO ₎•21/3_C4_H8_O2} and tetrahydrofurane {Mn(HCOO₎•21/3_C4_H8O}', Journal of Thermal Analysis and Calorimetry, vol. 90, no. 2, pp. 463-467. https://doi.org/10.1007/s10973-006-7683-2

The stability of inclusion compounds under heating: PPart I. Inclusion compounds of microporous manganese formate with included dioxane {Mn(HCOO ₎•21/3_C4_H8_O2} and tetrahydrofurane {Mn(HCOO₎•21/3_C4_H8O}. / Logvinenko, V.; Dybtsev, D.; Fedin, V. et al.
In: Journal of Thermal Analysis and Calorimetry, Vol. 90, No. 2, 11.2007, p. 463-467.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - The stability of inclusion compounds under heating

T2 - PPart I. Inclusion compounds of microporous manganese formate with included dioxane {Mn(HCOO )•21/3C4H8O2} and tetrahydrofurane {Mn(HCOO)•21/3C4H8O}

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AU - Drebushchak, V.

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PY - 2007/11

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AB - The thermal decomposition of two inclusion compounds Mn(HCOO) 2•1/3C4H8O2 and Mn(HCOO) 2•1/3C4H8O was studied in the inert atmosphere. The process of both dioxane, and tetrahydrofurane removal has two steps; the intermediate phase is unstable and kinetically hindered. Manganese formate is stable up to 330°C. Thermogravimetric data (obtained at different rates of linear heating) were processed with computer program (with 'Model free' approach). Kinetic parameters were calculated for the first decomposition step, and the process is described by equation of n-order reaction with autocatalysis.

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